Functionalized Copolymers of Isobutylene with Vinyl Phenol: Synthesis, Characterization, and Property

Shi-Xuan Yang; Zi-Yu Fan; Feng-Yu Zhang; Si-Hao Li; Yi-Xian Wu

doi:10.1007/s10118-019-2329-6

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Functionalized Copolymers of Isobutylene with Vinyl Phenol: Synthesis, Characterization, and Property

ARTICLE | Updated：2021-02-18

- Functionalized Copolymers of Isobutylene with Vinyl Phenol: Synthesis, Characterization, and Property
- Chinese Journal of Polymer Science Vol. 37, Issue 9, Pages: 919-929(2019)
- Affiliations：
  
  1.State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  wuyx@mail.buct.edu.cn
- Funds：
- DOI：10.1007/s10118-019-2329-6
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Shi-Xuan Yang, Zi-Yu Fan, Feng-Yu Zhang, et al. Functionalized Copolymers of Isobutylene with Vinyl Phenol: Synthesis, Characterization, and Property. [J]. Chinese Journal of Polymer Science 37(9):919-929(2019)
DOI：

Shi-Xuan Yang, Zi-Yu Fan, Feng-Yu Zhang, et al. Functionalized Copolymers of Isobutylene with Vinyl Phenol: Synthesis, Characterization, and Property. [J]. Chinese Journal of Polymer Science 37(9):919-929(2019) DOI： 10.1007/s10118-019-2329-6.

摘要

Abstract

The random copolymers of isobutylene (IB) with polar comonomers of 4-acetoxystyrene (ACS) or 4-,tert,-butoxystyrene (TBO), P(IB-,co,-ACS) and P(IB-,co,-TBO), could be successfully synthesized ,via, cationic copolymerization with FeCl,3,-based initiating system. The kinetics of the cationic copolymerization process was ,in situ, investigated by inserting a diamond probe into the reaction system by ATR-FTIR spectroscopy. The chemical structure and incorporation content of polar comonomers in the copolymers were characterized by GPC with RI/UV dual detectors and ,1,H-NMR spectroscopy. The corresponding functionalized random copolymers of IB with vinyl phenol P(IB-,co,-POH) carrying phenolic hydroxyl side groups could be further prepared ,via, the complete hydrolysis of acetoxyl side groups in P(IB-,co,-ACS) or ,tert,-butoxyl side groups in P(IB-,co,-TBO) copolymers. The functionalized P(IB-,co,-POH) copolymers became hydrophilic with water contact angle (WCA) of ,ca,. 80° for the self-assembly in hot water, compared to the hydrophobic polyisobutylene with WCA of ,ca,. 110°. The functionalized P(IB-,co,-POH) copolymers also displayed an excellent self-healing property due to the interaction of intermolecular hydrogen bonding and formation of three dimentional supramolecular networks from phenolic hydroxyl side groups. Furthermore, P(IB-,co,-POH) copolymers also provided a good matrix for the homogeneous dispersion for silica nanoparticles due to the formation of hydrogen bonding between copolymer chains and silica nanoparticles.

关键词

Keywords

Cationic polymerizationIsobutyleneCopolymersPolar monomerFunctionalized polyisobutylenes

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