Fabrication of Functional Biobased Epoxy Coatings <italic style="font-style: italic">via</italic> Cinnamic Acid Grafting: Synergistic Antibacterial, Antifouling, UV-resistant, and Superhydrophobic Properties

Ming-Xuan Chen; Shu Tian; Shuai-Peng Wang; Sakil Mahmud; Guang-Ming Lu; Jin-Yue Dai; Xiao-Qing Liu

doi:10.1007/s10118-025-3426-3

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Fabrication of Functional Biobased Epoxy Coatings via Cinnamic Acid Grafting: Synergistic Antibacterial, Antifouling, UV-resistant, and Superhydrophobic Properties

RESEARCH ARTICLE | Updated：2025-12-03

- Fabrication of Functional Biobased Epoxy Coatings via Cinnamic Acid Grafting: Synergistic Antibacterial, Antifouling, UV-resistant, and Superhydrophobic Properties
- Fabrication of Functional Biobased Epoxy Coatings via Cinnamic Acid Grafting: Synergistic Antibacterial, Antifouling, UV-resistant, and Superhydrophobic Properties
- Chinese Journal of Polymer Science 2025年43卷第12期页码：2252-2263
- Affiliations：
  
  a.Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  b.Key Laboratory of Advanced Marine Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  c.Ivory V. Nelson Center for the Sciences, Department of Chemistry and Physics, Lincoln University, Oxford, Pennsylvania 19352, USA
- Author bio：
  
  luguangming@nimte.ac.cn(G.M.L.)
  daijinyue@nimte.ac.cn (J.Y.D.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. U23A20589 and E52307038), China Postdoctoral Science Foundation (No. 2023M743622), Zhejiang Provincial Natural Science Foundation of China (No. LQ23E030006), Ningbo 2025 Key Scientific Research Programs (Nos. 2022Z111, 2022Z160, and 2022Z198), Natural Science Foundation of Ningbo City (Nos. 2022J302 and 2024J122), and Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang (No. 2021R01005).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-025-3426-3.
- DOI：10.1007/s10118-025-3426-3
  中图分类号：
- 收稿：2025-06-18，
  
  录用：2025-08-02，
  
  网络首发：2025-11-12，
  
  纸质出版：2025-12-15
- Accepted：
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Chen, M. X.; Tian, S.; Wang, S. P.; Mahmud, S.; Lu, G. M.; Dai, J. Y.; Liu, X. Q. Fabrication of functional biobased epoxy coatings via cinnamic acid grafting: synergistic antibacterial, antifouling, UV-resistant, and superhydrophobic properties. Chinese J. Polym. Sci. 2025, 43, 2252–2263

Ming-Xuan Chen, Shu Tian, Shuai-Peng Wang, et al. Fabrication of Functional Biobased Epoxy Coatings via Cinnamic Acid Grafting: Synergistic Antibacterial, Antifouling, UV-resistant, and Superhydrophobic Properties[J]. Chinese Journal of Polymer Science, 2025, 43(12): 2252-2263. DOI: 10.1007/s10118-025-3426-3.
Chen, M. X.; Tian, S.; Wang, S. P.; Mahmud, S.; Lu, G. M.; Dai, J. Y.; Liu, X. Q. Fabrication of functional biobased epoxy coatings via cinnamic acid grafting: synergistic antibacterial, antifouling, UV-resistant, and superhydrophobic properties. Chinese J. Polym. Sci. 2025, 43, 2252–2263 DOI： 10.1007/s10118-025-3426-3.

Ming-Xuan Chen, Shu Tian, Shuai-Peng Wang, et al. Fabrication of Functional Biobased Epoxy Coatings via Cinnamic Acid Grafting: Synergistic Antibacterial, Antifouling, UV-resistant, and Superhydrophobic Properties[J]. Chinese Journal of Polymer Science, 2025, 43(12): 2252-2263. DOI: 10.1007/s10118-025-3426-3. DOI：

摘要

In this study

a simple method was adopted to synthesize the epoxy resin precursor based on cinnamic acid. The inorganic component was introduced into the epoxy resin system by chemically bonding the KH560-modified silica aerogel. Finally

the multifunctional epoxy resin coating with UV resistance

anti-fouling and superhydrophobic properties was prepared through curing and crosslinking with IPDA.

