Fabrication of Cu(OH)<sub>2</sub> Nanowires Blended Poly(vinylidene fluoride) Ultrafiltration Membranes for Oil-Water Separation

Ye Wang; Ting-Ting Hu; Xiao-Long Han; Yu-Qi Wang; Ji-Ding Li

doi:10.1007/s10118-018-2041-y

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Fabrication of Cu(OH)₂ Nanowires Blended Poly(vinylidene fluoride) Ultrafiltration Membranes for Oil-Water Separation

Articles | Updated：2021-02-18

- Fabrication of Cu(OH)₂ Nanowires Blended Poly(vinylidene fluoride) Ultrafiltration Membranes for Oil-Water Separation
- Chinese Journal of Polymer Science Vol. 36, Issue 5, Pages: 612-619(2018)
- Affiliations：
  
  a.School of Chemical Engineering, Northwest University, Xi'an 710069, China
  b.The State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
- Author bio：
  
  Xiao-Long Han, E-mail hanxl@nwu.edu.cn
- Funds：
- DOI：10.1007/s10118-018-2041-y
  CLC：
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Ye Wang, Ting-Ting Hu, Xiao-Long Han, et al. Fabrication of Cu(OH)₂ Nanowires Blended Poly(vinylidene fluoride) Ultrafiltration Membranes for Oil-Water Separation. [J]. Chinese Journal of Polymer Science 36(5):612-619(2018)
DOI：

Ye Wang, Ting-Ting Hu, Xiao-Long Han, et al. Fabrication of Cu(OH)₂ Nanowires Blended Poly(vinylidene fluoride) Ultrafiltration Membranes for Oil-Water Separation. [J]. Chinese Journal of Polymer Science 36(5):612-619(2018) DOI： 10.1007/s10118-018-2041-y.

摘要

Abstract

Cu(OH),2, nanowires were prepared and incorporated into poly(vinylidene fluoride) (PVDF) to fabricate Cu(OH),2,-PVDF ultrafiltration (UF) membrane ,via, immersion precipitation phase inversion process. The effect of Cu(OH),2, nanowires on the morphology of membranes was investigated by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) spectroscopy, atomic force microscopy (AFM), scanning electron microscopy (SEM) and X-ray diffraction (XRD) measurements. The results showed that all the Cu(OH),2,-PVDF membranes had wider fingerlike pore structure and better hydrophilicity, smoother surface than pristine PVDF membrane due to the incorporation of Cu(OH),2, nanowires. In addition, water flux and bovine serum albumin (BSA) rejection were also measured to investigate the filtration performance of membranes. The results indicated that all the Cu(OH),2,-PVDF membranes had high water flux, outstanding BSA rejection and excellent antifouling properties. It is worth mentioning that the optimized performance could be obtained when the Cu(OH),2, nanowires content reached 1.2 wt%. Furthermore, the membrane with 1.2 wt% Cu(OH),2, nanowires showed outstanding oil-water emulsion separation capability.

关键词

Keywords

Cu(OH)2 nanowiresPVDF UF membraneOil-Water emulsion separation

references

B. T. Low , L. Zhao , T. C. Merkel , M. Weber , D. Stolten . A parametric study of the impact of membrane materials and process operating conditions on carbon capture from humidified flue gas . J. Membr. Sci. , 2013 . 431 (6 ):139 -155 . https://www.sciencedirect.com/science/article/pii/S0376738812009246https://www.sciencedirect.com/science/article/pii/S0376738812009246, .

S. L. Liu , L. Shao , M. L. Chua , C. H. Lau , H. Wang , S. Quan . Recent progress in the design of advanced PEO-containing membranes for CO2 removal . Prog. Polym. Sci. , 2013 . 38 (7 ):1089 -1120 . DOI:10.1016/j.progpolymsci.2013.02.002http://doi.org/10.1016/j.progpolymsci.2013.02.002.

