COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR*

CHEN Chuanfu; REN Changy; XI Fu

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COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR*

Papers | Updated：2021-06-21

- COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR*
- Vol. 12, Issue 2, Pages: 190-192(1994)
- Affiliations：
  
  1.   Institute of Chemistry
  2.   Academia Sinica
  3.   Beijing 100080
- Author bio：
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CHEN Chuanfu, REN Changy, XI Fu. COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR*. [J]. 12(2):190-192(1994)
DOI：

CHEN Chuanfu, REN Changy, XI Fu. COPOLYMERIZATION PROCESS OF TRIPHENYLMETHYL METHACRYLATE AND MMA WITH CHIRAL ANIONIC COMPLEX INITIATOR*. [J]. 12(2):190-192(1994) DOI：

摘要

<正> The copolymerization process of triphenylmethyl methacrylate （TrMA） and methylmethacrylate （MMA） using chiral anionic complex initiator （-） SP-FlLi （Scheme 1） has beenstudied in toluene and THF, respectively. The copolymer obtained in toluene possessed muchhigher specific rotation than that in THF. These copolymers have shown a tendency to a random and a like alternating structure, respectively.

Abstract

The copolymerization process of triphenylmethyl methacrylate （TrMA） and methylmethacrylate （MMA） using chiral anionic complex initiator （-） SP-FlLi （Scheme 1） has beenstudied in toluene and THF, respectively. The copolymer obtained in toluene possessed muchhigher specific rotation than that in THF. These copolymers have shown a tendency to a random and a like alternating structure, respectively.

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