Influence of the Type of Precipitant on the Structure of Phase-inversion Polyamido-imide Membranes

Zakharova N. V.; Lebedeva G. K.; Saprykina N. N.; Kruchinina E. V.; Novozhilova E. A.; Kononova S. V.

doi:10.1007/s10118-024-3247-9

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Influence of the Type of Precipitant on the Structure of Phase-inversion Polyamido-imide Membranes

RESEARCH ARTICLE | Updated：2024-12-31

- Influence of the Type of Precipitant on the Structure of Phase-inversion Polyamido-imide Membranes
- Influence of the Type of Precipitant on the Structure of Phase-inversion Polyamido-imide Membranes
- 高分子科学（英文） 2025年43卷第1期页码：120-131
- Affiliations：
  
  a.Institute of Macromolecular Compounds of the Russian Academy of Sciences, Saint-Petersburg 199004, Russia
  b.Saint-Petersburg State Technological Institute (Technical University), Saint-Petersburg 190013, Russia
- Author bio：
  
  Na_Zar@inbox.ru
- Funds：
  
  The work was carried out within the framework of State Programs of IMC RAS (No. 122012000452-9).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3247-9.
- DOI：10.1007/s10118-024-3247-9
  中图分类号：
- 收稿：2024-07-20，
  
  录用：2024-10-22，
  
  网络首发：2024-12-25，
  
  纸质出版：2025-01-01
- Accepted：
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Zakharova, N. V.; Lebedeva, G. K.; Saprykina, N. N.; Kruchinina, E. V.; Novozhilova, E. A.; Kononova, S. V. Influence of the type of precipitant on the structure of phase-inversion polyamido-imide membranes. Chinese J. Polym. Sci. 2025, 43, 120–131

Zakharova N. V., Lebedeva G. K., Saprykina N. N., et al. Influence of the Type of Precipitant on the Structure of Phase-inversion Polyamido-imide Membranes[J]. Chinese Journal of Polymer Science, 2025, 43(1): 120-131.
Zakharova, N. V.; Lebedeva, G. K.; Saprykina, N. N.; Kruchinina, E. V.; Novozhilova, E. A.; Kononova, S. V. Influence of the type of precipitant on the structure of phase-inversion polyamido-imide membranes. Chinese J. Polym. Sci. 2025, 43, 120–131 DOI： 10.1007/s10118-024-3247-9.

Zakharova N. V., Lebedeva G. K., Saprykina N. N., et al. Influence of the Type of Precipitant on the Structure of Phase-inversion Polyamido-imide Membranes[J]. Chinese Journal of Polymer Science, 2025, 43(1): 120-131. DOI： 10.1007/s10118-024-3247-9.

摘要

New phase-inversion membranes based on polyamide-imides containing hydroxyl groups in the diamine component of the repeating unit are studied. The changes in the morphology of membranes depending on the quality of the precipitant used for wet formation

as well as on the number of hydroxyl groups in macromolecules are considered.

Abstract

Porous phase-inversion membranes of complex morphology were obtained on the basis of aromatic polyamidoimides with different numbers of hydroxyl groups in the diamine component of the repeating unit. The influence of the quality of the precipitant (nonsolvent) applied in membrane preparation (

i.e.

the use of “strong” or “weak” nonsolvent) on structural and morphological

features of polymer membranes of various chemical compositions was studied. Investigation of dilute solutions of membrane-forming polymers by optical methods revealed the changes in the state of the system both in the presence of a solvent and in the presence of a nonsolvent. On the basis of the obtained results

it was possible to estimate the sensitivity of the studied polymer/solvent/nonsolvent system to changes in the copolymer composition (a number of hydroxyl groups in the repeating unit).

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references

Drioli, E.; Brunetti, A.; Di Profio, G.; Barbieri, G. Process intensification strategies and membrane engineering. Green Chem. 2012 , 14 , 1561..

Drioli E., Stankiewicz A. I., and Macedonio F. Membrane engineering in process intensification—an overview. J. Memb. Sci. 2011 , 380 , 1−8..

Bohr, S. J.; Wang, F.; Metze, M.; Vukušić; J. L.; Sapalidis, A.; Ulbricht, M.; Nestler, B.; Barbe, St. State-of-the-art review of porous polymer membrane formation characterization—How numerical and experimental approaches dovetail to drive innovation. Frontiers in Sustainability. Sec. Sustainable Chemical Process Design. 2023 , 4 , 1093911..

Szabadvary, F.; Robinson, A. The history of analytical chemistry. Comprehensive Analytical Chemistry, Ch. 2 . 1980 , 61−282..

