A Strong, Tough, and Self-Healing Strengthening Thioctic Acid-based Elastomer for Highly Reliable Flexible Strain Sensor

Xin-Yu Chen; Yu-Bing Fu; Xue-Ling Yan; Lan Liu

doi:10.1007/s10118-024-3210-9

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A Strong, Tough, and Self-Healing Strengthening Thioctic Acid-based Elastomer for Highly Reliable Flexible Strain Sensor

RESEARCH ARTICLE | Updated：2024-09-23

- A Strong, Tough, and Self-Healing Strengthening Thioctic Acid-based Elastomer for Highly Reliable Flexible Strain Sensor
- A Strong, Tough, and Self-Healing Strengthening Thioctic Acid-based Elastomer for Highly Reliable Flexible Strain Sensor
- 高分子科学（英文版） 2024年42卷第10期页码：1610-1618
- Affiliations：
  
  School of Materials Science and Engineering, Key Lab of Guangdong Province for High Property and Functional Polymer Materials, South China University of Technology, Guangzhou 510641, China
- Author bio：
  
  psliulan@scut.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 52073099), the Guangdong Basic and Applied Basic Research Foundation (No. 2024A1515010847) and the Guangdong Project of R&D Plan in Key Areas (No. 2020B010180001).
- DOI：10.1007/s10118-024-3210-9
  中图分类号：
- 收稿：2024-04-30，
  
  修回：2024-06-27，
  
  录用：2024-07-19，
  
  网络首发：2024-08-27，
  
  纸质出版：2024-10-01
- Accepted：
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Chen, X. Y.; Fu, Y. B.; Yan, X. L.; Liu, L. A strong, tough, and self-healing strengthening thioctic acid-based elastomer for highly reliable flexible strain sensor. Chinese J. Polym. Sci. 2024, 42, 1610–1618

Xin-Yu Chen, Yu-Bing Fu, Xue-Ling Yan, et al. A Strong, Tough, and Self-Healing Strengthening Thioctic Acid-based Elastomer for Highly Reliable Flexible Strain Sensor[J]. Chinese Journal of Polymer Science, 2024, 42(10): 1610-1618.
Chen, X. Y.; Fu, Y. B.; Yan, X. L.; Liu, L. A strong, tough, and self-healing strengthening thioctic acid-based elastomer for highly reliable flexible strain sensor. Chinese J. Polym. Sci. 2024, 42, 1610–1618 DOI： 10.1007/s10118-024-3210-9.

Xin-Yu Chen, Yu-Bing Fu, Xue-Ling Yan, et al. A Strong, Tough, and Self-Healing Strengthening Thioctic Acid-based Elastomer for Highly Reliable Flexible Strain Sensor[J]. Chinese Journal of Polymer Science, 2024, 42(10): 1610-1618. DOI： 10.1007/s10118-024-3210-9.

摘要

We have developed the PAxEy supramolecular elastomers based on the thermal growth of ion clusters and dynamic disulfide polymer frameworks

which simultaneously exhibit excellent strength and toughness

admirable self-healing properties

and good biocompatibility.

Abstract

Elastomers with high strength and toughness

excellent self-healing properties

and biocompatibility have broad application prospects in wearable electronics and other fields

but preparing it remains a challenge. In this work

we propose a highly adaptable strategy by introducing the small molecule crosslinking agent of triethanolamine (TEA) to the poly(thioctic acid) (PTA) chains and preparing the PA

elastomers using a simple synthesis step. This strategy stabilizes the PTA chains by constructing multiple non-covalent cross-linked dynamic networks

endowing materials with excellent strength and toughness (tensile strength of 288 kPa

toughness of 278.2 kJ/m

)

admirable self-healing properties (self-healing efficiency of 121.6% within 7 h at 70 °C)

and good biocompatibility. The PA

elastomers can also be combined with MWNTs to become flexible strain sensors

which can be used to monitor human

joint movements with high sensitivity

repeatable responses

and stability.

