A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer

Yu-Ting Wang; Huan Liang; Yen Wei; Jian-Long Wang; Xiang-Ming He; Yang Yang

doi:10.1007/s10118-024-3206-5

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A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer

RESEARCH ARTICLE | Updated：2024-09-23

- A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer
- Chinese Journal of Polymer Science Vol. 42, Issue 10, Pages: 1589-1594(2024)
- Affiliations：
  
  a.Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China
  b.The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China
- Author bio：
  
  yangyang86@tsinghua.edu.cn
- Funds：
- DOI：10.1007/s10118-024-3206-5
  CLC：
- Published：01 October 2024，
  
  Published Online：28 August 2024，
  
  Received：20 May 2024，
  
  Revised：16 July 2024，
  
  Accepted：18 July 2024
- Accepted：
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Wang, Y. T.; Liang, H.; Wei, Y.; Wang, J. L.; He, X. M.; Yang, Y. A simple-prepared and multi-reusable adhesive based on epoxy vitrimer. Chinese J. Polym. Sci. 2024, 42, 1589–1594

Yu-Ting Wang, Huan Liang, Yen Wei, et al. A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer. [J]. Chinese Journal of Polymer Science 42(10):1589-1594(2024)
Wang, Y. T.; Liang, H.; Wei, Y.; Wang, J. L.; He, X. M.; Yang, Y. A simple-prepared and multi-reusable adhesive based on epoxy vitrimer. Chinese J. Polym. Sci. 2024, 42, 1589–1594 DOI： 10.1007/s10118-024-3206-5.

Yu-Ting Wang, Huan Liang, Yen Wei, et al. A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer. [J]. Chinese Journal of Polymer Science 42(10):1589-1594(2024) DOI： 10.1007/s10118-024-3206-5.

摘要

A high-performance adhesive is developed based on epoxy vitrimer in a simple and green method. This epoxy-vitrimer adhesive not only exhibits multi-reusability

but also has good water resistance. This advancement provides a reliable strategy for fabricating multi-reusable adhesive in a sustainable method.

Abstract

Adhesives play an important role in modern society's production and daily life. Developing robust and sustainable adhesives remains a great challenge. Here we report a sustainable epoxy-vitrimer adhesive with high adhesive strength (about 10 MPa) and reusability (82% strength after 3 times). This adhesive can be fabricated from commercially available products through a straightforward hot-pressing method without the need of solvents. The adhesive process is also simple

requiring only 30 min at 180 °C. In addition

the vitrimer adhesive has the advantages of both erasability for reuse and excellent water resistance. This work provides a facile strategy to fabricate high-strength adhesive that ensures reusability

recyclability

low cost of raw materials

and simple processing technology. Simultaneously

it expands the range of potential applications for epoxy vitrimers.

关键词

Keywords

EpoxyVitrimerAdhesiveReusableSustainable

references

Sanghvi, M. R.; Tambare, O. H.; More, A. P. Performance of various fillers in adhesives applications: a review.Polym. Bull.2022,79, 10491−10553..

Elena, D.; Bianca, S., Adhesives: applications and Recent Advances.InTech. 2018 ..

Westerman, C. R.; McGill, B. C.; Wilker, J. J. Sustainably sourced components to generate high-strength adhesives.Nature2023,621, 306−311..

Mi, X.; Liang, N.; Xu, H.; Wu, J.; Jiang, Y.; Nie, B.; Zhang, D. Toughness and its mechanisms in epoxy resins.Prog. Mater. Sci.2022,130, 100977..

Prolongo, S. G.; del Rosario, G.; Ureña, A. Comparative study on the adhesive properties of different epoxy resins.Int. J. Adhe. Adhes.2006,26, 125−132..

Wang, J.; Sun, S.; Wu, P. A sustainable, ultratough, and ready-to-use adhesive heating patch driven by solar/electric dual energy.SusMat2021,1, 545−557..

Montarnal, D.; Capelot, M.; Tournilhac, F.; Leibler, L. Silica-like malleable materials from permanent organic networks.Science2011,334, 965−968..

Denissen, W.; Winne, J. M.; Du Prez, F. E. Vitrimers: permanent organic networks with glass-like fluidity.Chem. Sci.2016,7, 30−38..

Xu, H.; Zhang, Y.; Wang, H.; Wu, J. R. Unraveling the heterogeneity of epoxy-amine networks by introducing dynamic covalent bonds.Chinese J. Polym. Sci.2023,41, 926−932..

Wang, H.; Peng, W. S.; Wu, Q.; Zhao, Y.; Wang, S. T.; Yang, Y.; Wu, J. R.; Wang, X. L.; Zhang, R. C. Interplay of Crosslinking Structures and Segmental Dynamics in Solid-Liquid Elastomers.Chinese J. Polym. Sci.2022,40, 1297−1306..

Michal, B. T.; Spencer, E. J.; Rowan, S. J. Stimuli-responsive reversible two-level adhesion from a structurally dynamic shape-memory polymer.ACS Appl. Mater. Interfaces2016,8, 11041−11049..

Zheng, P.; McCarthy, T. J. A Surprise from 1954: Siloxane equilibration is a simple, robust, and obvious polymer self-healing mechanism.J. Am. Chem. Soc.2012,134, 2024−2027..

