The Role of Renewable Protocatechol Acid in Epoxy Coating Modification: Significantly Improved Antibacterial and Adhesive Properties

Ming-Xuan Chen; Jin-Yue Dai; Li-Yue Zhang; Shuai-Peng Wang; Jing-Kai Liu; Yong-Gang Wu; Xin-Wu Ba; Xiao-Qing Liu

doi:10.1007/s10118-023-3029-9

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The Role of Renewable Protocatechol Acid in Epoxy Coating Modification: Significantly Improved Antibacterial and Adhesive Properties

RESEARCH ARTICLE | Updated：2023-12-26

- The Role of Renewable Protocatechol Acid in Epoxy Coating Modification: Significantly Improved Antibacterial and Adhesive Properties
- Chinese Journal of Polymer Science Vol. 42, Issue 1, Pages: 63-72(2024)
- Affiliations：
  
  a.School of Chemistry and Materials Science, Hebei University, Baoding 071000, China
  b.Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  c.Key Laboratory of Marine Materials and Related Technologies, Chinese Academy of Sciences, Ningbo 315201, China
- Author bio：
  
  daijinyue@nimte.ac.cn (J.Y.D.)
  baxw@hbu.edu.cn (X.W.B.)
  liuxq@nimte.ac.cn (X.Q.L.)
- Funds：
- DOI：10.1007/s10118-023-3029-9
  CLC：
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Chen, M. X.; Dai, J. Y.; Zhang, L. Y.; Wang, S. P.; Liu, J. K.; Wu, Y. G.; Ba, X. W.; Liu, X. Q. The role of renewable protocatechol acid in epoxy coating modification: significantly improved antibacterial and adhesive properties. Chinese J. Polym. Sci. 2024, 42, 63–72

Ming-Xuan Chen, Jin-Yue Dai, Li-Yue Zhang, et al. The Role of Renewable Protocatechol Acid in Epoxy Coating Modification: Significantly Improved Antibacterial and Adhesive Properties. [J]. Chinese Journal of Polymer Science 42(1):63-72(2024)
Chen, M. X.; Dai, J. Y.; Zhang, L. Y.; Wang, S. P.; Liu, J. K.; Wu, Y. G.; Ba, X. W.; Liu, X. Q. The role of renewable protocatechol acid in epoxy coating modification: significantly improved antibacterial and adhesive properties. Chinese J. Polym. Sci. 2024, 42, 63–72 DOI： 10.1007/s10118-023-3029-9.

Ming-Xuan Chen, Jin-Yue Dai, Li-Yue Zhang, et al. The Role of Renewable Protocatechol Acid in Epoxy Coating Modification: Significantly Improved Antibacterial and Adhesive Properties. [J]. Chinese Journal of Polymer Science 42(1):63-72(2024) DOI： 10.1007/s10118-023-3029-9.

摘要

A multi-functional epoxy coating was prepared by using protocatechinic acid (PCA) as raw material in this paper, reacting with ethylene glycol diglycidyl ether (EGDE) by one-step method and curing with isophorone diamine (IPDA). It demonstrated outstanding adhesion and antibacterial activity, the highest adhesion was 13.60 MPa, and the highest antibacterial rate was 100%.

Abstract

It is of great significance to design epoxy coatings with superior antibacterial properties and high adhesive properties, as well as excellent processing, superior durability, and high transparency. However, it is still a challenge because of the common complex design and synthesis. Herein, the bio-based monomer protocatechuic acid (PCA) was used as raw material, the catechol structure with high bonding and antibacterial properties was introduced into the flexible alkane segment of ethylene glycol diglycidyl ether (EGDE) through an efficient, and green method, and it was cured with isophorone diamine (IPDA) to prepare corresponding thermosets. The cured resins exhibited excellent all-around qualities, particularly in bonding and antibacterial. When 30% PCA was added to pure epoxy resin, the adhesion between substrate and coating increased from 4.40 MPa to 13.60 MPa and the antibacterial rate of coating against ,E. coli, and ,S. aureus, could approach 100%. All of this is due to the fact that the catechol structure present in PCA has the ability to interact with various substrates and alter the permeability of bacterial cell membranes. The architecture of this method offers a fresh approach to dealing with the issues of challenging raw material selection and complex synthesis techniques.

关键词

Keywords

Epoxy coatingsThermosetsCatechol structureAntibacterialHigh adhesion

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