GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT*

WANG Wei; QIU Kunyuan; FENG Xinde

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GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT*

Papers | Updated：2021-06-21

- GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT*
- Vol. 12, Issue 2, Pages: 137-144(1994)
- Affiliations：
  
  1.   Department of Chemistry
  2.   Peking University
  3.   Beijing 100871
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WANG Wei, QIU Kunyuan, FENG Xinde. GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT*. [J]. 12(2):137-144(1994)
DOI：

WANG Wei, QIU Kunyuan, FENG Xinde. GRAFTING OF ACRYLAMIDE ONTO SURFACE OF COPOLYMERS CONTAINING P-TOLYLCARBAMOYL PENDANT GROUP INITIATED WITH CERIC SALT*. [J]. 12(2):137-144(1994) DOI：

摘要

<正> Two copolymers containing p-tolylcarbamoyl pendant group poly （MAMT-co-VAc） and poly（MAMT-co-MA） were synthesized f and the graft copolymerization of AAM onto these two func-tional copolymers films initiated with ceric salt were carried out in aqueous solution for variousperiods at 30℃. The formation of graft copolymer was verified by water absorption, ESCA andSEM photographs. Based on the results of the study of the initiation mechanism of model com-pounds and ceric salt systems, the reaction mechanism of the graft copolymerization initiated withceric salt was proposed.

Abstract

Two copolymers containing p-tolylcarbamoyl pendant group poly （MAMT-co-VAc） and poly（MAMT-co-MA） were synthesized f and the graft copolymerization of AAM onto these two func-tional copolymers films initiated with ceric salt were carried out in aqueous solution for variousperiods at 30℃. The formation of graft copolymer was verified by water absorption, ESCA andSEM photographs. Based on the results of the study of the initiation mechanism of model com-pounds and ceric salt systems, the reaction mechanism of the graft copolymerization initiated withceric salt was proposed.

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