Arahman, N.; Maimun, T.; and Mukramah, S. The study of membrane formation via phase inversion method by cloud point and light scattering experiment. International Conference on Engineering, Science and Nanotechnology (ICESNANO 2016) (Solo: AIP Conference Proceedings). 2016 , 30018..

Wang, J.; Zheng, L.; Wu, Z.; Zhang, Y.; Zhang, X. Fabrication of hydrophobic flat sheet and hollow fiber membranes from PVDF and PVDF-CTFE for membrane distillation. J. Memb. Sci. 2016 , 497 , 183−193..

Liu, G.; Tsen, W.-C.; Jang, S.-C.; Hu, F., Zhong, F.; Li u, H. Mechanically robust and highly methanol-resistant sulfonated poly(ether ether ketone)/poly(vinylidene fluoride) nanofiber composite membranes for direct methanol fuel cells. J. Membr. Sci. 2019 , 591 , 117321..

Nivedita, S.; Ahamed, D.; Joseph, S. Thermodynamic analysis of phase diagram of H2O-DMF-PCL system: investigation on the influence of inorganic additives TiO 2 /MMT. J. Mater. Sci. 2020 , 55 , 5431−5444,.

Yin, C. Q.; Dong, J.; Li, Z.; Zhang, Z. X.; Zhang, Q. Ternary phase diagram and fiber morphology for nonsolvent/DMAc/polyamic acid systems. Polym. Bull. 2015 , 72 , 1039−1054..

Brami, M. V.; Oren, Y.; Linder, C.; Bernstein, R. Nanofiltration properties of asymmetric membranes prepared by phase inversion of sulfonated nitropolyphenylsulfone. Polymer 2017 , 111 , 137−147..

Mazinani, S.; Darvishmanesh, S.; Ehsanzadeh, A.; van der Bruggen, B. Phase separation analysis of extem/solvent/non-solvent systems and relation with membrane morphology. J. Membr. Sci. 2017 , 526 , 301−314..

Zhang, B.; Lu, C.; Liu, Y.; Zhou, P. Wet spun polyacrylontrilebased hollow fibers by blending with alkali lignin. Polymer 2018 , 149 , 294−304..

Reuvers, A. J. Membrane Formation. diffusion induced demixing processes in ternay polymeric systems. (Ph. D. Thesis), Faculty of Science and Technology, Twente University of Technology, (The Netherlands). 1987, 8−10.

Matsuyama, H.; Nishiguchi, M.; Kitamura, Y. Phase separation mechanism during membrane formation by dry-cast process. J. Appl. Polym. Sci. 2000 , 77 , 776−783..

Schaper, J. Untersuchungen zur herstellung von lösungen und membranen aus celluloseacetat. (Thesis), University of Hannover, Hannover (Germany). 2002 .

Zuo, D. Y. Influence of alcohol-based nonsolvents on the formation and morphology of PVDF membranes in phase inversion process. Chinese J. Polym. Sci. 2006 , 24 , 281..

Rahman, N. A.; Sotani, T.; Matsuyama, H. Effect of the addition of the surfactant Tetronic 1307 on p oly(ether sulfone) porous hollow-fiber membrane formation. J. Appl. Polym. Sci. 2008 , 108 , 3411−3418..

Madaeni, S. S.; Bakhtiari, L. Thermodynamic-based predictions of membrane morphology in water/dimethylsulfoxide/polyethersulfone systems. Polymer 2012 , 53 , 4481−4488..

Metze, M. Untersuchungen zur Bildung von porösen Membranen aus Cellulosederivaten nach dem Verdunstungsverfahren. (Dissertation), Gottfried Wilhelm Leibniz Universität Hannover, Hannover (Germany). 2014 .

Wenning, C.; Barbe, S.; Achten, D.; Schmidt, A. M.; Leimenstoll, M. C. Prediction of initial miscibility for ternary polyurethane reaction mixtures on basis of solubility parameters and Flory-Huggins theory. Macromol. Chem. Phys. 2018 , 219 , 1700544..

Hoernschemeyer, D. The influence of solvent type on the viscosity of concentrated polymer solutions. J. Appl. Polym. Sci. 1974 , 18 , 61−75..

Kahrs, C.; Gühlstorf, T.; Schwellenbach, J. Influences of different preparation variables on polymer ic membrane formation via nonsolvent induced phase separation. J. Appl. Polym. Sci. 2020 , 137 , 48852..

Kahrs, C.; Schwellenbach, J. Membrane formation via non-solvent induced phase separationusing sustainable solvents: a comparative study. Polymer 2020 , 186 , 122071..

Lee, H. J.; Jung, B.; Kang, Y. S.; Lee, H. Phase separation of polymer casting solution by nonsolvent vapor. J. Membr. Sci. 2004 , 245 , 103−112..