Abstract

Effective antifouling coatings are critical for protecting marine infrastructure from biofouling and environmental degradation; however

achieving long-term antifouling performance along with environmental stability remains a major challenge. In this study

a multifunctional bio-based epoxy coating is developed by integrating a dual-action antifouling system. Cinnamic acid (CA)

which is known for its antibacterial and UV-shielding properties

was chemically grafted into ethylene glycol diglycidyl ether (EGDE) to provide intrinsic antifouling and anti-UV functions. Simultaneously

the KH560-modified silica aerogel was incorporated to create a dense hydrophobic surface that repels microorganism adhesion. The resulting coating exhibited a superhydrophobic contact angle of 154.3°

an ultralow surface energy

and exceptional resistance to protein and algal adhesion. Additionally

it achieves 99% bactericidal efficiency against

Escherichia coli

(

E. coli

) and

Staphylococcus aureus

(

S. aureus

) while maintaining high transparency and ease of processing. These results highlight a promising strategy for designing durable and eco-friendly antifouling coatings suitable for demanding marine environments.

关键词

Keywords

references

Qiu, H.; Feng, K.; Gapeeva, A.; Meurisch, K.; Kaps, S.; Li, X.; Baum, M. Functional polymer materials for modern marine biofouling control. Prog. Polym. Sci. 2022 , 127 , 101516..

Pan, J.; Ai, X.; Ma, C.; Zhang, G. Degradable vinyl polymers for combating marine biofouling. Acc. Chem. Res. 2022 , 55 , 1586−1598..

Tian, Z.; Lei, Z.; Chen, X.; Chen, Y.; Zhang, L. C.; Bi, J.; Liang, J. Nanosecond pulsed fiber laser cleaning of natural marine micro-biofoulings from the surface of aluminum alloy. J. Clean. Prod. 2019 , 244 , 1 18724..

Cao, P.; Tian, S.; Dai, J.; Li, J.; Lu, G.; Liu, X. A catfish skin-inspired dual-antifouling epoxy thermoset as coatings for marine antifouling applications. Chem. Eng. J. 2024 , 504 , 159057..

Kim, D.H.; Alayande, A.B.; Lee, J.M.; Jang, J.H.; Jo, S.M.; Jae, M.R.;Yang, E.; Chae, K.J. Emerging marine environmental pollution and ecosystem disturbance in ship hull cleaning for biofouling removal. Sci. Total Environ. 2024 , 906 , 167459..

Zhang, N.; Li, H.; Xu, F.; Thompson, C. E. L.; Townend, I. H.; He, Q. Drag acting on suspended sediment increased by microbial colonization. Nat. Geosci. 2025 , 18 , 396−401..

Chen, S.; Ma, C.; Zhang, G. Biodegradable polymer as controlled release system of organic antifoulant to prevent marine biofouling. Prog. Org. Coat. 2017 , 104 , 58−63..

Zeng, H.; Xie, Q.; Ma, C.; Zhang, G. Silicone elastomer with surface-enriched, nonleaching amphiphilic side chains for inhibiting marine biofouling. ACS Appl. Polym. Mater. 2019 , 1 , 1689−1696..

hi, X.; Wei, H.; Zhou, W.; Rodriguez, P.E.D.S.; Lin, C.; Wang, L.; Zhang, Z. Advanced strategies for marine antifouling based on nanomaterial-enhanced functional PDMS coatings. Nano Mater. Sci. 2024 , 6 , 375−395..

Shi, Y.; Qian, M.; Wei, D.; Zhang, W.; Lu, T.; Zhang, Z.; Li, S.; Liu, Y. Eucalyptus spp.-inspired degradable lubricant-releasing coating for marine antifouling surfaces. Prog. Org. Coat. 2024 , 198 , 108917..

Wang, C.; Liu, W.; Chen, R.; Sun, G.; Yu, J.; Liu, Q.; Liu, J.; Li, Y.; Zhu, J.; Liu, P.; Wang, J. Macrophage-Inspired marine antifouling coating with dynamic surfaces based on regulation of dynamic covalent bonds. J. Colloid Interface Sci. 2024 , 670 , 223−233..

Tian, Y.; Liu, Y.; Su, Z.; Wang, S.; Zhang, Q. Biomimetic brushlike slippery coatings with mechanically robust, self-cleaning, and icephobic properties. ACS Appl. Mater. Interfaces 2020 , 12 , 54041−54052..

Zhu, T.; Cheng, Y.; Huang, J. A transparent superhydrophobic coating with mechanochemical robustness for anti-icing, photocatalysis and self-c leaning. Chem. Eng. J. 2020 , 399 , 125746..

