

FOLLOWUS
a.Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.University of Chinese Academy of Sciences, Beijing 100049, China
yzhao@mail.ipc.ac.cn (Y.Z.)
wumin@mail.ipc.ac.cn (M.W.)
Received:23 March 2018,
Revised:2018-5-2,
Accepted:19 May 2018,
Online First:14 June 2018,
Published:2018-12
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Citation: Wei, Z. B.; Zhao, Y.; Wang, C.; Kuga, S.; Huang, Y.; Wu, M. Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite. Chinese J. Polym. Sci. 2018, 36(12), 1361–1367
Zi-Bo Wei, Yang Zhao, Chao Wang, et al. Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite[J]. Chinese Journal of Polymer Science, 2018, 36(12): 1361-1367.
Citation: Wei, Z. B.; Zhao, Y.; Wang, C.; Kuga, S.; Huang, Y.; Wu, M. Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite. Chinese J. Polym. Sci. 2018, 36(12), 1361–1367 DOI: 10.1007/s10118-018-2160-5.
Zi-Bo Wei, Yang Zhao, Chao Wang, et al. Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite[J]. Chinese Journal of Polymer Science, 2018, 36(12): 1361-1367. DOI: 10.1007/s10118-018-2160-5.
Multilayer graphene was prepared by mechanical exfoliation of natural graphite with dioctyl phthalate (DOP) as milling medium without solvent. The obtained mixture could be directly mixed with poly(vinyl chloride) (PVC) for melt-forming
with DOP acting as plasticizer and graphene acting as conductive filler for antistatic performance. The composite showed surface resistance of 2.5 × 10
6
Ω/□ at 1 wt% carbon additive
significantly lower than approx. 7 wt% of raw graphite required for achieving the same level. This value is low enough for practical antistatic criterion of 3 × 10
8
Ω/□. The effect of filler addition on mechanical performance was minimal
or even beneficial for the milled carbon in contrast to the case of raw graphite.
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