<italic style="font-style: italic">n</italic>-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide

Xu-Dong Bai; Zi-Di Yu; Yao Li; Tian-Yu Zhang; Di Zhang; Jie-Yu Wang; Jian Pei; Da-Hui Zhao

doi:10.1007/s10118-023-3026-z

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n-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide

RESEARCH ARTICLE | Updated：2023-09-21

- n-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide
  Enhanced Publication
- Chinese Journal of Polymer Science Vol. 41, Issue 10, Pages: 1584-1590(2023)
- Affiliations：
  
  1.Beijing National Laboratory for Molecular Sciences, Centre of Soft Matter Science and Engineering and Key Lab of Polymer Chemistry & Physics of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China
- Author bio：
  
  jianpei@pku.edu.cn (J.P.)
  dhzhao@pku.edu.cn (D.H.Z.)
- Funds：
- DOI：10.1007/s10118-023-3026-z
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Xu-Dong Bai, Zi-Di Yu, Yao Li, et al. n-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide. [J]. Chinese Journal of Polymer Science 41(10):1584-1590(2023)
DOI：

Xu-Dong Bai, Zi-Di Yu, Yao Li, et al. n-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide. [J]. Chinese Journal of Polymer Science 41(10):1584-1590(2023) DOI： 10.1007/s10118-023-3026-z.

摘要

Using the novel pyrene-1,5,6,10-tetracarboxyldiimide (PyDI) as the electron acceptor, two new D-A conjugated polymers are synthesized. In solution-processed FETs, these polymers display impressive electron mobility of 0.18 and 0.20 cm2·V,−1,·s,−1, demonstrating the optimal potential of PyDI for the development of high-performance electron-transporting materials.

Abstract

Donor-acceptor (D-A) conjugated polymers comprising electron-deficient aromatic dicarboximide units represent an important type of organic semiconductors, especially for electron transporting properties. Pyrene-1,5,6,10-tetracarboxyl diimide (PyDI), a new PAH dicarboximide molecule recently reported by us, provides a fine balance between the electron-stabilizing ability and ,π,-stacking tendency, as compared to the naphthalenediimide (NDI) and perylenediimide (PDI) analogues. In this study, using thienylene-vinylene-thienylene (TVT) and biselenophene (BS) as the electron donating comonomer, along with PyDI as the acceptor moiety, we develop two new D-A type conjugated polymers, which exhibit impressive electron-transporting performance. Specifically, in the solution-processed OFET devices, electron mobility of 0.18 and 0.20 cm,2,·V,−1,·s,−1, are achieved with these polymers, respectively. Such findings further prove the optimal potential of PyDI for application as an electron-acceptor building block in the development of polymeric ,n,-type semiconductors among all various high-performance functional D-A polymers.

关键词

Keywords

PyrenediimideConjugated polymersDonor-acceptorOrganic electronics

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n-Type Semiconductive Polymers Based on Pyrene-1,5,6,10-Tetracarboxyl Diimide

DOI：10.1007/s10118-023-3026-z

摘要

Abstract

关键词

Keywords

references