Polyelectrolytes of Inorganic Polyoxometalates: Prospecting New Charged Polymers for Advanced Applications

De-Yin Wang; Zhuo-Qun Lu; Wei Wang

doi:10.1007/s10118-024-3126-4

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Polyelectrolytes of Inorganic Polyoxometalates: Prospecting New Charged Polymers for Advanced Applications

PERSPECTIVE | Updated：2024-08-27

- Polyelectrolytes of Inorganic Polyoxometalates: Prospecting New Charged Polymers for Advanced Applications
- Chinese Journal of Polymer Science Vol. 42, Issue 9, Pages: 1254-1269(2024)
- Affiliations：
  
  a.College of Medical, Linyi University, Linyi 276000, China
  b.Center for Synthetic Soft Materials, Key Laboratory of Functional Polymer Materials of the Ministry of Education, Institute of Polymer Chemistry, Nankai University, Tianjin 300071, China
- Author bio：
  
  zqlu@mail.nankai.edu.cn (Z.Q. L.)
  weiwang@nankai.edu.cn (W.W.)
- Funds：
- DOI：10.1007/s10118-024-3126-4
  CLC：
- Published：01 September 2024，
  
  Published Online：20 April 2024，
  
  Received：25 January 2024，
  
  Revised：02 March 2024，
  
  Accepted：18 March 2024
- Accepted：
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Wang, D. Y.; Lu, Z. Q.; Wang, W. Polyelectrolytes of inorganic polyoxometalates: prospecting new charged polymers for advanced applications. Chinese J. Polym. Sci. 2024, 42, 1254–1269

De-Yin Wang, Zhuo-Qun Lu, Wei Wang. Polyelectrolytes of Inorganic Polyoxometalates: Prospecting New Charged Polymers for Advanced Applications. [J]. Chinese Journal of Polymer Science 42(9):1254-1269(2024)
Wang, D. Y.; Lu, Z. Q.; Wang, W. Polyelectrolytes of inorganic polyoxometalates: prospecting new charged polymers for advanced applications. Chinese J. Polym. Sci. 2024, 42, 1254–1269 DOI： 10.1007/s10118-024-3126-4.

De-Yin Wang, Zhuo-Qun Lu, Wei Wang. Polyelectrolytes of Inorganic Polyoxometalates: Prospecting New Charged Polymers for Advanced Applications. [J]. Chinese Journal of Polymer Science 42(9):1254-1269(2024) DOI： 10.1007/s10118-024-3126-4.

摘要

This perspective summarizes the synthesis methods of poly(polyoxometalate)s as a kind of new charged polymers/polyelectrolytes

as well as their properties and functions

while also focusing on their advanced application areas.

Abstract

Polyelectrolytes are charged polymers comprising macromolecules in which substantial portions of the constituent units contain cationic (

e.g.

pyridinium

ammonium) or anionic (

e.g.

sulfonate

carboxylate) groups

which possess special functions from the features of counterions

such as dissociation to charged species

mechanical stability

phase behavior

etc

. Therefore

functional polyelectrolytes have been widely applied in many fields. In this perspective

we present some progresses in the studies of poly(polyoxometalate)s

denoted as poly(POM)s

as a kind of new charged polymers/polyelectrolytes

by covalent bonding between the inorganic polyoxometalate (POM) clusters and the organic polymer chains. According to the distinct positions of POMs in polymer chain and functions of poly(POM)s

they are divided into the following four categories: crosslinked poly(POM); side-chain poly(POM); backbon

e poly(POM)

including poly(POM)-conjugated polymer hybrid and block poly(POM)-polymer; and POM-based covalent organic framework (PCOF). This perspective introduces the synthesis methods of poly(POM) polyelectrolytes and their macromolecular and aggregate structural characteristics

while also focusing on their properties and functions. Their application areas include catalysis

thermal resistance

optical functions

fuel cells and batteries

etc

关键词

Keywords

Charged polymerPolyelectrolytePolyoxometalatePoly(polyoxometalate)Covalent organic framework

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