Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films

Wei Wan-chu; Feng Shuo; Zheng Cai-xia; Liang Guo-dong; Zhu Fang-ming

doi:10.1007/s10118-017-1884-y

Your Location：

Home >

Browse articles >

Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films

Papers | Updated：2024-11-27

- Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films
- Chinese Journal of Polymer Science Vol. 35, Issue 3, Pages: 400-406(2017)
- Affiliations：
  
  a. Guangdong Provincial Key Laboratory for High Performance Polymeric Composites, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
  b. Key Laboratory for Polymer Composite and Functional Materials of Ministry of Education, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
- Author bio：
  
  Fang-ming Zhu(祝方明), E-mail:ceszfm@mail.sysu.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1884-y
  CLC：
- Received：20 August 2016，
  
  Revised：2016-9-20，
  
  Accepted：28 September 2016，
  
  Published：25 March 2017
- Accepted：
Scan QR Code
Wei Wan-chu, Feng Shuo, Zheng Cai-xia, et al. Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films[J]. Chinese Journal of Polymer Science, 2017, 35(3): 400-406.
DOI：

Wei Wan-chu, Feng Shuo, Zheng Cai-xia, et al. Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films[J]. Chinese Journal of Polymer Science, 2017, 35(3): 400-406. DOI： 10.1007/s10118-017-1884-y.

摘要

Abstract

The fluorescently labelled polymers including pyrene-labelled polystyrene (PyPS) and pyrene-labelled poly(methyl methacrylate) (PyPMMA) with narrow molecular weight distributions were synthesized by the atom transfer radical copolymerization (ATRCP) of styrene or methyl methacrylate with 1-pyrenemethyl methacrylate (PyMMA). The ultrathin PyPS and PyPMMA films with the thickness ranging from 30 nm to 400 nm supported on the quartz slides were prepared by spin-coating. The fluorescent quantum yield (QY) of the pyrene probe in the ultrathin polymer films was investigated by the photoluminescence spectrometer using an integrating sphere detector. The QY decreased with the reduction of film thickness in the sub-200 nm range.

关键词

Keywords

references

S. Marceau, , J.H. Tortai, , J. Tillier, , N. Vourdas, , E. Gogolides, , I. Raptis, . . Beltsios, K, van Werden, K.Microelectron. Eng. , 2006 . 83 1073 .

F. Ito, , T. Kakiuchi, . . Sakano, T, Nagamura, T.Phys. Chem. Chem. Phys. , 2010 . 12 10923 DOI: 10.1039/c003023f http://doi.org/10.1039/c003023f .

X Wan, , S. Liu, . . J. Mater. Chem. , 2011 . 21 10321 DOI: 10.1039/c1jm10332f http://doi.org/10.1039/c1jm10332f .

J. Hu, , G. Zhang, . . Ge, Z, Liu, S.Prog. Polym. Sci. , 2014 . 39 1096 DOI: 10.1016/j.progpolymsci.2013.10.006 http://doi.org/10.1016/j.progpolymsci.2013.10.006 .

K. Okabe, , N. Inada, , C. Gota, , Y. Harada, . . Funatsu, T, Uchiyama, S.Nat. Chem. , 2012 . 3 705 .

H Bodiguel, , C. Fretigny, . . Macromolecules , 2007 . 40 7291 DOI: 10.1021/ma070460d http://doi.org/10.1021/ma070460d .

Y.P. Koh, , G.B Mckenna, , S.L. Simon, . . J. Polym. Sci.Part B: Polym. Phys. , 2006 . 44 3518 DOI: 10.1002/(ISSN)1099-0488 http://doi.org/10.1002/(ISSN)1099-0488 .

Y.X Liu, , E.Q. Chen, . . Coord. Chem. Rev. , 2010 . 254 1011 DOI: 10.1016/j.ccr.2010.02.017 http://doi.org/10.1016/j.ccr.2010.02.017 .

S.D Kim, , J.M. Torkelson, . . Macromolecules , 2002 . 35 5943 DOI: 10.1021/ma0200322 http://doi.org/10.1021/ma0200322 .

H.Y. Lu, . . Chen, W, Russell, T.P.Macromolecules , 2009 . 42 9111 .

P.L. Clark, , Z.P. Liu, . . Zhang, J.H, Gierasch, L.M.Protein Sci. , 1996 . 5 1108 .

C.M Evans, , J.M. Torkelson, . . Polymer , 2012 . 53 6118 DOI: 10.1016/j.polymer.2012.10.038 http://doi.org/10.1016/j.polymer.2012.10.038 .

L. Chen, , X.L. Zhuang, . . Sun, G.E, Jing, X.B.Chinese J. Polym. Sci. , 2008 . 26 455 .

C.M. Evans, . . Sandoval, R.W, Torkelson, J.M.Macromolecules , 2011 . 44 6645 .

M.K. Mundra, , C.J. Ellison, . . Behling, R.E, Torkelson, J.M.Polymer , 2006 . 47 7747 .

H Schonherr, , C.W. Frank, . . Macromolecules , 2003 . 36 1188 DOI: 10.1021/ma020685i http://doi.org/10.1021/ma020685i .