Ji, F.; Liu, X.; Sheng, D.; Yang, Y. Epoxy-vitrimer composites based on exchangeable aromatic disulfide bonds: reprocessibility, adhesive, multi-shape memory effect.Polymer2020,197, 122514..

Obadia, M. M.; Mudraboyina, B. P.; Serghei, A.; Montarnal, D.; Drockenmuller, E. Reprocessing and recycling of highly cross-linked ion-conducting networks through transalkylation exchanges of C–N bonds.J. Am. Chem. Soc.2015,137, 6078−6083..

Lai, J. C.; Mei, J. F.; Jia, X. Y.; Li, C. H.; You, X. Z.; Bao, Z. A stiff and healable polymer based on dynamic-covalent boroxine bonds.Adv. Mater.2016,28, 8277−8282..

Wang, S.; Liu, Z.; Zhang, L.; Guo, Y.; Song, J.; Lou, J.; Guan, Q.; He, C.; You, Z. Strong, detachable, and self-healing dynamic crosslinked hot melt polyurethane adhesive.Mater. Chem. Front.2019,3, 1833−1839..

Yang, Y.; Pei, Z.; Li, Z.; Wei, Y.; Ji, Y. Making and remaking dynamic 3D structures by shining light on flat liquid crystalline vitrimer films without a mold.J. Am. Chem. Soc.2016,138, 2118−2121..

Yang, Y.; Wang, H.; Zhang, S.; Wei, Y.; He, X.; Wang, J.; Zhang, Y.; Ji, Y. Vitrimer-based soft actuators with multiple responsiveness and self-healing ability triggered by multiple stimuli.Matter2021,4, 3354−3365..

Luo, J.; Demchuk, Z.; Zhao, X.; Saito, T.; Tian, M.; Sokolov, A. P.; Cao, P. F. Elastic vitrimers: beyond thermoplastic and thermoset elastomers.Matter2022,5, 1391−1422..

Zheng, N.; Fang, Z.; Zou, W.; Zhao, Q.; Xie, T. Thermoset shape-memory polyurethane with intrinsic plasticity enabled by transcarbamoylation.Angew. Chem. Int. Ed.2016,55, 11421−11425..

Aubert, J. H. Note: Thermally removable epoxy adhesives incorporating thermally reversible diels-alder adducts.J. Adhesion2003,79, 609−616..

Zhang, S.; Liu, T.; Hao, C.; Wang, L.; Han, J.; Liu, H.; Zhang, J. Preparation of a lignin-based vitrimer material and its potential use for recoverable adhesives.Green Chem.2018,20, 2995−3000..

Zhao, S.; Abu-Omar, M. M. Catechol-mediated glycidylation toward epoxy vitrimers/polymers with tunable properties.Macromolecules2019,52, 3646−3654..

Santiago, D.; Guzmán, D.; Padilla, J.; Verdugo, P.; De la Flor, S.; Serra, À. Recyclable and reprocessable epoxy vitrimer adhesives.ACS Appl. Polym. Mater.2023,5, 2006−2015..

Zhou, Y.; Zeng, G.; Zhang, F.; Li, K.; Li, X.; Luo, J.; Li, J.; Li, J. Design of tough, strong and recyclable plant protein-based adhesiveviadynamic covalent crosslinking chemistry.Chem. Eng. J.2023,460, 141774..

Moreno, A.; Morsali, M.; Sipponen, M. H. Catalyst-free synthesis of lignin vitrimers with tunable mechanical properties: circular polymers and recoverable adhesives.ACS Appl. Mater. Interfaces2021,13, 57952−57961..

Sun, Y.; Wang, M.; Wang, Z.; Mao, Y.; Jin, L.; Zhang, K.; Xia, Y.; Gao, H. Amine-cured glycidyl esters as dual dynamic epoxy vitrimers.Macromolecules2022,55, 523−534..

Sun, P.; Li, Y.; Qin, B.; Xu, J. F.; Zhang, X. Super strong and multi-reusable supramolecular epoxy hot melt adhesives.ACS Mater. Lett.2021,3, 1003−1009..

Shi, Q.; Yu, K.; Kuang, X.; Mu, X.; Dunn, C. K.; Dunn, M. L.; Wang, T.; Jerry Qi, H. Recyclable 3D printing of vitrimer epoxy.Mater. Horiz.2017,4, 598−607..

Zheng, N.; Xu, Y.; Zhao, Q.; Xie, T. Dynamic covalent polymer networks: a molecular platform for designing functions beyond chemical recycling and self-healing.Chem. Rev.2021,121, 1716−1745..

Vidil, T.; Tournilhac, F.; Musso, S.; Robisson, A.; Leibler, L. Control of reactions and network structures of epoxy thermosets.Prog. Polym. Sci.2016,62, 126−179..

Kloxin, C. J.; Bowman, C. N. Covalent adaptable networks: smart, reconfigurable and responsive network systems.Chem. Soc. Rev.2013,42, 7161−7173..

Yang, Y.; Terentjev, E. M.; Zhang, Y.; Chen, Q.; Zhao, Y.; Wei, Y.; Ji, Y. Reprocessable thermoset soft actuators.Angew. Chem. Int. Ed.2019,58, 17474−17479..

Yang, Y.; Terentjev, E. M.; Wei, Y.; Ji, Y. Solvent-assisted programming of flat polymer sheets into reconfigurable and self-healing 3D structures.Nat. Commun.2018,9, 1906..

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