Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite

Zi-Bo Wei; Yang Zhao; Chao Wang; Shigenori Kuga; Yong Huang; Min Wu

doi:10.1007/s10118-018-2160-5

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Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite

ARTICLE | Updated：2021-02-18

- Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite
- Chinese Journal of Polymer Science Vol. 36, Issue 12, Pages: 1361-1367(2018)
- Affiliations：
  
  a.Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  yzhao@mail.ipc.ac.cn (Y.Z.)
  wumin@mail.ipc.ac.cn (M.W.)
- Funds：
- DOI：10.1007/s10118-018-2160-5
  CLC：
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Zi-Bo Wei, Yang Zhao, Chao Wang, et al. Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite. [J]. Chinese Journal of Polymer Science 36(12):1361-1367(2018)
DOI：

Zi-Bo Wei, Yang Zhao, Chao Wang, et al. Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite. [J]. Chinese Journal of Polymer Science 36(12):1361-1367(2018) DOI： 10.1007/s10118-018-2160-5.

摘要

Abstract

Multilayer graphene was prepared by mechanical exfoliation of natural graphite with dioctyl phthalate (DOP) as milling medium without solvent. The obtained mixture could be directly mixed with poly(vinyl chloride) (PVC) for melt-forming, with DOP acting as plasticizer and graphene acting as conductive filler for antistatic performance. The composite showed surface resistance of 2.5 × 10,6, Ω/□ at 1 wt% carbon additive, significantly lower than approx. 7 wt% of raw graphite required for achieving the same level. This value is low enough for practical antistatic criterion of 3 × 10,8, Ω/□. The effect of filler addition on mechanical performance was minimal, or even beneficial for the milled carbon in contrast to the case of raw graphite.

关键词

Keywords

Antistatic compositePoly(vinyl chloride)GrapheneMechanical exfoliationElectrical property

references

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