X. J. Chang , Z. X. Wang , S. Quan , Y. C. Xu , Z. X. Jiang , L. Shao . Exploring the synergetic effects of graphene oxide (GO) and polyvinylpyrrodione (PVP) on poly(vinylylidenefluoride) (PVDF) ultrafiltration membrane performance . Appl. Surf. Sci. , 2014 . 316 (1 ):537 -548 . http://www.sciencedirect.com/science/article/pii/S0169433214017322http://www.sciencedirect.com/science/article/pii/S0169433214017322, .

P. Le-Clech , V. Chen , T. A. G. Fane . Fouling in membrane bioreactors used in waste water treatment . J. Membr. Sci. , 2006 . 284 (1 ):17 -53 . https://www.sciencedirect.com/science/article/pii/S0376738806005679https://www.sciencedirect.com/science/article/pii/S0376738806005679, .

Z. H. Wang , H. R. Yu , J. F. Xia , F. F. Zhang , F. Li , Y. Z. Xia , Y. H. Li . Novel GO-blended PVDF ultrafiltration membranes . Desalination , 2012 . 299 (8 ):50 -54 . https://www.sciencedirect.com/science/article/pii/S0011916412002640https://www.sciencedirect.com/science/article/pii/S0011916412002640, .

M. A. Shannon , P. W. Bohn , M. Elimelech , J. G. Georgiadis , B. J. Marinas , A. M. Mayes . Science and technology for water purification in the coming decades . Nature , 2008 . 452 (7185 ):301 DOI:10.1038/nature06599http://doi.org/10.1038/nature06599.

H. I. Nurul , A. W. Mohammad , M. Markom , L. C. Peng . Effects of palm oil-based fatty acids on fouling of ultrafiltration membranes during the clarification of glycerin-rich solution . J Food. Eng. , 2010 . 101 (3 ):264 -272 . DOI:10.1016/j.jfoodeng.2010.07.006http://doi.org/10.1016/j.jfoodeng.2010.07.006.

N. A. Hashim , F. Liu , K. Li . A simplified method for preparation of hydrophilic PVDF membranes from an amphiphilic graft copolymer . J. Membr. Sci. , 2009 . 345 (1-2 ):134 -141 . DOI:10.1016/j.memsci.2009.08.032http://doi.org/10.1016/j.memsci.2009.08.032.

Y. Wei , H. Q. Chu , B. Z. Dong , X. Li , S. J. Xia , Z. M. Qiang . Effect of TiO2 nanowire addition on PVDF ultrafiltration membrane performance . Desalination , 2011 . 272 (1 ):90 -97 . http://www.sciencedirect.com/science/article/pii/S0011916411000245http://www.sciencedirect.com/science/article/pii/S0011916411000245, .

X. T. Zuo , S. L. Yu , X. Xu , J. Xu , R. L. Bao , X. J. Yan . New PVDF organic-inorganic membranes:the effect of SiO2 nanoparticles content on the transport performance of anion-exchange membranes . J. Membr. Sci. , 2009 . 340 (1-2 ):206 -213 . DOI:10.1016/j.memsci.2009.05.032http://doi.org/10.1016/j.memsci.2009.05.032.

S. Liang , K. Xiao , Y. H. Mo , X. Huang . A novel ZnO nanoparticle blended polyvinylidene fluoride membrane for anti-irreversible fouling . J. Membr. Sci. , 2012 . 394 -192. 394-395, 184-192 https://www.sciencedirect.com/science/article/pii/S0376738811009586https://www.sciencedirect.com/science/article/pii/S0376738811009586, .

D. X. Wang , F. Tong , P. Aerts . Application of the combined ultrafiltration and reverse osmosis for refinery wastewater reuse in Sinopec Yanshan Plant . Desalin. Water Treat , 2011 . 25 (1-3 ):133 -142 . DOI:10.5004/dwt.2011.1137http://doi.org/10.5004/dwt.2011.1137.

