Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films

Wei Wan-chu; Feng Shuo; Zheng Cai-xia; Liang Guo-dong; Zhu Fang-ming

doi:10.1007/s10118-017-1884-y

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Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films

Papers | Updated：2024-11-27

- Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films
- Chinese Journal of Polymer Science Vol. 35, Issue 3, Pages: 400-406(2017)
- Affiliations：
  
  a. Guangdong Provincial Key Laboratory for High Performance Polymeric Composites, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
  b. Key Laboratory for Polymer Composite and Functional Materials of Ministry of Education, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
- Author bio：
  
  Fang-ming Zhu(祝方明), E-mail:ceszfm@mail.sysu.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1884-y
  CLC：
- Published：25 March 2017，
  
  Received：20 August 2016，
  
  Revised：20 September 2016，
  
  Accepted：28 September 2016
- Accepted：
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Wei Wan-chu, Feng Shuo, Zheng Cai-xia, et al. Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films. [J]. Chinese Journal of Polymer Science, 2017,35(3):400-406.
DOI：

Wei Wan-chu, Feng Shuo, Zheng Cai-xia, et al. Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films. [J]. Chinese Journal of Polymer Science, 2017,35(3):400-406. DOI： 10.1007/s10118-017-1884-y.

摘要

Abstract

The fluorescently labelled polymers including pyrene-labelled polystyrene (PyPS) and pyrene-labelled poly(methyl methacrylate) (PyPMMA) with narrow molecular weight distributions were synthesized by the atom transfer radical copolymerization (ATRCP) of styrene or methyl methacrylate with 1-pyrenemethyl methacrylate (PyMMA). The ultrathin PyPS and PyPMMA films with the thickness ranging from 30 nm to 400 nm supported on the quartz slides were prepared by spin-coating. The fluorescent quantum yield (QY) of the pyrene probe in the ultrathin polymer films was investigated by the photoluminescence spectrometer using an integrating sphere detector. The QY decreased with the reduction of film thickness in the sub-200 nm range.

关键词

Keywords

Pyrene-labelled polystyrenePyrene-labelled poly(methyl methacrylate)Ultrathin polymer filmsFluorescent quantum yield

references

S. Marceau, , J.H. Tortai, , J. Tillier, , N. Vourdas, , E. Gogolides, , I. Raptis, . . Beltsios, K, van Werden, K.Microelectron. Eng. , 2006 . 83 1073 .

F. Ito, , T. Kakiuchi, . . Sakano, T, Nagamura, T.Phys. Chem. Chem. Phys. , 2010 . 12 10923 DOI:10.1039/c003023fhttp://doi.org/10.1039/c003023f.

X Wan, , S. Liu, . . J. Mater. Chem. , 2011 . 21 10321 DOI:10.1039/c1jm10332fhttp://doi.org/10.1039/c1jm10332f.

J. Hu, , G. Zhang, . . Ge, Z, Liu, S.Prog. Polym. Sci. , 2014 . 39 1096 DOI:10.1016/j.progpolymsci.2013.10.006http://doi.org/10.1016/j.progpolymsci.2013.10.006.

K. Okabe, , N. Inada, , C. Gota, , Y. Harada, . . Funatsu, T, Uchiyama, S.Nat. Chem. , 2012 . 3 705 .

H Bodiguel, , C. Fretigny, . . Macromolecules , 2007 . 40 7291 DOI:10.1021/ma070460dhttp://doi.org/10.1021/ma070460d.

Y.P. Koh, , G.B Mckenna, , S.L. Simon, . . J. Polym. Sci.Part B: Polym. Phys. , 2006 . 44 3518 DOI:10.1002/(ISSN)1099-0488http://doi.org/10.1002/(ISSN)1099-0488.

Y.X Liu, , E.Q. Chen, . . Coord. Chem. Rev. , 2010 . 254 1011 DOI:10.1016/j.ccr.2010.02.017http://doi.org/10.1016/j.ccr.2010.02.017.

S.D Kim, , J.M. Torkelson, . . Macromolecules , 2002 . 35 5943 DOI:10.1021/ma0200322http://doi.org/10.1021/ma0200322.

H.Y. Lu, . . Chen, W, Russell, T.P.Macromolecules , 2009 . 42 9111 .

P.L. Clark, , Z.P. Liu, . . Zhang, J.H, Gierasch, L.M.Protein Sci. , 1996 . 5 1108 .

C.M Evans, , J.M. Torkelson, . . Polymer , 2012 . 53 6118 DOI:10.1016/j.polymer.2012.10.038http://doi.org/10.1016/j.polymer.2012.10.038.

L. Chen, , X.L. Zhuang, . . Sun, G.E, Jing, X.B.Chinese J. Polym. Sci. , 2008 . 26 455 .

C.M. Evans, . . Sandoval, R.W, Torkelson, J.M.Macromolecules , 2011 . 44 6645 .

