Synthesis of Polydimethylsiloxane Ureas and Preparation of Magnetic Filaments for 3D Printing

Ekaterina A. Olenich; Vadim V. Gorodov; Nina V. Demchenko; Ulyana S. Andropova; Kirill K. Bakanov; Artur E. Krupnin; Irina O. Kuchkina; Sergei A. Kostrov; Sergey A. Milenin; Sergey N. Chvalun; Jun Zou; Elena Yu. Kramarenko

doi:10.1007/s10118-025-3457-9

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Synthesis of Polydimethylsiloxane Ureas and Preparation of Magnetic Filaments for 3D Printing

RESEARCH ARTICLE | Updated：2025-12-03

- Synthesis of Polydimethylsiloxane Ureas and Preparation of Magnetic Filaments for 3D Printing
  Enhanced Publication
- Synthesis of Polydimethylsiloxane Ureas and Preparation of Magnetic Filaments for 3D Printing
- Chinese Journal of Polymer Science 2025年43卷第12期页码：2325-2334
- Affiliations：
  
  a.Enikolopov Institute of Synthetic Polymeric Materials of Russian Academy of Sciences, Moscow 117393, Russia
  b.National Research Centre "Kurchatov Institute", 1 Kurchatov sq., Moscow 123098, Russia
  c.A.N. Nesmeyanov Institute of Organoelement Compounds, Moscow 119991, Russia
  d.Tula State Lev Tolstoy Pedagogical University, Tula 300026, Russia
  e.State Key Laboratory of Fluid Power and Mechatronic Systems, Zhejiang University, Hangzhou 310027, China
  f.School of Mechanical Engineering, Zhejiang University, Hangzhou 310027, China
  g.Faculty of Physics, Lomonosov Moscow State University, Moscow 119991, Russia
- Author bio：
  
  cephe@mail.ru (S.A.M.)
  kram@polly.phys.msu.ru (E.Y.K.)
- Funds：
  
  This work was financially supported by the Russian Science Foundation (No. 23-43-00057), and the International Cooperation Program of the Natural Science Foundation of China (No. 52261135542). 　The study of samples by NMR, GPC, TGA were performed with the financial support from Ministry of Science and Higher Education of the Russian Federation using the equipment of Collaborative Access Center “Сenter for Polymer Research” of ISPM RAS (No. FFSM-2024-0001). 　Studies of the mechanical properties of materials were conducted within the framework of State Assignment (No. 075-00276-25-00) of the Ministry of Science and Higher Education of the Russian Federation. 　The work was carried out with partial financial support from the State Assignment of the National Research Centre “Kurchatov Institute” (3D printing of the samples). SEM studies were performed with financial support from the Government of the Tula region (decree no. 899, December 30, 2021) in agreement no. September 11 7, 2022.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-025-3457-9.
- DOI：10.1007/s10118-025-3457-9
  中图分类号：
- 收稿：2025-08-19，
  
  录用：2025-09-18，
  
  网络出版：2025-11-19，
  
  纸质出版：2025-12-15
- Accepted：
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Olenich, E. A.; Gorodov, V. V.; Demchenko, N. V.; Andropova, U. S.; Bakanov, K. K.; Krupnin, A. E.; Kuchkina, I. O.; Kostrov, S. A.; Milenin, S. A.; Chvalun, S. N.; Zou, J.; Kramarenko, E. Y. Synthesis of polydimethylsiloxane ureas and preparation of magnetic filaments for 3D printing. Chinese J. Polym. Sci. 2025, 43, 2325–2334

Ekaterina A. Olenich, Vadim V. Gorodov, Nina V. Demchenko, et al. Synthesis of Polydimethylsiloxane Ureas and Preparation of Magnetic Filaments for 3D Printing[J]. Chinese Journal of Polymer Science, 2025, 43(12): 2325-2334.
Olenich, E. A.; Gorodov, V. V.; Demchenko, N. V.; Andropova, U. S.; Bakanov, K. K.; Krupnin, A. E.; Kuchkina, I. O.; Kostrov, S. A.; Milenin, S. A.; Chvalun, S. N.; Zou, J.; Kramarenko, E. Y. Synthesis of polydimethylsiloxane ureas and preparation of magnetic filaments for 3D printing. Chinese J. Polym. Sci. 2025, 43, 2325–2334 DOI： 10.1007/s10118-025-3457-9.

Ekaterina A. Olenich, Vadim V. Gorodov, Nina V. Demchenko, et al. Synthesis of Polydimethylsiloxane Ureas and Preparation of Magnetic Filaments for 3D Printing[J]. Chinese Journal of Polymer Science, 2025, 43(12): 2325-2334. DOI： 10.1007/s10118-025-3457-9.

摘要

This study develops magnetoactive polymer composites for soft robotics via extrusion-based 3D printing. Polysiloxane-urea copolymers were synthesized and characterized for thermal and rheological properties. Carbonyl iron microparticles were incorporated into the soft polymer matrix

and 3D printing experiments confirmed their suitability for additive manufacturing.

Abstract

The aim of this study is to develop magnetopolymer composites suitable for fabricating soft magnetoactive robots

via

extrusion-based 3D printing. Polysiloxane copolymers with urea fragments were synthesized and characterized

and their thermophysical and rheological properties were investigated. This study provides an assessment of the potential for their further use in additive manufacturing. The obtained materials were utilized as matrices for creating magnetically active polymer composites by incorporating microparticles of carbonyl iron. Samples of complex geometries were printed using both neat and filled filaments

demonstrating the feasibility of employing these materials in extrusion-based 3D printing.

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references

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