A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer

Yu-Ting Wang; Huan Liang; Yen Wei; Jian-Long Wang; Xiang-Ming He; Yang Yang

doi:10.1007/s10118-024-3206-5

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A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer

RESEARCH ARTICLE | Updated：2024-09-23

- A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer
- Chinese Journal of Polymer Science Vol. 42, Issue 10, Pages: 1589-1594(2024)
- Affiliations：
  
  a.Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China
  b.The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China
- Author bio：
  
  yangyang86@tsinghua.edu.cn
- Funds：
- DOI：10.1007/s10118-024-3206-5
  CLC：
- Received：20 May 2024，
  
  Revised：2024-07-16，
  
  Accepted：18 July 2024，
  
  Online First：28 August 2024，
  
  Published：01 October 2024
- Accepted：
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Wang, Y. T.; Liang, H.; Wei, Y.; Wang, J. L.; He, X. M.; Yang, Y. A simple-prepared and multi-reusable adhesive based on epoxy vitrimer. Chinese J. Polym. Sci. 2024, 42, 1589–1594

Yu-Ting Wang, Huan Liang, Yen Wei, et al. A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer[J]. Chinese Journal of Polymer Science, 2024, 42(10): 1589-1594.
Wang, Y. T.; Liang, H.; Wei, Y.; Wang, J. L.; He, X. M.; Yang, Y. A simple-prepared and multi-reusable adhesive based on epoxy vitrimer. Chinese J. Polym. Sci. 2024, 42, 1589–1594 DOI： 10.1007/s10118-024-3206-5.

Yu-Ting Wang, Huan Liang, Yen Wei, et al. A Simple-Prepared and Multi-Reusable Adhesive Based on Epoxy Vitrimer[J]. Chinese Journal of Polymer Science, 2024, 42(10): 1589-1594. DOI： 10.1007/s10118-024-3206-5.

摘要

A high-performance adhesive is developed based on epoxy vitrimer in a simple and green method. This epoxy-vitrimer adhesive not only exhibits multi-reusability

but also has good water resistance. This advancement provides a reliable strategy for fabricating multi-reusable adhesive in a sustainable method.

Abstract

Adhesives play an important role in modern society's production and daily life. Developing robust and sustainable adhesives remains a great challenge. Here we report a sustainable epoxy-vitrimer adhesive with high adhesive strength (about 10 MPa) and reusability (82% strength after 3 times). This adhesive can be fabricated from commercially available products through a straightforward hot-pressing method without the need of solvents. The adhesive process is also simple

requiring only 30 min at 180 °C. In addition

the vitrimer adhesive has the advantages of both erasability for reuse and excellent water resistance. This work provides a facile strategy to fabricate high-strength adhesive that ensures reusability

recyclability

low cost of raw materials

and simple processing technology. Simultaneously

it expands the range of potential applications for epoxy vitrimers.

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references

Sanghvi, M. R.; Tambare, O. H.; More, A. P. Performance of various fillers in adhesives applications: a review. Polym. Bull. 2022 , 79 , 10491−10553..

Elena, D.; Bianca, S., Adhesives: applications and Recent Advances. InTech . 2018 ..

Westerman, C. R.; McGill, B. C.; Wilker, J. J. Sustainably sourced components to generate high-strength adhesives. Nature 2023 , 621 , 306−311..

Mi, X.; Liang, N.; Xu, H.; Wu, J.; Jiang, Y.; Nie, B.; Zhang, D. Toughness and its mechanisms in epoxy resins. Prog. Mater. Sci. 2022 , 130 , 100977..

Prolongo, S. G.; del Rosario, G.; Ureña, A. Comparative study on the adhesive properties of different epoxy resins. Int. J. Adhe. Adhes. 2006 , 26 , 125−132..

Wang, J.; Sun, S.; Wu, P. A sustainable, ultratough, and ready-to-use adhesive heating patch driven by solar/electric dual energy. SusMat 2021 , 1 , 545−557..

Montarnal, D.; Capelot, M.; Tournilhac, F.; Leibler, L. Silica-like malleable materials from permanent organic networks. Science 2011 , 334 , 965−968..

Denissen, W.; Winne, J. M.; Du Prez, F. E. Vitrimers: permanent organic networks with glass-like fluidity. Chem. Sci. 2016 , 7 , 30−38..

Xu, H.; Zhang, Y.; Wang, H.; Wu, J. R. Unraveling the heterogeneity of epoxy-amine networks by introducing dynamic covalent bonds. Chinese J. Polym. Sci. 2023 , 41 , 926−932..

Wang, H.; Peng , W. S.; Wu, Q.; Zhao, Y.; Wang, S. T.; Yang, Y.; Wu, J. R.; Wang, X. L.; Zhang, R. C. Interplay of Crosslinking Structures and Segmental Dynamics in Solid-Liquid Elastomers. Chinese J. Polym. Sci. 2022 , 40 , 1297−1306..

Michal, B. T.; Spencer, E. J.; Rowan, S. J. Stimuli-responsive reversible two-level adhesion from a structurally dynamic shape-memory polymer. ACS Appl. Mater. Interfaces 2016 , 8 , 11041−11049..

Zheng, P.; McCarthy, T. J. A Surprise from 1954: Siloxane equilibration is a simple, robust, and obvious polymer self-healing mechanism. J. Am. Chem. Soc. 2012 , 134 , 2024−2027..

Ji, F.; Liu, X.; Sheng, D.; Yang, Y. Epoxy-vitrimer composites based on exchangeable aromatic disulfide bonds: reprocessibility, adhesive, multi-shape memory effect. Polymer 2020 , 197 , 122514..

