Polyarylene Ether Nitrile and Titanium Dioxide Hybrids as Thermal Resistant Dielectrics

Ren-Bo Wei; Chen-Hao Zhan; Yang Yang; Peng-Lin He; Xiao-Bo Liu

doi:10.1007/s10118-020-2481-z

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Polyarylene Ether Nitrile and Titanium Dioxide Hybrids as Thermal Resistant Dielectrics

ARTICLE | Updated：2020-09-02

- Polyarylene Ether Nitrile and Titanium Dioxide Hybrids as Thermal Resistant Dielectrics
- Chinese Journal of Polymer Science Vol. 39, Issue 2, Pages: 211-218(2021)
- Affiliations：
  
  a.Research Branch of Advanced Functional Materials, School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 610054, China
  b.School of Chemical Engineering, Northwest University, Xi’an 710069, China
- Author bio：
  
  weirb10@uestc.edu.cn (R.B.W.)
  liuxb@uestc.edu.cn (X.B.L)
- Funds：
- DOI：10.1007/s10118-020-2481-z
  CLC：
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Ren-Bo Wei, Chen-Hao Zhan, Yang Yang, et al. Polyarylene Ether Nitrile and Titanium Dioxide Hybrids as Thermal Resistant Dielectrics. [J]. Chinese Journal of Polymer Science 39(2):211-218(2021)
DOI：

Ren-Bo Wei, Chen-Hao Zhan, Yang Yang, et al. Polyarylene Ether Nitrile and Titanium Dioxide Hybrids as Thermal Resistant Dielectrics. [J]. Chinese Journal of Polymer Science 39(2):211-218(2021) DOI： 10.1007/s10118-020-2481-z.

摘要

Abstract

With the expanding application of capacitors, thermal resistant dielectric materials are in high demand due to the increasing harsh environments where the capacitors are needed and the heat generated by the capacitors. Herein, we present polyarylene ether nitrile and titanium dioxide hybrids which can be used as thermal resistant dielectrics for these capacitors. Phthalonitrile modified titanium dioxide (TiO,2,-CN) and phthalonitrile end-capped polyarylene ether nitrile (PEN-Ph) are firstly prepared. After being cast into TiO,2,-CN/PEN nanocomposite films, these composites self-crosslink upon heating at 320 °C for 4 h, forming the polyarylene ether nitrile and titanium dioxide hybrids (TiO,2,-PEN). Improved dielectric constants which are stable from room temperature to 200 °C of these hybrids are observed, indicating the potential application of the hybrids as thermal resistant dielectrics.

关键词

Keywords

HybridTiO2Polyarylene ether nitrileThermal resistanceDielectric properties

references

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