L. Yan , Y. S. Li , C. B. Xiang . Preparation of poly(vinylidene fluoride) (PVDF) ultrafiltration membrane modified by nano-sized alumina (Al2O3) and its antifouling research . Polymer , 2005 . 46 (18 ):7701 -7706 . DOI:10.1016/j.polymer.2005.05.155http://doi.org/10.1016/j.polymer.2005.05.155.

G. P. Wu , S. Y. Gan , L. Z. Cui , Y. Y. Xu . Preparation and characterization of PES/TiO2 composite membranes . Appl. Surf. Sci. , 2008 . 254 (21 ):7080 -7086 . DOI:10.1016/j.apsusc.2008.05.221http://doi.org/10.1016/j.apsusc.2008.05.221.

X. Huang , W. P. Wang , Y. D. Liu , H. Wang , Z. B. Zhang , W. L. Fan , L. Li . Treatment of oily waste water by PVP grafted PVDF ultrafiltration membranes . Chem. Eng. J. , 2015 . 273 421 -429 . DOI:10.1016/j.cej.2015.03.086http://doi.org/10.1016/j.cej.2015.03.086.

Y. N. Yang , P. Wang . Preparation and characterizations of a new PS/TiO2 hybrid membranes by sol-gel process . Polymer , 2006 . 47 (8 ):2683 -2688 . DOI:10.1016/j.polymer.2006.01.019http://doi.org/10.1016/j.polymer.2006.01.019.

Z. W. Xu , T. F. Wu , J. Shi , W. Wang , K. Y. Teng , X. M. Qian , M. J. Shan , H. Deng , X. Tian , C. Y. Li , F. Y. Li . Manipulating migration behavior of magnetic graphene oxide via magnetic field induced casting and phase separation toward high-performance hybrid ultrafiltration membranes . ACS Appl. Mater. Interfaces , 2016 . 8 (28 ):18418 -18429 . DOI:10.1021/acsami.6b04083http://doi.org/10.1021/acsami.6b04083.

J. G. Zhang , Z. W. Xu , W. Mai , C. Y. Min , B. M. Zhou , M. J. Shan , Y. L. Li , C. Y. Yang , Z. Wang , X. M. Qian . Improved hydrophilicity, permeability, antifouling and mechanical performance of PVDF composite ultrafiltration membranes tailored by oxidized low-dimensional carbon nanomaterials . J. Mater. Chem. A , 2013 . 1 (9 ):3101 -3111 . DOI:10.1039/c2ta01415ghttp://doi.org/10.1039/c2ta01415g.

J. G. Zhang , Z. W. Xu , M. J. Shan , B. M. Zhou , Y. L. Li , B. D. Li , J. R. Niu , X. M. Qian . Synergetic effects of oxidized carbon nanotubes and graphene oxide on fouling control and anti-fouling mechanism of polyvinylidene fluoride ultrafiltration membranes . J. Membr. Sci. , 2013 . 448 (24 ):81 -92 . https://www.sciencedirect.com/science/article/pii/S0376738813006406https://www.sciencedirect.com/science/article/pii/S0376738813006406, .

Z. W. Xu , T. F. Wu , J. Shi , K. Y. Teng , W. Wang , M. J. Ma , J. Li , X. M. Qian , C. Y. Li , J. T. Fan . Photocatalytic antifouling PVDF ultrafiltration membranes based on synergy of graphene oxide and TiO2 for water treatment . J. Membr. Sci. , 2016 . 520 281 -293 . DOI:10.1016/j.memsci.2016.07.060http://doi.org/10.1016/j.memsci.2016.07.060.

Y. Long , J. F. Hui , P. P. Wang , G. L. Xiang , B. Xu , S. Hu , W. C. Zhu , X. Q. Lü , J. Zhuang , X. Wang . Hydrogen bond nanoscale networks showing switchable transport performance . Sci. Rep. , 2012 . 2 (8 ):DOI:10.1038/srep00612http://doi.org/10.1038/srep00612 .