Obadia, M. M.; Mudraboyina, B. P.; Serghei, A.; Montarnal, D.; Drockenmuller, E. Reprocessing and recycling of highly cross-linked ion-conducting networks through transalkylation exchanges of C–N bonds. J. Am. Chem. Soc. 2015 , 137 , 6078−6083..

Lai, J. C.; Mei, J. F.; Jia, X. Y.; Li, C. H.; You, X. Z.; Bao, Z. A stiff and healable polymer based on dynamic-covalent boroxine bonds. Adv. Mater. 2016 , 28 , 8277−8282..

Wang, S.; Liu, Z.; Zhang, L.; Guo, Y.; Song, J.; Lou, J.; Guan, Q.; He, C.; You, Z. Strong, detachable, and self-healing dynamic crosslinked hot melt polyurethane adhesive. Mater. Chem. Front. 2019 , 3 , 1833−1839..

Yang, Y.; Pei, Z.; Li, Z.; Wei, Y.; Ji, Y. Making and remaking dynamic 3D structures by shining light on flat liquid crystalline vitrimer films without a mold. J. Am. Chem. Soc. 2016 , 138 , 2118−2121..

Yang, Y.; Wang, H.; Zhang, S.; Wei, Y.; He, X.; Wang, J.; Zhang, Y.; Ji, Y. Vitrimer-based soft actuators with multiple responsiveness and self-healing ability triggered by multiple stimuli. Matter 2021 , 4 , 3354−3365..

Luo, J.; Demchuk, Z.; Zhao, X.; Saito, T.; Tian, M.; Sokolov, A. P.; Cao, P. F. Elastic vitrimers: beyond thermoplastic and thermoset elastomers. Matter 2022 , 5 , 1391−1422..

Zheng, N.; Fang, Z.; Zou, W.; Zhao, Q.; Xie, T. Thermoset shape-memory polyurethane with intrinsic plasticity enabled by transcarbamoylation. Angew. Chem. Int. Ed. 2016 , 55 , 11421−11425..

Aubert, J. H. Note: Thermally removable epoxy adhesives incorporating thermally reversible diels-alder adducts. J. Adhesion 2003 , 79 , 609−616..

Zhang, S.; Liu, T.; Hao, C.; Wang, L.; Han, J.; Liu, H.; Zhang, J. Preparation of a lignin-based vitrimer material and its potential use for recoverable adhesives. Green Chem. 2018 , 20 , 2995−3000..

Zhao, S.; Abu-Omar, M. M. Catechol-mediated glycidylation toward epoxy vitrimers/polymers with tunable properties. Macromolecules 2019 , 52 , 3646−3654..

Santiago, D.; Guzmán, D.; Padilla, J.; Verdugo, P.; De la Flor, S.; Serra, À. Recyclable and reprocessable epoxy vitrimer adhesives. ACS Appl. Polym. Mater. 2023 , 5 , 2006−2015..

Zhou, Y.; Zeng, G.; Zhang, F.; Li, K.; Li, X.; Luo, J.; Li , J.; Li, J. Design of tough, strong and recyclable plant protein-based adhesive via dynamic covalent crosslinking chemistry. Chem. Eng. J. 2023 , 460 , 141774..

Moreno, A.; Morsali, M.; Sipponen, M. H. Catalyst-free synthesis of lignin vitrimers with tunable mechanical properties: circular polymers and recoverable adhesives. ACS Appl. Mater. Interfaces 2021 , 13 , 57952−57961..

Sun, Y.; Wang, M.; Wang, Z.; Mao, Y.; Jin, L.; Zhang, K.; Xia, Y.; Gao, H. Amine-cured glycidyl esters as dual dynamic epoxy vitrimers. Macromolecules 2022 , 55 , 523−534..

Sun, P.; Li, Y.; Qin, B.; Xu, J. F.; Zhang, X. Super strong and multi-reusable supramolecular epoxy hot melt adhesives. ACS Mater. Lett. 2021 , 3 , 1003−1009..

Shi, Q.; Yu, K.; Kuang, X.; Mu, X.; Dunn, C. K.; Dunn, M. L.; Wang, T.; Jerry Qi, H. Recyclable 3D printing of vitrimer epoxy. Mater. Horiz. 2017 , 4 , 598−607..

Zheng, N.; Xu, Y.; Zhao, Q.; Xie, T. Dynamic covalent polymer networks: a molecular platform for desi gning functions beyond chemical recycling and self-healing. Chem. Rev. 2021 , 121 , 1716−1745..

Vidil, T.; Tournilhac, F.; Musso, S.; Robisson, A.; Leibler, L. Control of reactions and network structures of epoxy thermosets. Prog. Polym. Sci. 2016 , 62 , 126−179..

Kloxin, C. J.; Bowman, C. N. Covalent adaptable networks: smart, reconfigurable and responsive network systems. Chem. Soc. Rev. 2013 , 42 , 7161−7173..

Yang, Y.; Terentjev, E. M.; Zhang, Y.; Chen, Q.; Zhao, Y.; Wei, Y.; Ji, Y. Reprocessable thermoset soft actuators. Angew. Chem. Int. Ed. 2019 , 58 , 17474−17479..

Yang, Y.; Terentjev, E. M.; Wei, Y.; Ji, Y. Solvent-assisted programming of flat polymer sheets into reconfigurable and self-healing 3D structures. Nat. Commun. 2018 , 9 , 1906..

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