Preparation of High-performance Polyimide Fibers with Wholly Rigid Structures Containing Benzobisoxazole Moieties

Yu-Ting Fang; Feng Gan; Jie Dong; Xin Zhao; Xiu-Ting Li; Qing-Hua Zhang

doi:10.1007/s10118-022-2666-8

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Preparation of High-performance Polyimide Fibers with Wholly Rigid Structures Containing Benzobisoxazole Moieties

RESEARCH ARTICLE | Updated：2022-03-23

- Preparation of High-performance Polyimide Fibers with Wholly Rigid Structures Containing Benzobisoxazole Moieties
- Chinese Journal of Polymer Science Vol. 40, Issue 3, Pages: 280-289(2022)
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  b.School of Textile Materials and Engineering, Wuyi University, Jiangmen 529020, China
- Author bio：
  
  Lixiuting@dhu.edu.cn (X.T.L.)
  qhzhang@dhu.edu.cn (Q.H.Z.)
- Funds：
- DOI：10.1007/s10118-022-2666-8
  CLC：
Scan for full text
Yu-Ting Fang, Feng Gan, Jie Dong, et al. Preparation of High-performance Polyimide Fibers with Wholly Rigid Structures Containing Benzobisoxazole Moieties. [J]. Chinese Journal of Polymer Science 40(3):280-289(2022)
DOI：

Yu-Ting Fang, Feng Gan, Jie Dong, et al. Preparation of High-performance Polyimide Fibers with Wholly Rigid Structures Containing Benzobisoxazole Moieties. [J]. Chinese Journal of Polymer Science 40(3):280-289(2022) DOI： 10.1007/s10118-022-2666-8.

摘要

Abstract

In this work, a fully rigid coplanar symmetric heterocyclic unit was introduced into the rigid polyimide macromolecular backbone structure to prepare high-performance polyimide fibers. The novel co-polyimide (co-PI) fibers based on 3,3’,4,4’-biphenyltetracarboxylic anhydride (BPDA),p,-phenylenediamine (PDA) and 2,6-(4,4’-diaminodiphenyl) benzo[1,2-,d,:5,4-,d,'] bisoxazole (PBOA) were fabricated ,via, a two-step wet-spinning method. The effects of benzobisoxazole moiety on spinnability, aggregation structure, and mechanical properties of fibers were systematically discussed. The detailed structural analysis revealed that the well-defined aggregation structures of co-PI fibers were obtained from initial amorphous structure when post hot-drawing temperature was higher than 460 °C under proper drawing ratio, and the incorporation PBOA into BPDA-PDA structures produced more compact structural co-PI fiber than homo BPDA-PDA fiber. The BPDA-PDA/PBOA co-PI fibers exhibited optimum tensile strength and modulus of 2.65 and 103 GPa, which increased by 182% and 84% compared to the homo BPDA-PDA fiber, respectively.

关键词

Keywords

Polyimide fiberBenzobisoxazoleCo-polymerizationMicrostructureMechanical properties

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