Dipolar Glass Polymers for Capacitive Energy Storage at Room Temperatures and Elevated Temperatures

Wen-Han Xu; Ya-Dong Tang; Hong-Yan Yao; Yun-He Zhang

doi:10.1007/s10118-022-2728-y

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Dipolar Glass Polymers for Capacitive Energy Storage at Room Temperatures and Elevated Temperatures

REVIEW | Updated：2022-06-22

- Dipolar Glass Polymers for Capacitive Energy Storage at Room Temperatures and Elevated Temperatures
- Chinese Journal of Polymer Science Vol. 40, Issue 7, Pages: 711-725(2022)
- Affiliations：
  
  1.National and Local Joint Engineering Laboratory for Synthetic Technology of High-Performance Polymer, Jilin University, Changchun 130012, China
- Author bio：
  
  zhangyunhe@jlu.edu.cn
- Funds：
- DOI：10.1007/s10118-022-2728-y
  CLC：
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Wen-Han Xu, Ya-Dong Tang, Hong-Yan Yao, et al. Dipolar Glass Polymers for Capacitive Energy Storage at Room Temperatures and Elevated Temperatures. [J]. Chinese Journal of Polymer Science 40(7):711-725(2022)
DOI：

Wen-Han Xu, Ya-Dong Tang, Hong-Yan Yao, et al. Dipolar Glass Polymers for Capacitive Energy Storage at Room Temperatures and Elevated Temperatures. [J]. Chinese Journal of Polymer Science 40(7):711-725(2022) DOI： 10.1007/s10118-022-2728-y.

摘要

Dipolar glass polymers exhibit outstanding dielectric properties and energy storage performances through enhanced dipolar polarization provided by free rotation of dipoles. Due to the steric hindrance of main-chain type dipoles, the side-chain type dipoles will become an effective route to explore high performance dipolar glass polymers.

Abstract

Dielectric polymers are the materials of choice for high energy density film capacitors. The increasing demand for advanced electrical systems requires dielectric polymers to operate efficiently under extreme conditions, especially at elevated temperatures. However, the low permittivity and relatively low operating temperature of dielectric polymers limit the high-temperature capacitive energy storage applications. Fortunately, dipolar glass polymers are demonstrated as the preferred materials to achieve high dielectric constant, low dielectric loss and high energy density at elevated temperatures. In this review, we critically elaborate on the recent progress of dipolar glass polymers based on orientational polarization from molecular engineering. In addition, the general design considerations and various dipole moment entities of dipolar glass polymers are described in detail. High dipolar moment, high dipole density and rotation freedom of dipoles are essential for dipolar glass polymers to gain superior dielectric and energy storage properties. Challenges and future opportunities for dipolar glass polymers towards high-temperature energy storage applications are also provided.

关键词

Keywords

Dipolar glass polymersOrientational polarizationCapacitive energy storageDielectric constantHigh-temperature

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