Dual Photo/Thermo-Responsive Polypeptoids

Yu-Xuan Zhang; Jie Huang; Jun Zhang; Ning Ren; Gang-Sheng Tong; Xin-Yuan Zhu

doi:10.1007/s10118-022-2837-7

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Dual Photo/Thermo-Responsive Polypeptoids

RESEARCH ARTICLE | Updated：2022-12-19

- Dual Photo/Thermo-Responsive Polypeptoids
- Chinese Journal of Polymer Science Vol. 41, Issue 1, Pages: 24-31(2023)
- Affiliations：
  
  1.School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Research Institute of Polymer Materials, Shanghai Jiao Tong University, Shanghai 200240, China
- Author bio：
  
  ningren@sjtu.edu.cn (N.R.)
  xyzhu@sjtu.edu.cn (X.Y.Z)
- Funds：
- DOI：10.1007/s10118-022-2837-7
  CLC：
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Yu-Xuan Zhang, Jie Huang, Jun Zhang, et al. Dual Photo/Thermo-Responsive Polypeptoids. [J]. Chinese Journal of Polymer Science 41(1):24-31(2023)
DOI：

Yu-Xuan Zhang, Jie Huang, Jun Zhang, et al. Dual Photo/Thermo-Responsive Polypeptoids. [J]. Chinese Journal of Polymer Science 41(1):24-31(2023) DOI： 10.1007/s10118-022-2837-7.

摘要

The synthesis of dual photo/thermo-responsive polypeptoid via ring-opening polymerization of a NNCA monomer bearing both Azo group and OEG segment.

Abstract

A series of polypeptoids with dual photo/thermo-responsiveness were prepared by incorporating both azobenzene (Azo) group and oligo(ethylene glycol) (OEG) segment into the side chains. Firstly, the ,N,-substituted-,N,-carboxyanhydride (NNCA) monomers with different Azo and OEG groups were synthesized, and then a single NNCA ring-openning polymerization was performed to afford dual-responsive polypeptoids without any post-polymerization modification. The ultra-violet/visible (UV/Vis) photo-responsive behaviors of the polypeptoids were achieved by ,cis,-,trans, photoisomerization of the Azo group and confirmed by both ,1,H-NMR and UV/Vis spectroscopy. The thermo-responsive behaviors were realized by both OEG segment and Azo group and confirmed by UV/Vis spectroscopy and dynamic light scattering. This work demonstrated the synthetic pathway for dual responsive polypeptoids using NNCA monomers with two responsive groups and revealed the potential of polypeptoids as smart materials that could respond to different environmental stimuli.

关键词

Keywords

Dual-responsive polymerPolypeptoidRing-opening polymerization

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