关键词

Keywords

references

Wu, H. C.; Nikzad, S.; Zhu, C. X.; Yan, H. P.; Li, Y.; Niu, W. J.; Matthews, J. R.; Xu, J.; Matsuhisa, N.; Arunachala, P. K.; Rastak, R.; Linder, C.; Zheng, Y. Q.; Toney, M. F.; He, M. Q.; Bao, Z. N. Highly stretchable polymer semiconductor thin films with multi-modal energy dissipation and high relative stretchability. Nat. Commun. 2023 , 14 , 8382..

Wang, D.; Xu, J. H.; Chen, J. Y.; Hu, P.; Wang, Y.; Jiang, W.; Fu, J. J. Transparent, mechanically strong, extremely tough, self-recoverable, healable supramolecular elastomers facilely fabricated via dynamic hard domains design for multifunctional applications. Adv. Funct. Mater. 2020 , 30 , 1907109..

Guan, T. T.; Wang, X. H.; Zhu, Y. L.; Qian, L.; Lu, Z. Y.; Men, Y. F.; Li, J.; Wang, Y. T.; Sun, J. Q. Mechanically robust skin-like poly(urethane-urea) elastomers cross-linked with hydrogen-bond arrays and their application as high-performance ultrastretchable conductors. Macromolecules 2022 , 55 , 5816−5825..

Kim, Y. M.; Kwon, J. H.; Kim, S.; Choi, U. H.; Moon, H. C. Ion-cluster-mediated ultrafast self-healable ionoconductors for reconfigurable electronics. Nat. Commun. 2022 , 13 , 3769..

Zhao, Y. Y.; Ohm, Y.; Liao, J. H.; Luo, Y. C.; Cheng, H. Y.; Won, P.; Roberts, P.; Carneiro, M. R.; Islam, M. F.; Ahn, J. H.; Walker, L. M.; Majidi, C. A self-healing electrically conductive organogel composite. Nat. Electron. 2023 , 6 , 206−215..

Khatib, M.; Zohar, O.; Haick, H. Self-healing soft sensors: from material design to implementation. Adv. Mater. 2021 , 33 , 2004190..

Shen, Z. Q.; Zhang, Z. L.; Zhang, N. B.; Li, J. H.; Zhou, P. W.; Hu, F. Q.; Rong, Y.; Lu, B. Y.; Gu, G. Y. High-stretchability, ultralow-hysteresis conductingpolymer hydrogel strain sensors for soft machines. Adv. Mater. 2022 , 34 , 2203650..

Xiang, H.; Li, X. X.; Wu, B. H.; Sun, S. T.; Wu, P. Y. Highly damping and self-healable ionic elastomer from dynamic phase separation of sticky fluorinated polymers. Adv. Mater. 2023 , 35 , 220958 1..

Kim, Y.; Zhao, X. H. Magnetic soft materials and robots. Chem. Rev. 2022 , 122 , 5317−5364..

Koo, J. H.; Kim, D. C.; Shim, H. J.; Kim, T. H.; Kim, D. H. Flexible and stretchable smart display: materials, fabrication, devicedesign, and system integration. Adv. Funct. Mater. 2018 , 28 , 1801834..

Qin, B.; Wang, J. C.; Xia, J. H. Clear viscoelastic film based on low-hard-segment silicone polyurea elastomers for flexible display applications. ACS Appl. Polym. Mater. 2024 , 6 , 1674−1687..

Yin, L.; Cao, M. Z.; Kim, K. N.; Lin, M. Y.; Moon, J. M.; Sempionatto, J. R.; Yu, J. L.; Liu, R. X.; Wicker, C.; Trifonov, A.; Zhang, F. Y.; Hu, H. J.; Moreto, J. R.; Go, J.; Xu, S.; Wang, J. S. A stretchableepidermal sweat sensing platform with an integrated printed battery and electrochromic display. Nat. Electron. 2022 , 5 , 694−705..

