

FOLLOWUS
a.School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241, China
b.National & Local United Engineering Laboratory of Integrative Utilization Technology of Eucommia Ulmoides, College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China
bccLyj@163.com (Y.J.L.)
mrxie@chem.ecnu.edu.cn (M.R.X.)
Received:29 August 2022,
Revised:2022-11-1,
Accepted:10 November 2022,
Online First:29 December 2022,
Published:01 June 2023
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Han, Z. Y.; Zhang, H. C.; Li, Y. J.; Quan, Y.; Xie, M. R. Unique damping properties of modified Eucommia ulmoides gum bearing polar and branched pendants. Chinese J. Polym. Sci. 2023, 41, 915–925
Zhi-Ying Han, Heng-Chen Zhang, You-Ji Li, et al. Unique Damping Properties of Modified
Han, Z. Y.; Zhang, H. C.; Li, Y. J.; Quan, Y.; Xie, M. R. Unique damping properties of modified Eucommia ulmoides gum bearing polar and branched pendants. Chinese J. Polym. Sci. 2023, 41, 915–925 DOI: 10.1007/s10118-023-2899-1.
Zhi-Ying Han, Heng-Chen Zhang, You-Ji Li, et al. Unique Damping Properties of Modified
Eucommia ulmoides
gum (EUG) was modified by triazolinedione
and the modified EUG exhibited the obviously enhanced damping properties with a wide effective damping temperature range
large loss factor
and high damping coefficient
attributed to the introduced polar and branched pendants
and the microphase separation morphology to dissipate vibrational mechanical energy.
Eucommia ulmoides
gum (EUG) was a biobased hard rubber with the prospected broad applications in rubber products
whereas possessed poor elasticity and weak damping functionality at room temperature. After modification of EUG by triazolinedione-based Alder-ene reaction
the modified EUG containing varied amount of polar and branched pendants could become a new type of soft rubber and functional material with excellent damping properties
and especially exhibited the unique damping plateau with a wide effective damping temperature range of 132 °C covering from −35 °C to 97 °C
large loss factor of 0.8
high damping coefficient of 0.53
and more hysteresis loss of 0.35. Therefore
this sustainable elastomeric material with adjustable damping performance would absorb more vibrational mechanical energy in a wide temperature range
and have broadened applications in energy-absorption devices and shock-absorbing materials.
Wu,J.;Huang,G.;Wang,X.;He,X.;Xu,B.Changesintheviscoelasticmechanismsofpolyisobutylenebyplasticization. Macromolecules 2012 , 45 ,8051−8057..
Stadler,F.J.;Auhl,D.;Münstedt,H.Influenceofthemolecularstructureofpolyolefinsonthedampingfunctioninshear. Macromolecules 2008 , 41 ,3720−3726..
Wu,J.;Bo,C.;Wang,Y.;Su,B.;Liu,Q.;Zhao,J.Effectofcuringtimeonmechanicalanddynamicmechanicalpropertiesofbutylrubber. Mater. Res. Innov. 2015 , 19 ,148−152..
SenakePerera,M.C.;Ishiaku,U.S.;Ishak,Z.A.M.CharacterisationofPVC/NBRandPVC/ENR50binaryblendsandPVC/ENR50/NBRternaryblendsbyDMAandsolidstateNMR. Eur. Polym. J. 2001 , 37 ,167−178..
Wang,J.;Wang,W.;Geng,X.;Nishi,T.;Zhao,X.;ZhangL.Developmentofhighdampingacrylicrubber/slidinggraftcopolymercomposites. RSC Adv. 2018 , 8 ,36172−36180..
Shi,X.;Song,Y.;Cai,Z.;Wang,X.;Cao,D.;Cheng,Q.;Zou,J.;Shi,Z.;Cui,Z.Theinfluenceofmicrocapsuleswithapartiallyfilledstructureonthedampingpropertiesofanepoxyresin. New J. Chem. 2018 , 42 ,12119−12125..
Lu,X.;Li,X.;Tian,M.Preparationofhighdampingelastomerwithbroadtemperatureandfrequencyrangesbasedonternaryrubberblends. Polym. Adv. Technol. 2014 , 25 ,21−28..
Martin,D.J.;Meijs,G.F.;Renwick,G.M.;Gunatillake,P.A.;MccarthyS.J.Effectofsoft-segmentCH 2 /Oratioonmorphologyandpropertiesofaseriesofpolyurethaneelastomers. J. Appl. Polym. Sci. 1996 , 60 ,557−571..
