Fluorinated Monodisperse Microporous Microspheres: Formation Mechanism, Assembly, and Molecular Separation

Si-Yu Wang; Xin-Rui Xu; Xin-Xin Qiu; Xiao-Li Huang; Xin-Qi Wang; Zhi-Yong Chen

doi:10.1007/s10118-024-3239-9

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Fluorinated Monodisperse Microporous Microspheres: Formation Mechanism, Assembly, and Molecular Separation

RESEARCH ARTICLE | Updated：2024-12-31

- Fluorinated Monodisperse Microporous Microspheres: Formation Mechanism, Assembly, and Molecular Separation
- Fluorinated Monodisperse Microporous Microspheres: Formation Mechanism, Assembly, and Molecular Separation
- 高分子科学（英文） 2025年43卷第1期页码：162-176
- Affiliations：
  
  Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China
- Author bio：
  
  chm_chenzy@ujn.edu.cn
- Funds：
  
  This work was financially supported by Natural Science Foundation of Shandong Province (No. ZR2022MB033), Science and Technology Bureau of Jinan City (No. 2021GXRC105) and University of Jinan Disciplinary Cross-Convergence Construction Project 2023 (No. XKJC-202302).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3239-9.
- DOI：10.1007/s10118-024-3239-9
  中图分类号：
- 收稿：2024-07-28，
  
  修回：2024-09-15，
  
  录用：2024-09-17，
  
  网络首发：2024-11-14，
  
  纸质出版：2025-01-01
- Accepted：
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Wang, S. Y.; Xu, X. R.; Qiu, X. X.; Huang, X. L.; Wang, X. Q.; Chen, Z. Y. Fluorinated monodisperse microporous microspheres: formation mechanism, assembly, and molecular separation. Chinese J. Polym. Sci. 2025, 43, 162–176

Si-Yu Wang, Xin-Rui Xu, Xin-Xin Qiu, et al. Fluorinated Monodisperse Microporous Microspheres: Formation Mechanism, Assembly, and Molecular Separation[J]. Chinese Journal of Polymer Science, 2025, 43(1): 162-176.
Wang, S. Y.; Xu, X. R.; Qiu, X. X.; Huang, X. L.; Wang, X. Q.; Chen, Z. Y. Fluorinated monodisperse microporous microspheres: formation mechanism, assembly, and molecular separation. Chinese J. Polym. Sci. 2025, 43, 162–176 DOI： 10.1007/s10118-024-3239-9.

Si-Yu Wang, Xin-Rui Xu, Xin-Xin Qiu, et al. Fluorinated Monodisperse Microporous Microspheres: Formation Mechanism, Assembly, and Molecular Separation[J]. Chinese Journal of Polymer Science, 2025, 43(1): 162-176. DOI： 10.1007/s10118-024-3239-9.

摘要

Fluorinated monodisperse microporous microspheres with superhydrophobicity can be fabricated by one-step approach and the fluorinated microspheres column achieves efficient separation of the mixture of target compounds.

Abstract

The construction of monodisperse microporous organic microspheres is deemed a challenging issue

primarily due to the difficulty in achieving both high microporosity and uniformity within the microspheres. In this study

a series of fluorinated monodisperse microporous microspheres are fabricated by solvothermal precipitation polymerization. The resulting fluorous methacrylate-based microspheres achieved higher than 400 m

/g surface area

along w

ith a yield of over 90% for the microspheres. Through comprehensive characterization and simulation methods

we discovered that the introduction of fluorous methacrylate monomers at high loading levels is the key factor contributing to the formation of the microporosity within the microspheres. The controlled temperature profile was found to be advantageous for achieving a high yield of microspheres and increased uniformity. Two-dimensional assemblies of these fluorinated microsphere arrays exhibited superhydrophobicity

superolephilicity

and water sliding angles below 10°. Furthermore

a three-dimensional assembly of the fluorinated microporous microsphere in a chromatographic column demonstrated significant improvement in the separation of Engelhardt agent compared to commercial columns. Our work offers a novel approach to constructing fluorinated monodisperse microporous microspheres for advanced applications.

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references

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