M.K. Mundra, , C.J. Ellison, . . Behling, R.E, Torkelson, J.M.Polymer , 2006 . 47 7747 .

H Schonherr, , C.W. Frank, . . Macromolecules , 2003 . 36 1188 DOI:10.1021/ma020685ihttp://doi.org/10.1021/ma020685i.

C. Tedeschi, . . Mohwald, H, Kirstein, S.J. Am. Chem. Soc. , 2001 . 123 954 DOI:10.1021/ja0031974http://doi.org/10.1021/ja0031974.

M.K. Mundral, , C.J. Ellison, . . Rittigstein, P, Torkelson, J.M.Eur. Phys. J. Special Topics , 2007 . 141 143 DOI:10.1140/epjst/e2007-00032-0http://doi.org/10.1140/epjst/e2007-00032-0.

B Valeur, , M.N. Berberan-Santos, . . "Molecular fluorescence: principles and applications", John Wiley & Sons, New York , 2012 . p.46 .

R.F. Chen, . . Anal. Lett. , 1967 . 1 35 DOI:10.1080/00032716708051097http://doi.org/10.1080/00032716708051097.

J. Olmsted, . . J. Phys. Chem. , 1979 . 83 258 .

L. Porres, , A. Holland, , L.O. Palsson, , A.P. Monkman, . . Kemp, C, Beeby, A.J. Fluoresc. , 2006 . 16 267 DOI:10.1007/s10895-005-0054-8http://doi.org/10.1007/s10895-005-0054-8.

J.A. Forrest, , K. Dalnoki-Veress, . . Stevens, J.R, Dutcher, J.R.Phys. Rev. Lett. , 1996 . 77 2002 DOI:10.1103/PhysRevLett.77.2002http://doi.org/10.1103/PhysRevLett.77.2002.

J.L. Keddie, . . Jone, R.A.L, Cor, R.A.Europhys. Lett. , 1994 . 27 59 .

J.L. Keddie, . . Jone, R.A.L, Cor, R.A.Faraday Discuss. , 1994 . 98 219 DOI:10.1039/fd9949800219http://doi.org/10.1039/fd9949800219.

J. You, , J.A. Yoon, , J. Kim, , C.F. Huang, . . Matyjaszewski, K, Kim, E.Chem. Mater. , 2010 . 22 4426 .

F.J. Xu, , Q.J. Cai, . . Kang, E.T, Neoh, K.G.Macromolecules , 2005 . 38 1051 .

X. Lou, , R. Daussin, , S. Cuenot, , A.S. Duwez, , C. Pagnoulle, , C. Detrembleur, . . Bailly, C, Jérôme, R.Chem. Mater. , 2004 . 16 4005 .

J.Y. Hu, , M. Era, . . Elsegood, M.R.J, Yamato, T.Eur. J. Org. Chem. , 2010 . 1 72 .

C.J Ellison, , J.M. Torkelson, . . J. Polym. Sci.Part B: Polym. Phys. , 2002 . 40 2745 DOI:10.1002/(ISSN)1099-0488http://doi.org/10.1002/(ISSN)1099-0488.

K Kalyanasundaram, , J.K. Thomas, . . J. Am. Chem. Soc. , 1977 . 99 2039 DOI:10.1021/ja00449a004http://doi.org/10.1021/ja00449a004.

C.J Ellison, , J.M. Torkelson, . . Nat. Mater. , 2003 . 2 695 DOI:10.1038/nmat980http://doi.org/10.1038/nmat980.

Y. Liu, , T.P. Russell, , M.G. Samant, . . Stöhr, J, Brown, H.R.Macromolecules , 1997 . 30 7768 .

G.F. Meyers, . . DeKoven, B.M, Seitz, J.T.Langmuir , 1992 . 8 2330 .

W.E. Wallace, , D.A. Fischer, , K. Efimenko, . . Wu, W.L, Genzer, J.Macromolecules , 2001 . 34 5081 DOI:10.1021/ma002075thttp://doi.org/10.1021/ma002075t.

S. Kim, , C.B Roth, , J.M. Torkelson, . . J. Polym. Sci.Part B: Polym. Phys. , 2008 . 46 2754 DOI:10.1002/polb.v46:24http://doi.org/10.1002/polb.v46:24.

D.C Dong, , M.A. Winnik, . . Can. J. Chem. , 1984 . 62 2560 DOI:10.1139/v84-437http://doi.org/10.1139/v84-437.

K Kalyanasundaram, , J.K. Thomas, . . J. Am. Chem. Soc. , 1977 . 99 2039 DOI:10.1021/ja00449a004http://doi.org/10.1021/ja00449a004.

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