[Zhang, Y.; Pan, J.; Xie, Q.; Ma, C.; Zhang, G. Self-regenerating zwitterionic hydrogel coating modified by metal-organic framework for integrated anti-Biofouling and anti-corrosion. Adv. Funct. Mater . 2025 ..

[Yan, M.; Wu, S.; Zhong, Y.; Wu, Y.; Wu, Y.; Lan, X.; Zhao, W. Constructing self-renewing silicone-hydrogel hybrid coatings with integrated fouling resistant/release/Killing mode toward superior biofouling defense. Small 2025 , 2504089..

Wang, F.; Ma, J.; Xie, F. Organic cation-dependent degradation mechanism of organotin halide perovskites. Adv. Funct. Mater. 2016 , 26 , 3417−3423..

Lyu, B.; Guo, X.; Gao, D. Highly-stable tin-based perovskite nanocrystals produced by passivation and coating of gelatin. J. Hazard. Mater. 2020 , 403 , 123967..

Peng, X.; Wu, X.; Zhang, M. Metal–organic framework coated devices for gas sensing. ACS Sens. 2023 , 8 , 2471−2492..

Zhou, Z.; Pourhashem, S.; Wang, Z. Distinctive roles of graphene oxide, ZnO quantum dots, and their nanohybrids in anti-corrosion and anti-fouling performance of waterborne epoxy coatings. Chem. Eng. J. 2022 , 439 , 135765..

Si, Y.; Guo, Z.; Liu, W. A Robust epoxy resins @ stearic acid-Mg(OH) 2 Micronanosheet superhydrophobic omnipotent protective coating for real-life applications. ACS Appl. Mater. Interfaces 2016 , 8 , 16511−16520..

Du, H.; Liu, F.; Wang, H. Bio-inspired robust superhydrophilic/underwater superoleophobic coating with lubrication, anti-crude oil fouling and anti-corrosion performances. J. Colloid Interface Sci. 2022 , 616 , 720−729..

Hou, B.; Zhang, W.; Lu, H.; Li, Y.; Liu, X. Multielement flame-retardant system constructed with metal POSS–organic frameworks for epoxy resin. ACS Appl. Mater. Interfaces 2022 , 14 , 49326−49337..

Wang, Y.; Zeng, Z.; Gao, M.; Li, J. Hygrothermal aging characteristics of silicone-modified aging-resistant epoxy resin insulating mate rial. Polymers 2021 , 13 , 2145..

Du, B.; Chen, N.; Zhang, G. Enhanced ultraviolet aging resistance of epoxy resins through surface enrichment achieved by fluorinated graphene oxide@CeO 2 . Compos. Sci. Technol. 2024 , 253 , 110655..

[Liao, D.; Gu, T.;Liu, J. Degradation behavior and ageing mechanism of E-glass fiber reinforced epoxy resin composite pipes under accelerated thermal ageing conditions. Compos. Part B Eng . 2023 , 270 ..

[Guo, X.; Brown, R.; Dong, Y. High-performance elastomer with excellent resistance to low temperature, aging and solvent. Adv. Funct. Mater . 2025 , 2501171..

Hoffman, J.; Middleton, J.; Kumosa, M. Effect of a surface coating on flexural performance of thermally aged hybrid glass/carbon epoxy composite rods. Compos. Sci. Technol. 2015 , 106 , 141−148..

Wang, M.; Liu, Z.; Wang, T. The UV aging resistance of strong and ductile epoxy resin achieved by UV-induced self-co mpensated crosslinking points. Chem. Eng. J. 2025 , 510 , 161661..

Zhai, Z.; Feng, L.; Li, G. The anti-ultraviolet light (UV) aging property of aluminium particles/epoxy composite. Prog. Org. Coat. 2016 , 101 , 305−308..

Wang, M.; Liu, Z.; Wang, T. Insights into the effect of segment rearrangement induced by dynamic disulfide bond on UV aging resistance of UV-induced self-compensated epoxy crosslinked network. Polym. Degrad. Stabil. 2025 , 238 , 111352..

Gu, R.; Lv, Y.; Mi, H. Transparent and anti-smudge ladder-like polysilsesquioxane coating with high wear resistance and UV aging resistance. Prog. Org. Coat. 2023 , 186 , 108087..

Zhang, W.; Li, S.; Wei, D. Fabrication of a fluorine-free photocatalytic superhydrophobic coating and its long-lasting anticorrosion and excellent antibacterial abilities. Prog. Org. Coat. 2023 , 184 , 107806..