Li, J. F.; Xu, Z. L.; Yang, H. Microporous polyethersulfone membranes prepared under the combined precipitation conditions with non-solvent additives. Polym. Adv. Technol. 2008 , 19 , 251−257..

Guillen, G. R.; Ramon, G. Z.; Kavehpour, H. P.; Kaner, R. B.; Hoek, E. M. V. Direct microscopic observation of membrane formation by nonsolvent induced phase separation. J. Memb. Sci. 2013 , 431 , 212−220..

Lin, K. Y.; Wang, D. M.; Lai, J. Y. Nonsolvent-Induced gelation and its effect on membrane morphology. Macromolecules 2002 , 35 , 6697−6706..

Ren, J.; Zhou, J.; and Deng, M. Morphology transition of asymmetric flat sheet and thickness-gradient membranes by wet phase-inversion process. Desalination 2010 , 253 , 1−8..

Wang, Z.; Ma, J. The role of nonsolvent in-diffusion velocity in determining polymeric membrane morphology. Desalination 2012 , 286 , 69−79..

Hung, W. L.; Wang, D. M.; Lai, J. Y.; Chou, S. C. On the initiation of macrovoids in polymeric membranes—effect of polymer chain entanglement. J. Membr. Sci. 2016 , 505 , 70−81..

Zhang, Z.; An, Q., Ji, Y.; Qian, J.; Gao, C. Effect of zero shear viscosity of the casting solution on the morphology and permeability of polysulfone membrane prepared via the phase-inversion process. Desalination 2010 , 260 , 43−50..

Sadrzadeh, M.; Bhattacharjee, S. Rational design of phase inversion membranes by tailoring thermodynamics and kinetics of casting solution using polymer additives. J. Membr. Sci. 2013 , 441 , 31−44..

Venault, A.; Jumao-as-Leyba; A. J., Yang, Z. R.; Carretier, S.; Chang, Y. Formation mechanisms of low-biofouling PVDF/F127 membranes prepared by VIPS process. J. Taiwan Inst. Chem. Eng. 2016 , 62 , 297−306..

Peng, N.; Chung, T.-S.; Li, K. Y. The role of additives on dope rheology and membrane formation of defect-free Torlon R hollow fibers for gas separation. J. Membr. Sci. 2009 , 343 , 62−72..

Mezger, T. G. in The Rheology Handbook , 4 th Ed. Hannover: Vincentz Network European Coatings TECH FILES. 2014 ..

Tanaka, H. Universality of viscoelastic phase separation in dynamically asymmetric fluid mixtures. Phys. Rev. Lett. 1996 , 76 , 787−790..

Tanaka, H. Viscoelastic model of phase separation. Phys. Rev. E. 1997 , 56 , 4451−4462..

Tanaka,H. Viscoelastic phase separation. J. Phys. Condens. Matter. 2000 , 12 , R207−R264..

Tsai, J. T.; Su, Y. S.; Wang, D. M.; Kuo, J. L.; Lai, J. Y.; Deratani, A. Retainment of pore connectivity in membranes prepared with vapor-induced phase separation. J. Membr. Sci. 2010 , 362 , 360−373..

Mousavi, S. M.; Zadhoush, A. Investigation of the relation between viscoelastic properties of polysulfone solutions, phase inversion process and membrane morphology: the effect of solvent power. J. Memb. Sci. 2017 , 532 , 47−57..

Fan, S. C.; Wang, Y. C.; Li, C. L.; Lee, K. R.; Liaw, D. J.; Huang, H. P. Effect of coagulation media on membrane formation and vapor permeation performance of novel aromatic polyamide membrane. J. Membr. Sci. 2002 , 204 , 67−79..

Kim, J. H.; Min, B. R.; Won, J.; Park, H. C.; Kang, Y. S. Phase behavior and mechanism of membrane formation for polyimide/DMSO/water system. J. Membr. Sci. 2001 , 187 , 47−55..

Wittmar, A. S. M.; Koch, D.; Prymak, O.; Ulbricht, M. Factors affecting the nonsolvent-induced phase separation of cellu lose from ionic liquid-based solutions. ACS Omega 2020 , 5 , 27314−27322..

Zhang, Sh.; Li, F. Х.; Yu, J. Y. Kinetics of cellulose regeneration from Cellulose-NaOH/thiourea/urea/H 2 O system. Cellulose Chem. Technol. 2011 , 45 , 9−10,593-604..

