Synthesis and Performance Evaluation of Degradable Sorbitol-derived Epoxy Resins

He-Chen Liu; Xiang-Qing Li; Xin-Xin Zhou; Huai-Qing Tian

doi:10.1007/s10118-025-3417-4

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Synthesis and Performance Evaluation of Degradable Sorbitol-derived Epoxy Resins

RESEARCH ARTICLE | Updated：2025-10-30

- Synthesis and Performance Evaluation of Degradable Sorbitol-derived Epoxy Resins
- Synthesis and Performance Evaluation of Degradable Sorbitol-derived Epoxy Resins
- 高分子科学（英文） 2025年43卷第11期页码：2073-2082
- Affiliations：
  
  Hebei Key Laboratory of Green and Efficient New Electrical Materials and Equipment, North China Electric Power University, Baoding 071003, China
- Author bio：
  
  15274692771@163.com
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 52377025).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-025-3417-4.
- DOI：10.1007/s10118-025-3417-4
  中图分类号：
- 收稿：2025-06-06，
  
  录用：2025-07-25，
  
  网络首发：2025-10-16，
  
  纸质出版：2025-11-05
- Accepted：
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Liu, H. C.; Li, X. Q.; Zhou, X. X.; Tian, H. Q. Synthesis and performance evaluation of degradable sorbitol-derived epoxy resins. Chinese J. Polym. Sci. 2025, 43, 2073–2082

He-Chen Liu, Xiang-Qing Li, Xin-Xin Zhou, et al. Synthesis and Performance Evaluation of Degradable Sorbitol-derived Epoxy Resins[J]. Chinese Journal of Polymer Science, 2025, 43(11): 2073-2082.
Liu, H. C.; Li, X. Q.; Zhou, X. X.; Tian, H. Q. Synthesis and performance evaluation of degradable sorbitol-derived epoxy resins. Chinese J. Polym. Sci. 2025, 43, 2073–2082 DOI： 10.1007/s10118-025-3417-4.

He-Chen Liu, Xiang-Qing Li, Xin-Xin Zhou, et al. Synthesis and Performance Evaluation of Degradable Sorbitol-derived Epoxy Resins[J]. Chinese Journal of Polymer Science, 2025, 43(11): 2073-2082. DOI： 10.1007/s10118-025-3417-4.

摘要

This paper is based on the construction of a resin cross-linking network using dynamic ester bonds

employing bio-based sorbitol glycidyl ether as the resin matrix. The effects of different catalysts on the performance of the resin were systematically investigated. And the resins produced can be degraded in benzyl alcohol

demonstrating excellent degradability.

Abstract

The introduction of dynamic covalent bonds into the structure of epoxy resins can improve the degradation performance of the materials. But to a certain extent

it will affect the insulating properties of the resin

and how to balance the insulating properties and degradation performance has become an urgent problem. In this paper

the effects of different catalysts on the thermal-force-electrical properties of sorbitol-based resins were systematically investigated based on the dynamic ester bonding to construct the resin crosslinking network

and the biobased sorbitol glycidyl ether was used as the resin matrix. The experiments show that the resin system catalyzed by triethanolamine (TEOA) exhibits excellent comprehensive performance

which combines good thermal stability and mechanical properties with excellent electrical properties (breakdown field strength of 44.21 kV/mm and dielectric loss factor of 0.29%). In addition

chemical degradation tests were conducted on the resin systems with different catalysts

and the experiments showed that the produced resins could be degraded in benzyl alcohol and exhibited good degradation performance. This study provides a theoretical basis and technical path for the development of new bio-based electrical insulating materials with both high insulation and degradation properties

which is conducive to the popularization and application of bio-based resins in the field of electrical equipment.

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Keywords

references

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