Yan, X.; Chen, S.; Zhang, G.; Shi, W.; Peng, Z.; Liu, Z.; Chen, Y.; Huang, Y.; Liu, L. Highly breathable, surface-hydrophobic and wet-adhesive silk based epidermal electrode for long-term electrophysiolo gical monitoring. Compos. Sci. Technol. 2022 , 230 , 109751..

Markvicka, E. J.; Bartlett, M. D.; Huang, X.; Majidi, C. An autonomously electrically self-healing liquid metal-elastomer composite for robust soft-matter robotics and electronics. Nat. Mater. 2018 , 17 , 618−624..

Wang, X. Y.; Zhao, M. Y.; Zhang, L.; Li, K.; Wang, D.; Zhang, L.; Zhang, A. M.; Xu, Y. Liquid metal bionic instant self-healing flexible electronics with full recyclability and high reliability. Chem. Eng. J. 2022 , 431 , 133965..

Dang, C.; Wang, M.; Yu, J.; Chen, Y.; Zhou, S. H.; Feng, X.; Liu, D. T.; Qi, H. S. Transparent, highly stretchable, rehealable, sensing, and fully recyclable ionic conductors fabricated by one-step polymerization based on a small biological molecule. Adv. Funct. Mater. 2019 , 29 , 1902467..

Gao, J. X.; Zhang, Q.; Wu, B.; Gao, X. D.; Liu, Z. Y.; Yang, H. Y.; Yuan, J. K.; Huang, J. J. Mussel-inspired, underwater self-healing ionoelastomers based on α -lipoic acid for iontronics. Small 2023 , 19 , 2207334..

Lai, J. C.; Jia, X. Y.; Wang, D. P.; Deng, Y. B.; Zheng, P.; Li, C. H.; Zuo, J. L.; Bao, Z. N. Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers. Nat. Commun. 2019 , 10 , 1−9..

Lai, Y.; Kuang, X.; Zhu, P.; Huang, M. M.; Dong, X.; Wang, D. J. Colorless, transparent, robust, and fast scratch-self-healing elastomers via a phase-locked dynamic bonds design. Adv. Mater. 2018 , 30 , 1802556..

Kim, S. M.; Jeon, H.; Shin, S. H.; Park, S. A.; Jegal, J.; Hwang, S. Y.; Oh, D. X.; Park, J. Superior toughness and fast self-healing at room temperature engineered by transparent elastomers. Adv. Mater. 2017 , 29 , 1705145..

Ji, S.; Cao, W.; Yu, Y.; Xu, H. Visible-light-induced self-healing diselenide-containing polyurethane elastomer. Adv. Mater. 2015 , 27 , 7740−7745..

Kumar Raut, S.; Sarkar, S.; Mondal, P.; Meldrum, A.; Singha, N. K. Covalent adaptable network in an anthracenyl functionalised non-olefinic elastomer; a new class of self-healing elastomer coupled with fluorescence switching. Chem. Eng. J. 2023 , 453 , 139641..

Foster, J. C.; Cook, A. W.; Monk, N. T.; Jones, B. H.; Appelhans, L. N.; Redline, E. M.; Leguizamon, S. C. Continuous additive manufacturing using olefin metathesis. Adv. Sci. 2022 , 9 , 2200770..

Fu, Y. B.; Chen, S.; Chen, X. Y.; Zheng, H. X.; Yan, X. L.; Liu, Z. L.; Wang, M. T.; Liu, L. A Hierarchical energy dissipated structure enabled strong, ultra-tough, and sustainable adhesives. Adv. Funct. Mater . 2024 , 34 , 2314561..

Zheng, H. X.; Chen, S.; Fu, Y. B.; Chen, X. Y.; Zhang, G. P.; Liu, L. Robust dynamic epoxy adhesives with high environmental tolerance enabled by the coordination of small-molecule coupling agents with boroxine. ACS Appl. Polym. Mater. 2023 , 5 , 9346−9353..

Chen, X. C.; Chen, S.; Chen, X. Y.; Zheng, H. X.; Fu, Y. B.; Liu, F.; Liu, Q.; Zhang, G. P.; Liu, L. Robust, high-temperature and solvent tolerant, yet detachable polyimide adhesives enabled by dynamic boroxines. Surf. Interfaces 2023 , 41 , 103270..

