Viscosity, NMR Diffusometry and Light Scattering Data for Aqueous and Aqueous-Salt Solutions of Poly(1-butyl-3-vinylimidazolium bromide)

Petr A. Korchak; Polina S. Yarchenko; Evgenia A. Safonova; Alina S. Koneva; Alexey I. Victorov

doi:10.1007/s10118-025-3269-y

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Viscosity, NMR Diffusometry and Light Scattering Data for Aqueous and Aqueous-Salt Solutions of Poly(1-butyl-3-vinylimidazolium bromide)

RESEARCH ARTICLE | Updated：2025-01-23

- Viscosity, NMR Diffusometry and Light Scattering Data for Aqueous and Aqueous-Salt Solutions of Poly(1-butyl-3-vinylimidazolium bromide)
- Viscosity, NMR Diffusometry and Light Scattering Data for Aqueous and Aqueous-Salt Solutions of Poly(1-butyl-3-vinylimidazolium bromide)
- 高分子科学（英文） 2025年43卷第2期页码：380-391
- Affiliations：
  
  St. Petersburg State University, St. Petersburg 199034, Russia
- Author bio：
  
  e.a.safonova@spbu.ru
- Funds：
  
  This work was financially supported by the Russian Science Foundation (No. 20-13-00038). The experimental measurements were partially performed at the Research Park of St. Petersburg State University (“Center for Magnetic Resonance”, “Center for Thermogravimetric and Calorimetric Research”, “Center for Diagnostics of Functional Materials for Medicine, Pharmacology, and Nanoelectronics”).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-025-3269-y.
- DOI：10.1007/s10118-025-3269-y
  中图分类号：
- 收稿：2024-08-12，
  
  修回：2024-11-13，
  
  录用：2024-11-17，
  
  网络首发：2025-01-17，
  
  纸质出版：2025-02-01
- Accepted：
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Korchak, P. A.; Yarchenko, P. S.; Safonova, E. A.; Koneva, A. S.; Victorov, A. I. Viscosity, NMR diffusometry and light scattering data for aqueous and aqueous-salt solutions of poly(1-butyl-3-vinylimidazolium bromide). Chinese J. Polym. Sci. 2025, 43, 380–391

Petr A. Korchak, Polina S. Yarchenko, Evgenia A. Safonova, et al. Viscosity, NMR Diffusometry and Light Scattering Data for Aqueous and Aqueous-Salt Solutions of Poly(1-butyl-3-vinylimidazolium bromide)[J]. Chinese Journal of Polymer Science, 2025, 43(2): 380-391.
Korchak, P. A.; Yarchenko, P. S.; Safonova, E. A.; Koneva, A. S.; Victorov, A. I. Viscosity, NMR diffusometry and light scattering data for aqueous and aqueous-salt solutions of poly(1-butyl-3-vinylimidazolium bromide). Chinese J. Polym. Sci. 2025, 43, 380–391 DOI： 10.1007/s10118-025-3269-y.

Petr A. Korchak, Polina S. Yarchenko, Evgenia A. Safonova, et al. Viscosity, NMR Diffusometry and Light Scattering Data for Aqueous and Aqueous-Salt Solutions of Poly(1-butyl-3-vinylimidazolium bromide)[J]. Chinese Journal of Polymer Science, 2025, 43(2): 380-391. DOI： 10.1007/s10118-025-3269-y.

摘要

Summary: In this study

we synthesized and characterized samples of the polymerized ionic liquid and obtained experimental data on the viscosity

static and dynamic light scattering

and NMR diffusometry for aqueous and aqueous-salt solutions. We discuss the effects of the polymer concentration and salinity on the behavior of the solution.

Abstract

Poly(1-butyl-3-vinylimidazolium bromide) is a polymerized ionic liquid (PILs)

a relatively new class of materials that combines the attractive properties of ionic liquids (ILs) and polyelectrolytes and finds wide applications. The backbone of this PIL is composed of quaternary imidazolium salts

which are among the most promising and popular ILs. However

little is known about the physicochemical characteristics of the aqueous solutions of this PIL. In this study

we synthesized and characterized samples of this PIL and obtained experimental data on the viscosity

static and dynamic light scattering

and nuclear magnetic resonance diffusometry for aqueous and aqueous KBr solutions with varying polymer contents at

=298.15 K. We discuss the effects of the polymer concentration and salin

ity on the behavior of the solution.

