Ingenious Engineering of Phosphorus and Nitrogen-enriched Nickel/Iron Bimetallic Phyllosilicates: Forging Multifunctional Epoxy Composites with Excellent Toughness, Self-lubrication, Wear Resistance and Flame Retardancy

Peng Jin; Ji-Nian Yang; Wei-Long Chen; De-Han Chen; Yu-Xuan Xu; Han-Xing Yang; Bing-Yi Li; Shi-Bin Nie

doi:10.1007/s10118-026-3685-7

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Ingenious Engineering of Phosphorus and Nitrogen-enriched Nickel/Iron Bimetallic Phyllosilicates: Forging Multifunctional Epoxy Composites with Excellent Toughness, Self-lubrication, Wear Resistance and Flame Retardancy

RESEARCH ARTICLE | Updated：2026-07-27

- Ingenious Engineering of Phosphorus and Nitrogen-enriched Nickel/Iron Bimetallic Phyllosilicates: Forging Multifunctional Epoxy Composites with Excellent Toughness, Self-lubrication, Wear Resistance and Flame Retardancy
- Ingenious Engineering of Phosphorus and Nitrogen-enriched Nickel/Iron Bimetallic Phyllosilicates: Forging Multifunctional Epoxy Composites with Excellent Toughness, Self-lubrication, Wear Resistance and Flame Retardancy
- Chinese Journal of Polymer Science 2026年44卷第8期页码：2726-2747
- Affiliations：
  
  a.School of Materials Science and Engineering, Anhui University of Science & Technology, Huainan 232001, China
  b.School of Construction Management, Jiangsu Vocational Institute of Architectural Technology, Xuzhou 221116, China
  c.School of Public Security and Emergency Management, Anhui University of Science & Technology, Hefei 231131, China
- Author bio：
  
  jnyang@aust.edu.cn (J.N.Y.)
  nieshibin88@163.com (S.B.N.)
- Funds：
  
  This work was financially supported by the Outstanding Youth Scientific Research Project in Anhui Province (No. 2022AH020055), the Graduate Innovation Fund of Anhui University of Science and Technology (Nos. 2024cx2083 and 2025cx2086), the Innovation Training Program for College Students at Anhui University of Science and Technology (No.202510361079), and the General Program of Jiangsu Provincial Basic Science Research in Higher Education Institutions (Natural Sciences, No. 24KJD620002). The authors would also like to thank the Analytical and Testing Center of Anhui University of Science and Technology for XPS and TGA examinations, and Qing Yi from SCI-GO (www.sci-go.com) for elemental mapping analysis.;The authors declare no interest conflict.Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-026-3685-7.The data supporting the findings of this study are available from the corresponding author upon reasonable request.
- DOI：10.1007/s10118-026-3685-7
  中图分类号：
- 收稿：2026-02-06，
  
  录用：2026-03-26，
  
  网络首发：2026-07-09，
  
  纸质出版：2026-08-15
- Accepted：
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Jin, P.; Yang, J. N.; Chen, W. L.; Chen, D. H.; Xu, Y. X.; Yang, H. X.; Li, B. Y.; Nie, S. B. Ingenious engineering of phosphorus and nitrogen-enriched nickel/iron bimetallic phyllosilicates: forging multifunctional epoxy composites with excellent toughness, self-lubrication, wear resistance and flame retardancy. Chinese J. Polym. Sci. 2026, 44, 2726–2747

Peng Jin, Ji-Nian Yang, Wei-Long Chen, et al. Ingenious Engineering of Phosphorus and Nitrogen-enriched Nickel/Iron Bimetallic Phyllosilicates: Forging Multifunctional Epoxy Composites with Excellent Toughness, Self-lubrication, Wear Resistance and Flame Retardancy[J]. Chinese Journal of Polymer Science, 2026, 44(8): 2726-2747.
Jin, P.; Yang, J. N.; Chen, W. L.; Chen, D. H.; Xu, Y. X.; Yang, H. X.; Li, B. Y.; Nie, S. B. Ingenious engineering of phosphorus and nitrogen-enriched nickel/iron bimetallic phyllosilicates: forging multifunctional epoxy composites with excellent toughness, self-lubrication, wear resistance and flame retardancy. Chinese J. Polym. Sci. 2026, 44, 2726–2747 DOI： 10.1007/s10118-026-3685-7.

Peng Jin, Ji-Nian Yang, Wei-Long Chen, et al. Ingenious Engineering of Phosphorus and Nitrogen-enriched Nickel/Iron Bimetallic Phyllosilicates: Forging Multifunctional Epoxy Composites with Excellent Toughness, Self-lubrication, Wear Resistance and Flame Retardancy[J]. Chinese Journal of Polymer Science, 2026, 44(8): 2726-2747. DOI： 10.1007/s10118-026-3685-7.

摘要

This work ingeniously designed and synthesized rice-like hierarchical PN-NiFePS derived from NiFe-MOF

which integrates

in situ

grown inorganic nanosheets and covalently grafted P/N-containing organic chains

significantly enhancing the comprehensive properties and providing a novel strategy for multifunctional EP composites.

Abstract

Epoxy resin (EP) is one of the most promising thermosetting resins used in engineering applications; however

its intrinsic drawbacks of poor abrasion resistance and flame retardancy limit its long-term application in harsh environments. In this study

to improve the comprehensive properties of EP

a prospective four-in-one strategy was proposed to prepare composites by rationally introducing multifunctional nanofillers. First

phosphorus- and nitrogen-enriched nickel/iron bimetallic phyllosilicates (PN-NiFePS) were facilely synthesized and subsequently incorporated into EP to prepare high-performance composites. The results indicate that PN-NiFePS nanoparticles display unique rice-grain-shaped morphologies with rough surfaces

as numerous PN-NiFePS nanosheets were vertically grown on the crystalline surface of the metal-organic framework. The chemically grafted P/N-containing pendant chains enabled well-bonded polymer-filler interfaces and homogeneous dispersion

significantly enhancing the mechanical properties. With the increase filler concentration

the wear rate exhibits a trend of initial decrease followed by subsequent increase

reaching a minimum of 1.19×10

-6

/(N·m) by adding 1% PN-NiFePS

which is 72% lower than pure EP. The incorporated PN-NiFePS endowed the composites with improved flame retardancy

leading to a steady increase in the limiting oxygen index and excellent self-extinguishing during combustion. This study provides an ingenious engineering strategy for constructing cross-function-integrated polymer composites su

itable for harsh environments.

关键词

Keywords

references

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