Dong, B.; Xu, G.; Yang, R.; Guo, X.; Wang, Q. Preparation of block copolymers by a sequential tr ansesterification strategy: a feasible route for upcycling end-of-life polyester plastics to elastomers. Macromolecules 2023 , 56 , 10143−10152..

Ying, H.; Zhang, Y.; Cheng, J. Dynamic urea bond for the design of reversible and self-healing polymers. Nat. Commun. 2014 , 5 , 3218..

Vallin, A.; Battegazzore, D.; Damonte, G.; Fina, A.; Monticelli, O. On the development of nanocomposite covalent associative networks based on polycaprolactone and reduced graphite oxide. Nanomaterials 2022 , 12 , 3744..

Hentschel, J.; Kushner, A. M.; Ziller, J.; Guan, Z. Self-healing supramolecular block copolymers. Angew. Chem. Int. Ed. 2012 , 51 , 10561−10565..

Ma, J.; Wen, S.; Zhou, Z. Bioinspired thermoplastic elastomer with flexible, self-healing capabilities. Langmuir 2022 , 38 , 8862−8870..

Chen, L.; Zhao, H. B.; Ni, Y.-P.; Fu, T.; Wu, W.-S.; Wang, X. L.; Wang, Y. Z. 3D printable robust shape memory PET copolyesters with fire safety via π -stacking and synergistic crosslinking. J. Mater. Chem. A 2019 , 7 , 17037−17045..

Liu, J.; Scherman, O. A. Cucurbit[n ] uril supramolecular hydrogel networks as tough and healable adhesives. Adv. Funct. Mater. 2018 , 28 , 1800848..

Lai, J. C.; Li, L.; Wang, D. P.; Zhang, M. H.; Mo, S. R.; Wang, X.; Zeng, K. Y.; Li, C. H.; Jiang, Q.; You, X. Z.; Zuo, J. L. A rigid and healable polymer cross-linked by weak but abundant Zn(II)-carboxylate interactions. Nat. Commun. 2018 , 9 , 2725..

Eom, Y.; Kim, S. M.; Lee, M.; Jeon, H.; Park, J.; Lee, E. S.; Hwang, S. Y.; Park, J.; Oh, D. X. Mechano-responsive hydrogen-bonding array of thermoplastic polyurethane elastomer captures both strength and self-healing. Nat. Commun. 2021 , 12 , 621..

Deng, Y. X.; Zhang, Q.; Feringa, B. L.; Tian, H.; Qu, D. H. Toughening a self-healable supramolecular polymer by ionic cluster-enhanced iron-carboxylate complexes. Angew. Chem. Int. Ed. 2020 , 59 , 5278−5283..

Matsuda, T.; Kawakami, R.; Namba, R.; Nakajima, T.; Gong, J. P. Mechanoresponsive self-gr owing hydrogels inspired by muscle training. Science 2019 , 363 , 504−508..

Zhang, Q.; Shi, C. Y.; Qu, D. H.; Long, Y. T.; Feringa, B.; Tian, H. Exploring a naturally tailored small molecule for stretchable, self-healing, and adhesive supramolecular polymers. Sci. Adv. 2018 , 4 , 1−8..

Rivero, G.; Nguyen, L. T. T.; Hillewaere, X. K. D.; Du Prez, F. E. One-pot thermo-remendable shape memory polyurethanes. Macromolecules 2014 , 47 , 2010−2018..

Amamoto, Y.; Otsuka, H.; Takahara, A.; Matyjaszewski, K. Self-healing of covalently cross-linked polymers by reshuffling thiuram disulfide moieties in air under visible light. Adv. Mater. 2012 , 24 , 3975−3980..

Chen, S.; Chen, X. Y.; Luo, K. Y.; Yang, W. W.; Yan, X. L.; Liu, L. Thermo-growing ion clusters enabled healing strengthening and tough adhesion for highly reliable skin electronics. Mater. Horiz. 2024 , 11 , 1923−1933..