Shu, F.; Jiang, B.; Yuan. Biological activities and emerging roles of lignin and lignin-based products-a review. Biomacromolecules 2021 , 22 , 4905−4918..

Li, Y.; Zhao, S.; Hu, D. Role evaluation of active groups in lignin on UV-shielding performance. ACS Sustain. Chem. Eng. 2022 , 10 , 11856−11866..

Oufensou, S.; Casalini, S.; Balmas, V. Prenylated trans-cinnamic esters and ethers against clinical fusarium spp.: repositioning of natural compounds in antimicrobial discovery. Molecules 2021 , 26 , 658..

Huang, X.; Wang, P.; Li, T. Self-assemblies based on traditional medicine berberine and cinnamic acid for adhesion-induced inhibition multidrug-resistant staphylococcus aureus. ACS Appl. Mater. Interfaces 2020 , 12 , 227−237..

Morais, MC.; Oliveira, Lima, E.; Perez-Castillo, Y. Synthetic cinnamides and cinnamates: antimicrobial activity, mechanism of action, and in silico study. Molecules 2023 , 28 , 1918..

Zhang, S.; Cheng, X.; Fu, Q. Pectin-nanolignin composite films with water resistance, UV resistance, and antibacterial activity. Food Hydrocoll. 2023 , 143 , 108783..

Li, B.; Zhu, X.; Xu, C. Sustainable strategy for lignin etherification and its promotion of anti-UV aging PLA biocomposite. Chem. Eng. J. 2024 , 500 , 156746..

Xu, S.; Liu, L.; Jia, X. Investigation of aging resistance of organic layered double hydroxide/antioxidant composite-modified asphalt. ACS Sustain. Chem. Eng. 2023 , 11 , 267−277..

Malheiro, J. F.; Maillard, J. Y.; Borges, F. Evaluation of cinnamaldehyde and cinnamic acid derivatives in microbial growth control. Int. Biodeterior. Biodegrad. 2019 , 141 , 71−78..

Amoneit, M.; Weckowska, D.; Spahr, S. Green chemistry and responsible research and innovation: Moving beyond the 12 principles. J. Clean. Prod. 2024 , 484 , 144011..

Chen, M.; Dai, J.; Zhang, L. The role of renewable protocatechol acid in epoxy coating modification: significantly improved antibacterial and adhesive properties. Chinese. J. Polym. Sci. 2023 , 42 , 63−72..

Liu, J.; Dai, J.; Wang, S. Facile synthesis of bio-based reactive flame retardant from vanillin and guaiacol for epoxy resin. Compos. Part B Eng. 2020 , 190 , 107926..

Wang, Y.; Chen, Y.; Li, Z. Regulation and mechanism of water-cement ratio and superplasticizer on rheological properties of waterborne epoxy resin emulsion modified cement paste. Constr. Build. Mater. 2025 , 476 , 141288..

Jangizehi, A.; Ahmadi, M.; Seiffert, S. Dynamics of supramolecular associative polymer networks at the interplay of chain entanglement, transient chain association, and chain-sticker clustering. J. Polym. Sci. 2019 , 57 , 1209−1223..

Gao, G.; Zhang, T.; Wang, Q. ADA-07 suppresses solar ultraviolet-induced skin carcinogenesis by directly inhibiting TOPK. Mol. Cancer Ther. 2017 , 16 , 1843−1854..

Zheng, Q.; Capell, B. C.; Parekh, V. Whole-exome and transcriptome analysis of UV-exposed epidermis and carcinoma in situ reveals early drivers of carcinogenesis. J. Invest. Dermatol. 2021 , 141 , 295−307..

Aslan, A.; Salur, E.; Düzcükoğlu, H. The effects of harsh aging environments on the properties of neat and MWCNT reinforced epoxy resins. Constr. Build. Mater. 2021 , 272 , 121929..

Xu, C.; Qu, Z.; Tan, Z. High-temperature resistance and hydrophobic polysiloxane-based polyurethane films with cross-linked structure prepared by the sol-gel process. Polym. Test. 2020 , 86 , 106485..

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Fabrication of Functional Biobased Epoxy Coatings via Cinnamic Acid Grafting: Synergistic Antibacterial, Antifouling, UV-resistant, and Superhydrophobic Properties

Fabrication of Functional Biobased Epoxy Coatings via Cinnamic Acid Grafting: Synergistic Antibacterial, Antifouling, UV-resistant, and Superhydrophobic Properties

DOI：10.1007/s10118-025-3426-3

摘要

Abstract

关键词

Keywords

references