C. Tedeschi, . . Mohwald, H, Kirstein, S.J. Am. Chem. Soc. , 2001 . 123 954 DOI: 10.1021/ja0031974 http://doi.org/10.1021/ja0031974 .

M.K. Mundral, , C.J. Ellison, . . Rittigstein, P, Torkelson, J.M.Eur. Phys. J. Special Topics , 2007 . 141 143 DOI: 10.1140/epjst/e2007-00032-0 http://doi.org/10.1140/epjst/e2007-00032-0 .

B Valeur, , M.N. Berberan-Santos, . . "Molecular fluorescence: principles and applications", John Wiley & Sons, New York , 2012 . p.46 .

R.F. Chen, . . Anal. Lett. , 1967 . 1 35 DOI: 10.1080/00032716708051097 http://doi.org/10.1080/00032716708051097 .

J. Olmsted, . . J. Phys. Chem. , 1979 . 83 258 .

L. Porres, , A. Holland, , L.O. Palsson, , A.P. Monkman, . . Kemp, C, Beeby, A.J. Fluoresc. , 2006 . 16 267 DOI: 10.1007/s10895-005-0054-8 http://doi.org/10.1007/s10895-005-0054-8 .

J.A. Forrest, , K. Dalnoki-Veress, . . Stevens, J.R, Dutcher, J.R.Phys. Rev. Lett. , 1996 . 77 2002 DOI: 10.1103/PhysRevLett.77.2002 http://doi.org/10.1103/PhysRevLett.77.2002 .

J.L. Keddie, . . Jone, R.A.L, Cor, R.A.Europhys. Lett. , 1994 . 27 59 .

J.L. Keddie, . . Jone, R.A.L, Cor, R.A.Faraday Discuss. , 1994 . 98 219 DOI: 10.1039/fd9949800219 http://doi.org/10.1039/fd9949800219 .

J. You, , J.A. Yoon, , J. Kim, , C.F. Huang, . . Matyjaszewski, K, Kim, E.Chem. Mater. , 2010 . 22 4426 .

F.J. Xu, , Q.J. Cai, . . Kang, E.T, Neoh, K.G.Macromolecules , 2005 . 38 1051 .

X. Lou, , R. Daussin, , S. Cuenot, , A.S. Duwez, , C. Pagnoulle, , C. Detrembleur, . . Bailly, C, Jérôme, R.Chem. Mater. , 2004 . 16 4005 .

J.Y. Hu, , M. Era, . . Elsegood, M.R.J, Yamato, T.Eur. J. Org. Chem. , 2010 . 1 72 .

C.J Ellison, , J.M. Torkelson, . . J. Polym. Sci.Part B: Polym. Phys. , 2002 . 40 2745 DOI: 10.1002/(ISSN)1099-0488 http://doi.org/10.1002/(ISSN)1099-0488 .

K Kalyanasundaram, , J.K. Thomas, . . J. Am. Chem. Soc. , 1977 . 99 2039 DOI: 10.1021/ja00449a004 http://doi.org/10.1021/ja00449a004 .

C.J Ellison, , J.M. Torkelson, . . Nat. Mater. , 2003 . 2 695 DOI: 10.1038/nmat980 http://doi.org/10.1038/nmat980 .

Y. Liu, , T.P. Russell, , M.G. Samant, . . Stöhr, J, Brown, H.R.Macromolecules , 1997 . 30 7768 .

G.F. Meyers, . . DeKoven, B.M, Seitz, J.T.Langmuir , 1992 . 8 2330 .

W.E. Wallace, , D.A. Fischer, , K. Efimenko, . . Wu, W.L, Genzer, J.Macromolecules , 2001 . 34 5081 DOI: 10.1021/ma002075t http://doi.org/10.1021/ma002075t .

S. Kim, , C.B Roth, , J.M. Torkelson, . . J. Polym. Sci.Part B: Polym. Phys. , 2008 . 46 2754 DOI: 10.1002/polb.v46:24 http://doi.org/10.1002/polb.v46:24 .

D.C Dong, , M.A. Winnik, . . Can. J. Chem. , 1984 . 62 2560 DOI: 10.1139/v84-437 http://doi.org/10.1139/v84-437 .

K Kalyanasundaram, , J.K. Thomas, . . J. Am. Chem. Soc. , 1977 . 99 2039 DOI: 10.1021/ja00449a004 http://doi.org/10.1021/ja00449a004 .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Squaramide-directed Cooperative One-dimensional Assembly in Telechelic Polydimethylsiloxane for Hierarchical Network Formation

Sliding Dynamics of Ring Chain on a Rod-Coil Block Copolymer in Rotaxane

End-to-End Neuron-inspired Signal Transduction Using Organic Electrochemical Transistors

Epoxy-functionalized Cyclohexane-based Ricinoleate Plasticizer: Synthesis, Performance Evaluation, and Plasticizing Mechanism

Special Topic: Chirality in Polymers

Related Author

No data

Related Institution

No data

⁰