Achieving Complete Photonic Band Gaps in a Low-symmetric Rectangular Cross-sectional Columnar Phase Self-assembled from Block Copolymers

Hai-Yan Weng; Zhan-Wei Li; Yan-Chun Li; Zhong-Yuan Lu

doi:10.1007/s10118-025-3329-3

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Achieving Complete Photonic Band Gaps in a Low-symmetric Rectangular Cross-sectional Columnar Phase Self-assembled from Block Copolymers

RESEARCH ARTICLE | Updated：2025-07-14

- Achieving Complete Photonic Band Gaps in a Low-symmetric Rectangular Cross-sectional Columnar Phase Self-assembled from Block Copolymers
- Achieving Complete Photonic Band Gaps in a Low-symmetric Rectangular Cross-sectional Columnar Phase Self-assembled from Block Copolymers
- 高分子科学（英文） 2025年43卷第6期页码：1059-1066
- Affiliations：
  
  a.State Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, Jilin University, Changchun 130023, China
  b.College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
- Author bio：
  
  zhanwei@zzu.edu.cn (Z.W.L.)
  luzhy@jlu.edu.cn (Z.Y.L.)
- Funds：
  
  This work was financially supported by the National Key R&D Program of China (No. 2022YFB3707300) and the National Natural Science Foundation of China (Nos. 22133002, 22373089). Z.W.L. acknowledges the support from the Excellent Youth Foundation of Henan Scientific Committee (No. 242300421032).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-025-3329-3.
- DOI：10.1007/s10118-025-3329-3
  中图分类号：
- 收稿：2025-01-20，
  
  修回：2025-02-20，
  
  录用：2025-03-05，
  
  网络首发：2025-05-08，
  
  纸质出版：2025-05-20
- Accepted：
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Weng, H. Y.; Li, Z. W.; Li, Y. C.; Lu, Z. Y. Achieving complete photonic band gaps in a low-symmetric rectangular cross-sectional columnar phase self-assembled from block copolymers. Chinese J. Polym. Sci. 2025, 43, 1059–1066

Hai-Yan Weng, Zhan-Wei Li, Yan-Chun Li, et al. Achieving Complete Photonic Band Gaps in a Low-symmetric Rectangular Cross-sectional Columnar Phase Self-assembled from Block Copolymers[J]. Chinese Journal of Polymer Science, 2025, 43(6): 1059-1066.
Weng, H. Y.; Li, Z. W.; Li, Y. C.; Lu, Z. Y. Achieving complete photonic band gaps in a low-symmetric rectangular cross-sectional columnar phase self-assembled from block copolymers. Chinese J. Polym. Sci. 2025, 43, 1059–1066 DOI： 10.1007/s10118-025-3329-3.

Hai-Yan Weng, Zhan-Wei Li, Yan-Chun Li, et al. Achieving Complete Photonic Band Gaps in a Low-symmetric Rectangular Cross-sectional Columnar Phase Self-assembled from Block Copolymers[J]. Chinese Journal of Polymer Science, 2025, 43(6): 1059-1066. DOI： 10.1007/s10118-025-3329-3.

摘要

We demonstrate that block copolymers (BCPs) incorporating shape-anisotropic rod-like side chains can self-assemble into a hexagonally packed columnar phase with low-symmetric rectangular cross-sections using dissipative particle dynamics simulations. This structure exhibits a complete photonic band gap. Our findings offer an effective strategy for low-symmetric photonic crystals.

Abstract

A significant challenge in developing block copolymer photonic crystals is constructing low-symmetric ordered phases

which are essential for achieving a complete photonic band gap. Here

we propose a promising strategy to create low-symmetric ordered morphologies by incorporating shape-anisotropic rod-like side chains into block copolymers. Using dissipative particle dynamics simulations

we demonstrate that block copolymers with longer rod-like side chains can self-assemble into a hexagonally packed columnar phase characterized by a low-symmetric rectangular cross-section. Photonic band structure calculations reveal that this low-symmetric columnar phase can exhibit a complete photonic band gap

with the gap size dependent on the aspect ratio of the rectangular cross-sections of the columns. Our findings suggest an effective approach to constructing low-symmetric photonic crystals through the self-assembly of block copolymers with shape-anisotropic segments.

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