Synthesis and Properties of Photodegradable Poly(furan-amine)s by a Catalyst-free Multicomponent Cyclopolymerization

Wei-Qiang Fu; Gui-Nan Zhu; Jian-Bing Shi; Bin Tong; Zheng-Xu Cai; Yu-Ping Dong

doi:10.1007/s10118-019-2281-5

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Synthesis and Properties of Photodegradable Poly(furan-amine)s by a Catalyst-free Multicomponent Cyclopolymerization

ARTICLE | Updated：2021-02-18

- Synthesis and Properties of Photodegradable Poly(furan-amine)s by a Catalyst-free Multicomponent Cyclopolymerization
- Chinese Journal of Polymer Science Vol. 37, Issue 10, Pages: 981-989(2019)
- Affiliations：
  
  Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
- Author bio：
  
  bing@bit.edu.cn (J.B.S.)
  chdongyp@bit.edu.cn (Y.P.D.)
- Funds：
- DOI：10.1007/s10118-019-2281-5
  CLC：
- Received：20 March 2019，
  
  Revised：2019-4-16，
  
  Accepted：22 April 2019，
  
  Online First：20 June 2019，
  
  Published：2019-10
- Accepted：
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Fu, W. Q.; Zhu, G. N.; Shi, J. B.; Tong, B.; Cai, Z. X.; Dong, Y. P. Synthesis and properties of photodegradable poly(furan-amine)s by a catalyst-free multicomponent cyclopolymerization. Chinese J. Polym. Sci. 2019, 37, 981–989.

Wei-Qiang Fu, Gui-Nan Zhu, Jian-Bing Shi, et al. Synthesis and Properties of Photodegradable Poly(furan-amine)s by a Catalyst-free Multicomponent Cyclopolymerization[J]. Chinese Journal of Polymer Science, 2019, 37(10): 981-989.
Fu, W. Q.; Zhu, G. N.; Shi, J. B.; Tong, B.; Cai, Z. X.; Dong, Y. P. Synthesis and properties of photodegradable poly(furan-amine)s by a catalyst-free multicomponent cyclopolymerization. Chinese J. Polym. Sci. 2019, 37, 981–989. DOI： 10.1007/s10118-019-2281-5.

Wei-Qiang Fu, Gui-Nan Zhu, Jian-Bing Shi, et al. Synthesis and Properties of Photodegradable Poly(furan-amine)s by a Catalyst-free Multicomponent Cyclopolymerization[J]. Chinese Journal of Polymer Science, 2019, 37(10): 981-989. DOI： 10.1007/s10118-019-2281-5.

摘要

Abstract

A series of new photodegradable poly(furan-amine)s (PFAs) were synthesized by a one-pot

catalyst-free

multicomponent cyclopolymerization between diisocyanides

dialkylacetylene dicarboxylates

and aromatic dialdehydes. All polymerizations were conducted in toluene at 100 °C for 6 h without inert gas protection and furnished polymers with a satisfactory molecular weight (

up to 32200) and yield. The PFA structure was confirmed by spectroscopic techniques

such as GPC

FTIR

and NMR

as well as by comparison with a model compound. The polymers exhibited good solubility in common organic solvents and thermal stability. All the PFAs had high refractive indices in the visible light region (400 nm to 800 nm). Moreover

the PFAs were substantially degraded by UV irradiation due to the presence of furan rings. The film thickness reduction rate could be over 90%.

关键词

Keywords

references

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