Revisiting the Effect of Reactive Compatibilization on Polymer Crystallization: From Static Suppression to Shear-induced Promotion

Bao-Gou Wu; Xiao-Hu Bing; Qian Ren; Lan Ding; Ji-Zhang Li; Wen-Ge Zheng; Long Wang

doi:10.1007/s10118-025-3529-x

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Revisiting the Effect of Reactive Compatibilization on Polymer Crystallization: From Static Suppression to Shear-induced Promotion

RESEARCH ARTICLE | Updated：2026-02-13

- Revisiting the Effect of Reactive Compatibilization on Polymer Crystallization: From Static Suppression to Shear-induced Promotion
- Revisiting the Effect of Reactive Compatibilization on Polymer Crystallization: From Static Suppression to Shear-induced Promotion
- Chinese Journal of Polymer Science 2026年44卷第3期页码：756-767
- Affiliations：
  
  a.Ningbo Key Lab of Polymer Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  wanglong@nimte.ac.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 52573053).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-025-3529-x.
- DOI：10.1007/s10118-025-3529-x
  中图分类号： [M
- 收稿：2025-11-07，
  
  录用：2025-12-09，
  
  网络首发：2026-02-04，
  
  纸质出版：2026-03-15
- Accepted：
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Wu, B. G.; Bing, X. H.; Ren, Q.; Ding, L.; Li, J. Z.; Zheng, W. G.; Wang, L. Revisiting the effect of reactive compatibilization on polymer crystallization: from static suppression to shear-induced promotion. Chinese J. Polym. Sci. 2026, 44, 756–767

Bao-Gou Wu, Xiao-Hu Bing, Qian Ren, et al. Revisiting the Effect of Reactive Compatibilization on Polymer Crystallization: From Static Suppression to Shear-induced Promotion[J]. Chinese Journal of Polymer Science, 2026, 44(3): 756-767.
Wu, B. G.; Bing, X. H.; Ren, Q.; Ding, L.; Li, J. Z.; Zheng, W. G.; Wang, L. Revisiting the effect of reactive compatibilization on polymer crystallization: from static suppression to shear-induced promotion. Chinese J. Polym. Sci. 2026, 44, 756–767 DOI： 10.1007/s10118-025-3529-x.

Bao-Gou Wu, Xiao-Hu Bing, Qian Ren, et al. Revisiting the Effect of Reactive Compatibilization on Polymer Crystallization: From Static Suppression to Shear-induced Promotion[J]. Chinese Journal of Polymer Science, 2026, 44(3): 756-767. DOI： 10.1007/s10118-025-3529-x.

摘要

Reactive compatibilization typically suppresses crystallization in polymer blends by reducing chain mobility and regularity

but this study reveals that under shear flow it instead significantly enhances the crystallization rate.

Abstract

Reactive compatibilization has been widely applied to enhance the compatibilit

y of polymer blends

thereby improving their mechanical properties. However

it generally reduces the chain mobility and regularity

often leading to slower polymer crystallization. Here

we demonstrate that reactive compatibilization in poly(lactic acid)/poly(butylene adipate-

-terephthalate) (PLA/PBAT) blends unexpectedly promotes PLA matrix crystallization during injection molding

in contrast to the retarded kinetics observed in differential scanning calorimetry isothermal crystallization studies. The phase morphology

rheological behavior

and crystalline structure were systematically analyzed to elucidate markedly different crystallization kinetics under static and shear fields. The potential mechanism underlying crystallization enhancement is attributed to PBAT domain refinement and viscosity increase induced by reactive compatibilization

which

under shear flow

create favorable conditions for crystallization by enhancing PBAT fibril nucleation and retarding the relaxation of oriented PLA chains. This study offers new perspectives on the effect of reactive compatibilization on the polymer crystallization behavior.

关键词

Keywords

references

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