关键词

Keywords

references

Marcilla, R.; Blazquez, J. A.; Fernandez, R.; Grande, H.; Pomposo, J. A.; Mecerreyes, D. Synthesis of novel polycations using the chemistry of ionic liquids. Macromol. Chem. Phys. 2005 , 206 , 299−304..

Eftekhari, A.; Saito, T. Synthesis and properties of polymerized ionic liquids. Eur. Polym. J. 2017 , 90 , 245−272..

Green, O.; Grubjesic, S.; Lee, S.; Firestone, M. A. The design of polymeric ionic liquids for the preparation of functional materials. Polym. Rev. 2009 , 49 , 339−360..

Yuan, J.; Antonietti, M. Poly(ionic liquid)s: polymers expanding classical property profiles. Polymer. 2011 , 52 , 1469−1482..

Yuan, J.; Mecerreyes, D.; Antonietti, M. Poly(ionic liquid)s: an update. Prog. Polym. Sci. 2013 , 38 , 1009−1036..

Mecerreyes, D. Polymeric ionic liquids: broadening the properties and applications of polyelectrolytes. Prog. Polym. Sci. 2011 , 36 , 1629−1648..

Shaplov, A. S.; Ponkratov, D. O.; Vygodskii, Y. S. Poly(ionic liquid)s: synthesis, properties, and application. Polym. Sci. - Ser. B 2016 , 58 , 73−142..

Marcilla, R.; Blazquez, J. A.; Rodriguez, J.; Pomposo, J. A.; Mecerreyes, D. Tuning the solubility of polymerized ionic liquids by simple anion-exchange reactions. J. Polym. Sci., Part A: Polym. Chem. 2004 , 42 , 208−212..

Tang, Y.; Zhang, Y.; Chen, X.; Xie, X.; Zhou, N.; Dai, Z.; Xiong, Y. Up/down tuning of poly(ionic liquid)s in aqueous two-phase systems. Angew. Chem. Int. Ed . 2023 , 62 . https://doi.org/10.1002/anie.202215722..

Ke, Y.; Zhang, J.; Xie, Y.; Yang, Q.; Ren, Q.; Xing, H. Aqueous biphasic systems containing customizable poly(ionic liquid)s for highly efficient extractions. ChemSusChem 2020 , 13 , 1906−1914..

João, K. G.; Tomé, L. C.; Isik, M.; Mecerreyes, D.; Marrucho, I. M. Poly(ionic liquid)s as phase splitting promoters in aqueous biphasic systems. Phys. Chem. Chem. Phys. 2015 , 17 , 27462−27472..

Plaquevent, J. C.; Levillain, J.; Guillen, F.; Malhiac, C.; Gaumont, A. C. Ionic liquids: new targets and media for α -amino acid and peptide chemistry. Chem. Rev. 2008 , 108 , 5035−5060..

Smirnova, N. A.; Safonova, E. A. Ionic liquids as surfactants. Russ. J. Phys. Chem. A 2010 , 84 , 1695−1704..

Ventura, S. P. M.; E Silva, F. A.; Quental, M. V.; Mondal, D.; Freire, M. G.; Coutinho, J. A. P. Ionic-liquid-mediated extraction and separation processes for bioactive compounds: past, present, and future trends. Chem. Rev . 2017 , 117 , 6984−7052..

Korchak,P. A.; Safonova, E. A.; Victorov, A. I. Amino acid ionic liquids as components of aqueous biphasic systems for l-tryptophan extraction : experiment and thermodynamic modeling with EPC-SAFT equation of state. J. Mol. Liq. 2022 , 366 , 120185..

Korchak, P. A.; Safonova, E. A.; Victorov, A. I. Partitioning of l-tryptophan in aqueous biphasic systems containing an alkylimidazolium ionic liquid and a phosphate salt. Ind. Eng. Chem. Res. 2021 , 60 , 16078−16088..

Zimm, B. H. Dynamics of polymer molecules in dilute solution: viscoelasticity, flow birefringence and dielectric loss. J. Chem. Phys. 1956 , 24 , 269−278..

