Hypercrosslinking Polymers Fabricated from Divinyl Benzene <italic style="font-style: italic">via</italic> Friedel-Crafts Addition Polymerization

Zheng-Yu Duan; Yan-Yan Wang; Qi-Wei Pan; Yun-Feng Xie; Zhi-Yong Chen

doi:10.1007/s10118-022-2667-7

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Hypercrosslinking Polymers Fabricated from Divinyl Benzene via Friedel-Crafts Addition Polymerization

RESEARCH ARTICLE | Updated：2022-03-23

- Hypercrosslinking Polymers Fabricated from Divinyl Benzene via Friedel-Crafts Addition Polymerization
- Chinese Journal of Polymer Science Vol. 40, Issue 3, Pages: 310-320(2022)
- Affiliations：
  
  a.Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, School of Chemistry and Chemical Engineering; University of Jinan, Jinan 250022, China
  b.Nutrition & Health Research Institute, COFCO Corporation, Beijing Key Laboratory of Nutrition & Health and Food Safety, Beijing 102209, China
- Author bio：
  
  chm_panqw@ujn.edu.cn (Q.W.P.)
  xieyunfeng@cofco.com (Y.F.X.)
  chm_chenzy@ujn.edu.cn (Z.Y.C.)
- Funds：
- DOI：10.1007/s10118-022-2667-7
  CLC：
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Zheng-Yu Duan, Yan-Yan Wang, Qi-Wei Pan, et al. Hypercrosslinking Polymers Fabricated from Divinyl Benzene via Friedel-Crafts Addition Polymerization. [J]. Chinese Journal of Polymer Science 40(3):310-320(2022)
DOI：

Zheng-Yu Duan, Yan-Yan Wang, Qi-Wei Pan, et al. Hypercrosslinking Polymers Fabricated from Divinyl Benzene via Friedel-Crafts Addition Polymerization. [J]. Chinese Journal of Polymer Science 40(3):310-320(2022) DOI： 10.1007/s10118-022-2667-7.

摘要

Abstract

Microporous organic polymers with high surface area are widely used in many applications. Among them, hypercrosslinked polymers have been extensively concerned because of their simple processes and low-cost reagents. However, due to most state-of-the-art strategies for HCPs based on condensation reactions, the release of small molecules such as hydrochloric acid and methanol involved in such strategies brings about new hazards to environment. Herein, we propose a method of fabrication of hypercrosslinked polymers ,via, self-addition polymerization of divinyl benzene and its crosslinking with polar aromatic molecules. The hypercrosslinked polyDVB-based products are demonstrated by Friedel-Crafts addition reaction of double bonds on DVB that can connect adjacent phenyl rings of aromatic molecules to form the crosslinked networks. The HCPDVB-CB obtained in 1-chlorobutane as solvent has a high micropore content and displays high surface area up to 931 m,2,/g. Following this finding, DVB is used as a novel external crosslinker for knitting polar aromatic molecules. When L-phenylalanine and bisphenol A are used as the aromatic units, the obtained HCP(Phe-DVB) and HCP(BPA-DVB) could reach surface area of 612 and 471 m,2,/g, and have hydrogen uptake of 0.62 wt% and 0.58 wt% at 77 K and 1.13 bar by comparison with HCPDVB-CB having hydrogen uptake of 0.30 wt%, respectively.

关键词

Keywords

Hypercrosslinked polymersDivinyl benzeneFriedel-Crafts alkylationMicroporous organic polymersGas storage

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Hypercrosslinking Polymers Fabricated from Divinyl Benzene via Friedel-Crafts Addition Polymerization

DOI：10.1007/s10118-022-2667-7

摘要

Abstract

关键词

Keywords

references