F. Zhang , W. B. Zhang , Z. Shi , D. Wang , J. Jin , L. Jiang . Nanowire-haired inorganic membranes with superhydrophilicity and underwater ultralow adhesive superoleophobicity for high-efficiency oil/water separation . Adv. Mater. , 2013 . 25 (30 ):4192 -4198 . DOI:10.1002/adma.201301480http://doi.org/10.1002/adma.201301480.

A. Bottino , G. Camera-Roda , G. Capannelli , S. Munari . The formation of microporous polyvinylidene difluoride membranes by phase separation . J. Membr. Sci. , 1991 . 57 (1 ):1 -20 . DOI:10.1016/S0376-7388(00)81159-Xhttp://doi.org/10.1016/S0376-7388(00)81159-X.

W. Z. Wang , C. Lan , Y. Z. Li , K. Q. Hong , G. H. Wang . A simple wet chemical route for large-scale synthesis of Cu(OH)2 nanowires . Chem. Phys. Lett. , 2002 . 366 (3 ):220 -223 . http://www.sciencedirect.com/science/article/pii/S0009261402015713http://www.sciencedirect.com/science/article/pii/S0009261402015713, .

M. Safarpour , A. Khataee , V. Vatanpour . Effect of reduced graphene oxide/TiO2 nanocomposite with different molar ratios on the performance of PVDF ultrafiltration membranes . Sep. Purif. Technol. , 2015 . 140 32 -42 . DOI:10.1016/j.seppur.2014.11.010http://doi.org/10.1016/j.seppur.2014.11.010.

C. Pagliero , M. Mattea , N. Ochoa , J. Marchese . Fouling of polymeric membranes during degumming of crude sunflower and soybean oil . J. Food. Eng. , 2007 . 78 (1 ):194 -197 . DOI:10.1016/j.jfoodeng.2005.09.015http://doi.org/10.1016/j.jfoodeng.2005.09.015.

A. B. Koltuniewicz , R. W. Field . Process factors during removal of oil-in-water emulsions with cross-flow microfiltration . Desalination , 1996 . 105 (105 ):79 -89 . https://www.sciencedirect.com/science/article/pii/0011916496000616https://www.sciencedirect.com/science/article/pii/0011916496000616, .

X. S. Yi , S. L. Yu , W. X. Shi , N. Sun , L. M. Jin , S. Wang , B. Zhang , C. Ma , L. P. Sun . The influence of important factors on ultrafiltration of oil/water emulsion using PVDF membrane modified by nano-sized TiO2/Al2O3 . Desalination , 2011 . 281 (1 ):179 -184 . http://www.sciencedirect.com/science/article/pii/S0011916411006709http://www.sciencedirect.com/science/article/pii/S0011916411006709, .

C. F. Li , Y. D. Yin , H. G. Hou , N. Y. Fan , F. L. Yuan , Y. M. Shi , Q. L. Meng . Preparation and characterization of Cu(OH)2 and CuO nanowires by the coupling route of microemulsion with homogenous precipitation . Solid State Commun. , 2010 . 150 (13 ):585 -589 . https://www.sciencedirect.com/science/article/pii/S0038109810000049https://www.sciencedirect.com/science/article/pii/S0038109810000049, .

F. Al-Hazmi , F. Alnowaiser , A. A. Al-Ghamdi , M. M. Aly , R. M. Al-Tuwirqi , F. El-Tantawy . A new large-scale synthesis of magnesium oxide nanowires:structural and antibacterial properties . Superlattice Microst. , 2012 . 52 (2 ):200 -209 . DOI:10.1016/j.spmi.2012.04.013http://doi.org/10.1016/j.spmi.2012.04.013.

J. He , X. N. Zhao , J. J. Zhu , J. Wang . Preparation of CdS nanowires by the decomposition of the complex in the presence of microwave irradiation . J. Cryst. Growth , 2002 . 240 (3 ):389 -394 . http://www.sciencedirect.com/science/article/pii/S0022024802009442http://www.sciencedirect.com/science/article/pii/S0022024802009442, .