Aprem,A.S.;Jose,S.;Thomas,S.;Barkoula,N.M.;Kocsis,J.K.Influenceofhygrothermallydegradedpolyester-urethaneonphysicalandmechanicalpropertiesofchloroprenerubber. Eur. Polym. J. 2003 , 39 ,69−76..
Ma,S.;Liu,X.;Jiang,Y.;Tang,Z.;Zhang,C.;Zhu,J.Bio-basedepoxyresinfromitaconicacidanditsthermosetscuredwithanhydrideandcomonomers. Green Chem. 2013 , 15 ,245−254..
Ma,Q.;Liu,X.;Zhang,R.;Zhu,J.;Jiang,Y.Synthesisandpropertiesoffullbio-basedthermosettingresinsfromrosinacidandsoybeanoil:theroleofrosinacidderivatives. Green Chem. 2013 , 15 ,1300−1310..
Yao,K.;Nie,H.;Liang,Y.;Qiu,D.;He,A.Polymorphiccrystallizationbehaviorsin cis -1,4-polyisoprene/ trans -1,4-polyisopreneblends. Polymer 2015 , 80 ,259−264..
Zhang,H.;Ma,C.;Sun,R.;Liao,X.;Wu,J.;Xie,M.Sustainableelastomeroftriazolinedione-modified Eucommia ulmoides gumwithenhancedelasticityandshapememorycapability. Polymer 2019 , 184 ,121904..
Tsujimoto,T.;Toshimitsu,K.;Uyama,H.;Takeno,S.;Nakazawa,Y.Maleated trans -1,4-polyisoprenefrom Eucommia ulmoides Oliver withdynamicnetworkstructureanditsshapememoryproperty. Polymer 2014 , 55 ,6488−6493..
Xia,L.;Wang,Y.;Ma,Z.G.;Du,A.H.;Qiu,G.X.;Xin,Z.X.Preparationofepoxidized Eucommia ulmoides gumanditsapplicationinstyrene-butadienerubber(SBR)/silicacomposites. Polym. Adv. Technol. 2017 , 28 ,94−101..
Zhao,Y.X.;Huang,B.C.;Yao,W.;Cong,H.L.;Shao,H.F.;Du,A.H.Epoxidationofhigh trans -1,4-polyisopreneanditsproperties. J. Appl. Polym. Sci. 2008 , 107 ,2986−2993..
Qi,X.;Zhang,J.;Zhang,L.;Yue,D.Bio-basedself-healing Eucommia ulmoides esterelastomerwithdampingandoilresistance. J. Mater. Sci. 2020 , 55 ,4940−4951..
Qi,X.;Zhang,J.;Zhang,L.;Yue,D.Bio-based,robust,shapememory,self-healingandrecyclableelastomersbasedonasemi-interpenetratingdynamicnetwork. J. Mater. Chem. A 2021 , 9 ,25399−25407..
Qi,X.;Zhao,X.;Li,Y.;Zhang,J.;Zhang,L.;Yue,D.Ahightoughnesselastomerbasedonnatural Eucommia ulmoides gum. J. Appl. Polym. Sci. 2021 , 13 ,50007..
Zhang,J.;Xue,Z.;Yan,R.DampingperformanceofEucommiaulmoidesgum. Chinese J. Polym. Sci. 2011 , 29 ,157−163..
Sarina;Zhang,J.;Zhang,L.Dynamicmechanicalpropertiesof Eucommia ulmoides gumwithdifferentdegreeofcross-linking. Polym. Bull. 2012 , 68 ,2021−2032..
Cao,R.;Deng,L.;Feng,Z.;Zhao,X.;Li,X.;Zhang,L.Preparationofnaturalbio-based Eucommia ulmoides gum/styrene-butadienerubbercompositesandtheevaluationoftheirdampingandsoundabsorptionproperties. Polymer 2021 , 213 ,123292..
Ni,Q.;Wu,J.;Kong,P.;Wang,Y.;Li,Y.;Li,Y.;Peng,X.Inversevulcanizationpolymer-modified Eucommia ulmoides gumwithenhancedshapememorycapabilityandsoundabsorptionproperty. ACS Appl. Polym. Mater. 2022 , 4 ,4689−4698..
Qi,X.;Xie,F.;Zhang,J.;Zhang,L.;Yue,D.Bio-basedcyclized Eucommia ulmoides gumelastomerforpromisingdampingapplications. RSC Adv. 2019 , 9 ,42367−42374..
