a.School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241, China
b.National & Local United Engineering Laboratory of Integrative Utilization Technology of Eucommia Ulmoides, College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China
bccLyj@163.com (Y.J.L.)
mrxie@chem.ecnu.edu.cn (M.R.X.)
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Zhi-Ying Han, Heng-Chen Zhang, You-Ji Li, et al. Unique Damping Properties of Modified
Zhi-Ying Han, Heng-Chen Zhang, You-Ji Li, et al. Unique Damping Properties of Modified
Eucommia ulmoides, gum (EUG) was modified by triazolinedione, and the modified EUG exhibited the obviously enhanced damping properties with a wide effective damping temperature range, large loss factor, and high damping coefficient, attributed to the introduced polar and branched pendants, and the microphase separation morphology to dissipate vibrational mechanical energy.
Eucommia ulmoides, gum (EUG) was a biobased hard rubber with the prospected broad applications in rubber products, whereas possessed poor elasticity and weak damping functionality at room temperature. After modification of EUG by triazolinedione-based Alder-ene reaction, the modified EUG containing varied amount of polar and branched pendants could become a new type of soft rubber and functional material with excellent damping properties, and especially exhibited the unique damping plateau with a wide effective damping temperature range of 132 °C covering from −35 °C to 97 °C, large loss factor of 0.8, high damping coefficient of 0.53, and more hysteresis loss of 0.35. Therefore, this sustainable elastomeric material with adjustable damping performance would absorb more vibrational mechanical energy in a wide temperature range, and have broadened applications in energy-absorption devices and shock-absorbing materials.
Eucommia ulmoides gum ModificationBranched pendantDamping performance
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