J. Benjamin , E. Wylie-van , G. Y. Aidan , I. A. Najeh , K. Tim , M. S. Nick . Ligand-functionalised copper(Ⅱ) hydroxide for quantum dot photoluminescence quenching . J. Colloid Interfaces Sci. , 2010 . 346 (2 ):288 DOI:10.1016/j.jcis.2010.03.010http://doi.org/10.1016/j.jcis.2010.03.010.

N. Liu , D. Wu , H. X. Wu , F. Luo , J. Chen . Controllable synthesis of metal hydroxide and oxide nanostructures by ionic liquids assisted electrochemical corrosion method . Solid State Sci. , 2008 . 10 (8 ):1049 -1055 . DOI:10.1016/j.solidstatesciences.2007.11.017http://doi.org/10.1016/j.solidstatesciences.2007.11.017.

Y. Z. Sun , L. Ma , B. B. Zhou , P. Gao . Cu(OH)2 and CuO nanotube networks from hexaoxacyclooctadecane-like posnjakite microplates:Synthesis and electrochemical hydrogen storage . Int. J. Hydrogen Energ. , 2012 . 37 (3 ):2336 -2343 . DOI:10.1016/j.ijhydene.2011.10.090http://doi.org/10.1016/j.ijhydene.2011.10.090.

S. Lee , S. Park , H. Jeong , C. W. Kim , D. J. Lee , C. Jin . Effects of post-annealing treatment on the microstructural evolution and quality of Cu(OH)2 nanowires . J. Alloy Compd. , 2015 . 652 (4 ):153 -157 . https://www.researchgate.net/publication/282983636_Effects_of_post-annealing_treatment_on_the_microstructural_evolution_and_quality_of_Cu(OH)2_nanowireshttps://www.researchgate.net/publication/282983636_Effects_of_post-annealing_treatment_on_the_microstructural_evolution_and_quality_of_Cu(OH)2_nanowires, .

L. Y. Yu , Z. L. Xu , H. M. Shen , H. Yang . Preparation and characterization of PVDF-SiO2 composite hollow fiber UF membrane by sol-gel method . J. Membr. Sci. , 2009 . 337 (1 ):257 -265 . http://www.sciencedirect.com/science/article/pii/S0376738809002579http://www.sciencedirect.com/science/article/pii/S0376738809002579, .

V. Vatanpour , M. E. Yekavalangi , M. Safarpour . Preparation and characterization of nanocomposite PVDF ultrafiltration membrane embedded with nanoporous SAPO-34 to improve permeability and antifouling performance . Sep. Purif. Technol. , 2016 . 163 300 -309 . DOI:10.1016/j.seppur.2016.03.011http://doi.org/10.1016/j.seppur.2016.03.011.

L. Yan , Y. S. Li , C. B. Xiang , S. Xianda . Effect of nano-sized Al2O3-particle addition on PVDF ultrafiltration membrane performance . J. Membr. Sci. , 2006 . 276 (1 ):162 -167 . http://www.sciencedirect.com/science/article/pii/S0376738805006812http://www.sciencedirect.com/science/article/pii/S0376738805006812, .

S. Zhao , W. T. Yan , M. Q. Shi , Z. Wang , J. X. Wang , S. C. Wang . Improving permeability and antifouling performance of polyethersulfone ultrafiltration membrane by incorporation of ZnO-DMF dispersion containing nano-ZnO and polyvinylpyrrolidone . J. Membr. Sci. , 2015 . 478 105 -116 . DOI:10.1016/j.memsci.2014.12.050http://doi.org/10.1016/j.memsci.2014.12.050.

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Fabrication of Cu(OH)2 Nanowires Blended Poly(vinylidene fluoride) Ultrafiltration Membranes for Oil-Water Separation

DOI：10.1007/s10118-018-2041-y

摘要

Abstract

关键词

Keywords

references

Fabrication of Cu(OH)₂ Nanowires Blended Poly(vinylidene fluoride) Ultrafiltration Membranes for Oil-Water Separation