Kilogram-scale Flux Synthesis of Olefin-linked Amorphous Conjugated Microporous Polymers toward C2H2/CO2 Separation

Yu-Shu Zhang; Kai-Yuan Wang; Li-Qin Hao; Ji-Xian Wang; Meng-Jin Wang; Yao Chen; Peng Cheng; Xia Li; Zhen-Jie Zhang

doi:10.1007/s10118-025-3437-0

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Kilogram-scale Flux Synthesis of Olefin-linked Amorphous Conjugated Microporous Polymers toward C₂H₂/CO₂ Separation

RESEARCH ARTICLE | Updated：2026-04-30

- Kilogram-scale Flux Synthesis of Olefin-linked Amorphous Conjugated Microporous Polymers toward C₂H₂/CO₂ Separation
- Kilogram-scale Flux Synthesis of Olefin-linked Amorphous Conjugated Microporous Polymers toward C₂H₂/CO₂ Separation
- Chinese Journal of Polymer Science 2026年44卷第5期页码：1364-1372
- Affiliations：
  
  a.College of Chemistry, State Key Laboratory of Medicinal Chemical Biology, Nankai University, Tianjin 300071, China
  b.Key Laboratory of Advanced Energy Materials Chemistry, Ministry of Education, Nankai University, Tianjin 300071, China
  c.College of Pharmacy, Nankai University, Tianjin 300071, China
  d.Frontiers Science Center for New Organic Matter, Renewable Energy Conversion and Storage Center, Nankai University, Tianjin 300071, China
  e.Nankai International Advanced Research Institute (Shenzhen Futian), Nankai University, Tianjin 300071, China
  f.Nankai Cangzhou Bohai New Area Green Chemical Research Co., LTD., Cangzhou 061100, China
- Author bio：
  
  zhangzhenjie@nankai.edu.cn
- Funds：
  
  This work was financially supported by the National Key Research and Development Program of China (No. 2020YFA0907300), the National Natural Science Foundation of China (Nos. 22205116 and 22175099), and 111 Project (No. B12015) and NCC Fund (No. 2022-PY-04).;The authors declare no interest conflict.Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-025-3437-0.Data supporting the findings of this study can be provided by contacting the corresponding author.
- DOI：10.1007/s10118-025-3437-0
  中图分类号：
- 收稿：2025-07-06，
  
  录用：2025-08-17，
  
  网络首发：2025-12-22，
  
  纸质出版：2026-05-05
- Accepted：
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Zhang, Y. S.; Wang, K. Y.; Hao, L. Q.; Wang, J. X.; Wang, M. J.; Chen, Y.; Cheng, P.; Li, X.; Zhang, Z. J. Kilogram-scale flux synthesis of olefin-linked amorphous conjugated microporous polymers toward C₂H₂/CO₂ separation. Chinese J. Polym. Sci. 2026, 44, 1364–1372

Yu-Shu Zhang, Kai-Yuan Wang, Li-Qin Hao, et al. Kilogram-scale Flux Synthesis of Olefin-linked Amorphous Conjugated Microporous Polymers toward C₂H₂/CO₂ Separation[J]. Chinese Journal of Polymer Science, 2026, 44(5): 1364-1372.
Zhang, Y. S.; Wang, K. Y.; Hao, L. Q.; Wang, J. X.; Wang, M. J.; Chen, Y.; Cheng, P.; Li, X.; Zhang, Z. J. Kilogram-scale flux synthesis of olefin-linked amorphous conjugated microporous polymers toward C₂H₂/CO₂ separation. Chinese J. Polym. Sci. 2026, 44, 1364–1372 DOI： 10.1007/s10118-025-3437-0.

Yu-Shu Zhang, Kai-Yuan Wang, Li-Qin Hao, et al. Kilogram-scale Flux Synthesis of Olefin-linked Amorphous Conjugated Microporous Polymers toward C₂H₂/CO₂ Separation[J]. Chinese Journal of Polymer Science, 2026, 44(5): 1364-1372. DOI： 10.1007/s10118-025-3437-0.

摘要

This work presents a solvent-free flux synthesis of olefin-linked CMPs

offering a scalable and environmentally friendly alternative to traditional methods. Notably

NKCMP-1 was successfully synthesized on a kilogram scale (0.54 kg) while preserving high surface area and uniform microporosity. The materials exhibit excellent C

/CO

selectivity and stability

demonstrating great potential for industrial gas separation.

Abstract

Conjugated microporous polymers (CMPs) have demonstrated significant potential for gas separation due to their permanent microporosity

high adsorption capacity

and exceptional chemical robustness. However

the scalable

cost-effective and environmentally friendly synthesis of CMPs as an alternative to energy-intensive traditional solvothermal methods remains underexplored. Herein

we present a solvent-free

flux synthesis method for constructing olefin-linked amorphous CMPs (NKCMP-1 and NKCMP-2) through Knoevenagel condensation of 2

6-tetramethylpyrazine with linear aromatic aldehydes. This method surpasses ion

othermal and mechanochemical routes in terms of scalability and product uniformity. Notably

NKCMP-1 can be synthesized on a kilogram scale (0.54 kg) while maintaining structural integrity

high surface area and a uniform microporous architecture. Both NKCMP-1 and NKCMP-2 exhibit outstanding C

/CO

selectivity and cyclic stability under ambient conditions

as confirmed by dynamic breakthrough experiments. These features make the developed CMPs highly promising for real-world industrial gas purification applications.

关键词

Keywords

references

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