Dobrynin, A. V.; Colby, R. H.; Rubinstein, M. Scaling theory of polyelectrolyte solutions. Macromolecules 1995 , 28 , 1859−1871..

Fuoss, R. M.; Strauss, U. P. Electrostatic interaction of polyelectrolytes and simple electrolytes. J. Polym. Sci. 1948 , 3 , 602−603..

Boris, D. C.; Colby, R. H. Rheology of sulfonated polystyrene solutions. Macromolecules 1998 , 31 , 5746−5755..

Lopez, C. G.; Colby, R. H.; Graham, P.; Cabral, J. T. Viscosity and scaling of semi Fl exible polyelectrolyte NaCMC in aqueous salt solutions. Macromolecules 2017 , 50 , 332−338..

Dou, S.; Colby, R. H. Charge density effects in salt-free polyelectrolyte solution rheology. J. Polym. Sci., Part B: Polym. Phys. 2006 , 44 , 2001−2013..

Colby, R. H. Structure and linear viscoelasticity of flexible polymer solutions : comparison of polyelectrolyte and neutral polymer solutions. Rheol. Acta 2010 , 49 , 425−442..

Fernandez Prini, R.; Lagos, A.E. Tracer diffusion, electrical conductivity, and viscosity of aqueous solutions of polystyrenesulfonates. J. Polym. Sci., Part A: Gen. Pap. 1964 , 2 , 2917−2928..

Lopez, C. G.; Rogers, S. E.; Colby, R. H.; Graham, P.; Cabral, J. T. Structure of sodium carboxymethyl cellulose aqueous solutions: a SANS and rheology study. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53 , 492−501..

Chen, X.; Zhao, J.; Zhang, J.; Qiu, L.; Xu, D.; Zhang, H.; Han, X.; Sun, B.; Fu, G.; Zhang, Y.; Yan, F. Bis-imidazolium based poly(ionic liquid) electrolytes for quasi-solid-state dye-sensitized solar cells. J. Mater. Chem. 2012 , 22 , 18018−18024..

Green, M. D.; Salas-de la Cruz, D.; Ye, Y.; Layman, J. M.; Elabd, Y. A.; Winey, K. I.; Long, T. E. Alkyl-substituted N-vinylimidazolium polymerized ionic liquids: thermal properties and ionic conductivities. Macromol. Chem. Phys. 2011 , 212 , 2522−2528..

Millar, S. Tips and tricks for the lab: air-sensitive techniques. ChemViews 2013 . https://doi.org/10.1002/chemv.201300002..

Kulicke, W.-M.; Clasen, C. Viscosimetry of Polymers and Polyelectrolytes ; Springer-Verlag Berlin Heidelberg, 2004 , p. 43, 55, 61.

Sperling, L. H. Introduction to Physical Polymer Science ; John Wiley & amp; Sons, Inc., 2006 , p. 115.

Rubinstein, M.; Colby, R. H.; Dobrynin, A. V. Dynamics of semidilute polyelectrolyte solutions. Phys. Rev. Lett. 1994 , 73 , 2776−2779..

Söderman, O.; Stilbs, P. NMR studies of complex surfactant systems. Prog. Nucl. Magn. Reson. Spectrosc. 1994 , 26 , 445−482..

Kazakov, A.; Magee, J. W.; Chirico, R. D.; Paulechka, E.; Diky, V.; Muzny, C. D.; Kroenlein, K.; Frenkel, M. NIST standard reference database 147: NIST Ionic Liquids Database - (ILThermo). Version 2.0 http://ilthermo.boulder.nist.gov/.

Isono, T. Density, viscosity, and electrolytic conductivity of concentrated aqueous electrolyte solutions at several temperatures. alkaline-earth chlorides, lanthanum chloride, sodium chloride, sodium nitrate, sodium bromide, potassium nitrate, potassium bromide, A. J. Chem. Eng. Data 1984 , 29 , 45−52..

Förster, S.; Sch midt, M.; Antonietti, M. Static and dynamic light scattering by aqueous polyelectrolyte solutions: effect of molecular weight, charge density and added salt. Polymer (Guildf). 1990 , 31 , 781−792..

Nishimura, N.; Ohno, H. 15 th Anniversary of polymerised ionic liquids. Polymer 2014 , 55, 3289–3297..

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