Urayama,K.;Miki,T.;Takigawa,T.;Kohjiya,S.Dampingelastomerbasedonmodelirregularnetworksofend-linkedpoly(dimethylsiloxane). Chem. Mater. 2004 , 16 ,173−178..
Chueangchayaphan,W.;Chueangchayaphan,N.;Tanrattanakul,V.;Muangsap,S.Influencesofthegraftingpercentageofnaturalrubber- graft -poly(2-hydroxyethylacrylate)onpropertiesofitsvulcanizates. Polym. Int. 2018 , 67 ,739−746..
Zhang,C.;Pal,K.;Byeon,J.U.;Han,S.M.;Kim,J.K.Astudyonmechanicalandthermalpropertiesofsiliconerubber/EPDMdampingmaterials. J. Appl. Polym. Sci. 2011 , 119 ,2737−2741..
Lei,Z.;Xing,W.;Wu,J.;Huang,G.;Wang,X.;Zhao,L.Theproperglasstransitiontemperatureofamorphouspolymersondynamicmechanicalspectra. J. Therm. Anal. Calorim. 2014 , 116 ,447−453..
Butler,G.B.Triazolinedionemodifiedpolydienes. Ind. Eng. Chem. Prod. Res. Dev. 1980 , 19 ,512−528..
Li,H.;Ren,Q.;Chen,J.;Zhang,H.;Wu,J.;Xie,M.Triazolinedione-basedAlder-enemodificationof Eucommia ulmoide gumtoflexiblepolyelectrolyteandiongel. React. Funct. Polym. 2018 , 132 ,104−111..
Zhao,J.;Zhang,H.;Ma,C.;Han,H.;Sun,R.;Xie,M.Binarymodificationof Eucommia ulmoides gumtowardelastomerwithtunablemechanicalpropertiesandgoodcompatibility. J. Polym. Sci. Part A: Polym. Chem. 2019 , 57 ,1247−1255..
VanHerck,N.;DuPrez,F.E.Fasthealingofpolyurethanethermosetsusingreversibletriazolinedionechemistryandshape-memory. Macromolecules 2018 , 51 ,3405−3414..
VanderHeijden,S.;DeBruycker,K.;Simal,R.;DuPrez,F.;DeClerck,K.UseoftriazolinedioneclickchemistryfortuningthemechanicalpropertiesofelectrospunSBS-fibers. Macromolecules 2015 , 48 ,6474−6481..
Xiao,L.;Chen,Y.;Zhang,K.Efficientmetal-free“graftingonto”methodforbottlebrushpolymersbycombiningRAFTandtriazolinedione-dieneclickreaction. Macromolecules 2016 , 49 ,4452−4461..
Lee,J.H.;Driva,P.;Hadjichristidis,N.;Wright,P.J.;Rucker,S.P.;Lohse,D.J.Dampingbehaviorofentangledcombpolymers:experiment. Macromolecules 2009 , 42 ,1392−1399..
Beniah,G.;Fortman,D.J.;Heath,W.H.;Dichtel,W.R.;Torkelson,J.M.Non-isocyanatepolyurethanethermoplasticelastomer:amide-basedchainextenderyieldsenhancednanophaseseparationandpropertiesinpolyhydroxyurethane. Macromolecules 2017 , 50 ,4425−4434..
Xu,Y.;Petrovic,Z.;Das,S.;Wilkes,G.L.Morphologyandpropertiesofthermoplasticpolyurethaneswithdanglingchainsinricinoleate-basedsoftsegments. Polymer 2008 , 49 ,4248−4258..
Lei,W.;Qi,S.;Rong,Q.;Huang,J.;Xu,Y.;Fang,R.;Liu,K.;Jiang,L.;Liu,M.Diffusion-freezing-inducedmicrophaseseparationforconstructinglarge-areamultiscalestructuresonhydrogelsurfaces. Adv. Mater. 2019 , 31 ,1808217..
Vlaminck,L.;DeBruycker,K.;Türünç,O.;DuPrez,F.E.ADMETandTADchemistry:asustainablealliance. Polym. Chem. 2016 , 7 ,5655−5663..
Gaitzsch,J.;Delahaye,M.;Poma,A.;DuPrez,F.;Battaglia,G.Comparisonofmetalfreepolymer–dyeconjugationstrategiesinproticsolvents. Polym. Chem. 2016 , 7 ,3046−3055..
Chen,B.;Ma,N.;Bai,X.;Zhang,H.;Zhang,Y.Effectsofgrapheneoxideonsurfaceenergy,mechanical,dampingandthermalpropertiesofethylene-propylene-dienerubber/petroleumresinblends. RSC Adv. 2012 , 2 ,4683−4689..
