Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales

Wei Zhao; Tian-Pin Wang; Jia-Li Wu; Ru-Ping Pan; Xiang-Yang Liu; Xi-Kui Liu

doi:10.1007/s10118-019-2313-1

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Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales

RAPID COMMUNICATION | Updated：2021-02-18

- Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales
- Chinese Journal of Polymer Science Vol. 37, Issue 11, Pages: 1045-1052(2019)
- Affiliations：
  
  College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  xkliu@scu.edu.cn
- Funds：
- DOI：10.1007/s10118-019-2313-1
  CLC： M
- Received：15 April 2019，
  
  Revised：2019-5-30，
  
  Accepted：08 June 2019，
  
  Online First：12 September 2019，
  
  Published：2019-11
- Accepted：
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Zhao, W.; Wang, T. P.; Wu, J. L.; Pan, R. P.; Liu, X. Y.; Liu, X. K. Monolithic covalent organic framework aerogels through framework crystallization induced self-assembly: Heading towards framework materials synthesis over all length scales. Chinese J. Polym. Sci. 2019, 37, 1045–1052.

Wei Zhao, Tian-Pin Wang, Jia-Li Wu, et al. Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales[J]. Chinese Journal of Polymer Science, 2019, 37(11): 1045-1052.
Zhao, W.; Wang, T. P.; Wu, J. L.; Pan, R. P.; Liu, X. Y.; Liu, X. K. Monolithic covalent organic framework aerogels through framework crystallization induced self-assembly: Heading towards framework materials synthesis over all length scales. Chinese J. Polym. Sci. 2019, 37, 1045–1052. DOI： 10.1007/s10118-019-2313-1.

Wei Zhao, Tian-Pin Wang, Jia-Li Wu, et al. Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales[J]. Chinese Journal of Polymer Science, 2019, 37(11): 1045-1052. DOI： 10.1007/s10118-019-2313-1.

摘要

Abstract

Here

through the synergism between kinetic dynamic imine-exchange control and thermodynamic control

rarely observed compressible

porous

crystalline covalent organic framework (COF) aerogels were synthesized

the mechanism behind which is a framework crystallization induced self-assembly (FCISA) process. The prepared COF aerogel possessed extremely high BET surface over 2000 m

·g

−1

and high maximum equilibrium adsorption capacity toward bisphenol-A of 699 mg·g

−1

in aqueous solution.

关键词

Keywords

references

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