Zhang, Q.; Deng, Y. X.; Luo, H. X.; Shi, C. Y.; Geise, G. M.; Feringa, B. L.; Tian, H.; Qu, D. H. Assembling a na tural small molecule into a supramolecular network with high structural order and dynamic functions. J. Am. Chem. Soc. 2019 , 141 , 12804−12814..

Shi, C. Y.; Zhang, Q.; Wang, B. S.; Chen, M.; Qu, D. H. Intrinsically photopolymerizable dynamic polymers derived from a natural small molecule. ACS Appl. Mater. Interfaces 2021 , 13 , 44860−44867..

Shi, Y.; Wu, B.; Sun, S.; Wu, P. Aqueous spinning of robust, self-healable, and crack-resistant hydrogel microfibers enabled by hydrogen bond nanoconfinement. Nat. Commun. 2023 , 14 , 1370..

Deng, Y.; Zhang, Q.; Qu, D. H.; Tian, H.; Feringa, B. L. A chemically recyclable crosslinked polymer network enabled by orthogonal dynamic covalent chemistry. Angew. Chem. Int. Ed. 2022 , 61 , e202209100..

Dashtimoghadam, E.; Maw, M.; Keith, A. N.; Vashahi, F.; Kempkes, V.; Gordievskaya, Y. D.; Kramarenko, E. Y.; Bersenev, E. A.; Nikitina, E. A.; Ivanov, D. A.; Tian, Y.; Dobrynin, A. V.; Vatankhah-Varnosfaderani, M.; Sheiko, S. S. Super-soft, firm, and strong elastomers toward replication of tissue viscoelastic response. Mater. Horiz. 2022 , 9 , 3022−3030..

Yang, Y.; Urban, M. W. Self-healing polymeric materials. Chem. Soc. Rev. 2013 , 42 , 7446−7467..

Shi, C. Y.; Zhang, Q.; Wang, B. S.; He, D. D.; Tian, H.; Qu, D. H. Highly ordered supramolecular assembled networks tailored by bioinspired h-bonding confinement for recyclable ion-transport materials. CCS Chem. 2023 , 5 , 1422−1432..

Shi, C. Y.; He, D. D.; Zhang, Q.; Tong, F.; Shi, Z. T.; Tian, H.; Qu, D. H. Robust and dynamic underwater adhesives enabled by catechol-functionalized poly(disulfides) network. Natl. Sci. Rev. 2023 , 10 , nwac139..

Yang, D.; Zhao, K.; Yang, R.; Zhou, S. W.; Chen, M.; Tian, H.; Qu, D. H. A Rational design of bio-derived disulfide CANs for wearable capacitive pressure sensor. Adv. Mater . 2024 , 36 , 2403880..

Xu, L.; Huang, Z.; Deng, Z.; Du, Z.; Sun, T. L.; Guo, Z. H.; Yue, K. A Transparent, highly stretchable, solvent-resistant, recyclable multifunctional ionogel with underwater self-healing and adhesion for reliable strain sensors. Adv. Mater. 2021 , 33 , 2105306..

Hou, K. X.; Zhao, S. P.; Wang, D. P.; Zhao, P. C.; Li, C. H.; Zuo, J. L. A Puncture-resistant and self-healing conductive gel for multifunctional electronic skin. Adv. Funct. Mater. 2021 , 31 , 2107006..

Sun, P.; Wang, Y.; Huang, Z.; Yang, X.; Dong, F.; Xu, X.; Liu, H. Limonene-thioctic acid-ionic liquid polymer: A self-healing and antibacterial material for movement detection sensor. Ind. Crops Prod. 2022 , 189 , 115802..

Chai, C.; Guo, Y.; Huang, Z.; Zhang, Z.; Yang, S.; Li, W.; Zhao, Y.; Hao, J. Antiswelling and durable adhesion biodegradable hydrogels for tissue repairs and strain sensors. Langmuir 2020 , 36 , 10448−10459..

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