Zhang,J.;Xue,Z.Acomparativestudyonthepropertiesof Eucommia ulmoides gumandsynthetic trans -1,4-polyisoprene. Polym. Test. 2011 , 30 ,753−759..
Yang,F.;Dai,L.;Liu,T.;Zhou,J.;Fang,Q.Preparationofhigh-dampingsoftelastomerbasedon Eucommia ulmoides gum. Polym. Bull. 2020 , 77 ,33−47..
Yu,W.;Du,M.;Zhang,D.;Lin,Y.;Zheng,Q.Influenceofdanglingchainsonmoleculardynamicsofpolyurethanes. Macromolecules 2013 , 46 ,7341−7351..
Yamazaki,H.;Takeda,M.;Kohno,Y.;Ando,H.;Urayama,K.;Takigawa,T.Dynamicviscoelasticityofpoly(butylacrylate)elastomerscontainingdanglingchainswithcontrolledlengths. Macromolecules 2011 , 44 ,8829−8834..
Wang,Y.;Wang,Y.;Zhang,H.;Zhang,L.Anovelapproachtoprepareagradientpolymerwithawidedampingtemperaturerangeby in-situ chemicalmodificationofrubberduringvulcanization. Macromol. Rapid Commun. 2006 , 27 ,1162−1167..
Urayama,K.Networktopology-mechanicalpropertiesrelationshipsofmodelelastomers. Polym. J. 2008 , 40 ,669−678..
Liu,Y.;Tang,Z.;Wu,S.;Guo,B.Integratingsacrificialbondsintodynamiccovalentnetworkstowardmechanicallyrobustandmalleableelastomers. ACS Macro Lett. 2019 , 8 ,193−199..
Wang,W.;Zhao,D.;Yang,J.;Nishi,T.;Ito,K.;Zhao,X.;Zhang,L.Novelslide-ringmaterial/naturalrubbercompositeswithhighdampingproperty. Sci. Rep. 2016 , 6 ,22810..
Yin,C.;Zhao,X.;Zhu,J.;Hu,H.;Song,M.;Wu,S.ExperimentalandmoleculardynamicssimulationstudyonthedampingmechanismofC5petroleumresin/chlorinatedbutylrubbercomposites. J. Mater. Sci. 2019 , 54 ,3960−3974..
Wu,C.;Yamagishi,T.;Nakamoto,Y.;Ishida,S.;Nitta,K.;Kubota,S.Viscoelasticpropertiesofanorganichybridofchlorinatedpolyethyleneandasmallmolecule. J. Polym. Sci. B 2000 , 38 ,1341−1347..
Sun,T.;Gong,X.;Jiang,W.;Li,J.;Xu,Z.;Li,W.Studyonthedampingpropertiesofmagnetorheologicalelastomersbasedon cis -polybutadienerubber. Polym. Test. 2008 , 27 ,520−526..
Zhang,G.;Zhou,X.;Liang,K.;Guo,B.;Li,X.;Wang,Z.;Zhang,L.MechanicallyrobustandrecyclableEPDMrubbercompositesbyagreencross-linkingstrategy. ACS Sustain. Chem. Eng. 2019 , 7 ,11712−11720..
Wang,J.;Zhao,X.;Wang,W.;Geng,X.;Zhang,L.;Guo,B.;Nishi,T.;Hu,G.Significantlyimprovingstrengthanddampingperformanceofnitrilerubber via incorporatingslidinggraftcopolymer. Ind. Eng. Chem. Res. 2018 , 57 ,16692−16700..
Liu,Z.;Wang,Y.;Huang,G.;Wu,J.Dampingcharacteristicsofchlorobutylrubber/poly(ethylacrylate)/piezoelectricceramic/carbonblackcomposites. J. Appl. Polym. Sci. 2008 , 108 ,3670−3676..
Liu,B.;Wang,S.;Liu,J.;Tang,Z.;Guo,B.Promotedstrain-inducedcrystallizationof cis -1,4-polyisoprenewithfunctionalcarbonnanodots. Adv. Ind. Eng. Polym. 2019 , 2 ,25−31..
Montano,V.;Wempe,M.M.B.;Does,S.M.H.;Bijleveld;Johan,C.;Zwaag,S.V.D.;Garcia,S.J.Controllinghealingandtoughnessinpolyurethanesbybranch-mediatedtubedilation. Macromolecules 2019 , 52 ,8067−8078..
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