Functionalized Hyperbranched Aliphatic Polyester Polyols: Synthesis, Properties and Applications

Aleksei Maksimov; Gennadii Kutyrev

doi:10.1007/s10118-022-2823-0

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Functionalized Hyperbranched Aliphatic Polyester Polyols: Synthesis, Properties and Applications

REVIEW | Updated：2022-11-16

- Functionalized Hyperbranched Aliphatic Polyester Polyols: Synthesis, Properties and Applications
- Chinese Journal of Polymer Science Vol. 40, Issue 12, Pages: 1567-1585(2022)
- Affiliations：
  
  1.Kazan National Research Technological University, Department of General Chemical Technologies, Kazan 420015, Russia
- Author bio：
  
  c6u92@yandex.ru
- Funds：
- DOI：10.1007/s10118-022-2823-0
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Aleksei Maksimov, Gennadii Kutyrev. Functionalized Hyperbranched Aliphatic Polyester Polyols: Synthesis, Properties and Applications. [J]. Chinese Journal of Polymer Science 40(12):1567-1585(2022)
DOI：

Aleksei Maksimov, Gennadii Kutyrev. Functionalized Hyperbranched Aliphatic Polyester Polyols: Synthesis, Properties and Applications. [J]. Chinese Journal of Polymer Science 40(12):1567-1585(2022) DOI： 10.1007/s10118-022-2823-0.

摘要

Functionalized hyperbranched aliphatic polyesters have a spatially unloaded core (ethoxylated pentaerythritol, orange color) and a shell of branched dendrons (monomer 2,2-dihydroxypropanoic acid, yellow color), in which terminal oxygen-, nitrogen-, silicon-, sulfur- and organophosphorus functional fragments are predominantly located in the surface layer (red color).

Abstract

Recently, hyperbranched polymers (HBPs), which differ significantly in structure and properties from linear, cross-linked and branched analogs, have become increasingly important. HBP have a spatial unloaded core and a shell of branched monomer units (dendrons), in which functional groups are predominantly located in the surface layer. The size of macromolecules ranges from 2 nm to 100 nm. Currently, there are a fairly large number of publications in the literature devoted to the modification of hyperbranched polyester polyols with various functional groups and the assessment of the potential for their use. However, there are no review articles on this topic in recent years. In this regard, it is relevant to generalize the latest achievements in the field of synthesis, properties and application of hyperbranched polyester polyols with terminal oxygen, nitrogen, silicon, sulfur and organophosphorus fragments. The advantage of hyperbranched polyester polyols of the Boltorn H series is their industrial availability, biodegradability, nanoscale, non-toxicity and high solubility in various polar solvents due to short monomer units, as well as the presence of reactive terminal hydroxyl groups. Functionalization of hyperbranched polyester polyols at hydroxyl groups is mainly carried out by addition of acid anhydrides, iso(thio)cyanates, alkenes, lactides, lactones, lactams, epoxy compounds or reactions with halogenated compounds (alkyl halides, acid chlorides). In some cases, for the functionalization of polyester polyols special linkers are used, such as acid chlorides of unsaturated or dicarboxylic acids, diisocyanates,etc,., which provide covalent bonding of the hyperbranched polymer with the target functional group. The obtained derivatives of hyperbranched polyesters are widely used in such areas as biomedicine, pharmacy, paints and varnishes, they are also used as catalysts, membranes, multifunctional coatings, plasticizers and polymer stabilizers.

关键词

Keywords

Hyperbranched polymersHyperbranched polyester polyolsCurable coatingsTargeted drug deliveryMembranes

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