Kononova, S. V.; Lebedeva, G. K.; Gubanova, G. N.; Kruchinina, E. V.; Vlasova, E. N.; Afanas’eva, N. V.; Popova, E. N.; Volkov, A. Ya.; Bykova, E. N.; Zakharova, N. V. Effect of hydroxyl-containing fragments on the structure and properties of membrane-forming polyamide-imides. Membranes 2023 , 13 , 716..

Kononova, S. V.; Gubanova, G. N.; Romashkova, K. A.; Korytkova, E. N.; Timpu, D. Polyamide-imide membranes of various morphology - features of nano-scale elements of structure. In Scanning Probe Microscopy-Physical Property Characterization at Nanoscale . 2012 ..

Kononova, S. V.; Kruchinina, E. V.; Romashkova, K. A.; Potokin, I. L.; Shchukarev, A. V.; Kudryavtsev, V. V. Phase-inversion gradient-porous films on the basis of polyamidoimides derived from phthalimidobenzenedicarbonyl dichloride and various diamines. Russian J. General Chem. 2010 , 80 , 1977−1985..

Kononova, S. V.; Kuznetsov, Y. P.; Romashkova, K. A.; Kudryavtsev, V. V. Interrelation between preparation conditions and structure of asymmetric membranes based on poly((diphenyl oxide amido)- N -phenylphthalimide). Polym. Sci., Series A 2006 , 48 , 967−973..

Lebedeva, G. К.; Kononova, S. V.; Kruchinina, E. V.; Vlasova, E. N.; Gofman, I.; Bol'shakov, M.; Romashkova, K. A. Novel hydroxyl-containing and thermo-dehydrocyclizable polycondensation polymers for multifunctional materials: synthesis, properties, application. J. Appl. Polym. Sci. 2022 , 139 , 51978,.

Mulder, M. Basic Principles of Membrane Technology. Dordrecht: Kluwer Academic Publishers. 1991 , 1−363.

Fowkes, F. M. Attractive forces at interfaces. Ind. Eng. Chem. 1964 , 56 , 40−52..

Kononova, S.V.; Kremnev, R. V.; Suvorova, E. I.; Baklagina, Y. G.; Volchek, B. Z.; Uchytil, P.; Shabsels, B. M.; Ro-mashkova, K. A.; Setnickova, K.; Reznickova, J. Pervaporation membranes with poly( γ -benzyl-L-glutamate) selective layer s for separation of toluene- n -heptane mixtures. J. Membr. Sci. 2015 , 477 , 14−24..

Lai, J. Y.; Lin, F. C.; Wang, C. C.; Wang, D., M. Effect of nonsolvent additives on the porosity and morphology of asymmetric TPX membranes. J. Membr. Sci. 1996 , 118 , 49−61,.

Ismail, A. F.; Lai, P.Y. Review on the development of defect free andultrathin-skinned asymmetric membranes for gas separation through manipulation of phase inversion and rheological factors. J. Appl. Polym. Sci. 2003 , 88 , 442−451,.

Yamasaki, A.; Tyagi, R.K.; Fouda, A.E.; Matsuura, T.; Jonasson, К. Effect of solvent evaporation condition on gas separation performance for asymmetric membranes. J. Appl. Polym. Sci. 1999 , 71 , 1367−1374,.

Pesek, S. C.; Koros, W. J. Aqueous quenched asymmetric polysulphone membranes prepared by dry/wet phase separation. J. Membr. Sci. 1993 , 81 , 71−88..

Wang, D.; Li, K.; Sourirajan, S.; Teo, W. K. Phase separation phenomena of polysulfone/solvent/organic nonsolvent and pol yethersulfone/solvent/organic nonsolvent systems. J. Appl. Polym. Sci. 1993 , 50 , 1693−1700..

Pratsenko, S. A.; Bildyukevich, A. V. Structure of casting solutions and its effect on the characteristics of polyamide membranes. Polym. Sci. Ser. A (in Russian) 1994 , 36 , 457–460..

Bildyukevich, A. V.; Pratsenko, S. A.; Plisko, T. V. Inﬂuence of pore-generators on properties of polyethersulfone membranes. Chem. Technol . (in Russian) 2012 , 13 , 174–178..

Feng, Y.; Han, G.; Chung, T. Sh.; Weber, M.; Widjojo, N.; Maletzko, Ch. Effects of polyethylene glycol on membrane formation and properties of hydrophilic sulfonated polyphenylenesulfone (sPPSU) membranes. J. Membr. Sci. 2017 , 531 , 27−35..

Jansen, J. C.; Buonomenna, M. G.; Figoli, A.; Drioli, E. Asymmetric membranes of modified poly(ether ether ketone) with an ultra-thin skin for gas and vapour separations. J. Membr. Sci. 2006 , 272 , 188−197..

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