Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales

Wei Zhao; Tian-Pin Wang; Jia-Li Wu; Ru-Ping Pan; Xiang-Yang Liu; Xi-Kui Liu

doi:10.1007/s10118-019-2313-1

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Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales

RAPID COMMUNICATION | Updated：2021-02-18

- Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales
- Chinese Journal of Polymer Science Vol. 37, Issue 11, Pages: 1045-1052(2019)
- Affiliations：
  
  1.College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  xkliu@scu.edu.cn
- Funds：
- DOI：10.1007/s10118-019-2313-1
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Wei Zhao, Tian-Pin Wang, Jia-Li Wu, et al. Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales. [J]. Chinese Journal of Polymer Science 37(11):1045-1052(2019)
DOI：

Wei Zhao, Tian-Pin Wang, Jia-Li Wu, et al. Monolithic Covalent Organic Framework Aerogels through Framework Crystallization Induced Self-assembly: Heading towards Framework Materials Synthesis over All Length Scales. [J]. Chinese Journal of Polymer Science 37(11):1045-1052(2019) DOI： 10.1007/s10118-019-2313-1.

摘要

Abstract

Here, through the synergism between kinetic dynamic imine-exchange control and thermodynamic control, rarely observed compressible, porous, crystalline covalent organic framework (COF) aerogels were synthesized, the mechanism behind which is a framework crystallization induced self-assembly (FCISA) process. The prepared COF aerogel possessed extremely high BET surface over 2000 m,2,·g,−1, and high maximum equilibrium adsorption capacity toward bisphenol-A of 699 mg·g,−1, in aqueous solution.

关键词

Keywords

Covalent organic framework (COF)AerogelFramework crystallization

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