Luminescent Composite Films Based on Mechanically Strong Ladder-like Polyphenylsilsesquioxane and Oligophenyleuropiumsiloxane

E. E. Kim; T. O. Ershova; A. S. Belova; D. A. Khanin; E. V. Bashkova; G. G. Nikiforova; Yu. N. Kononevich; A. A. Anisimov; O. I. Shchegolikhina; A. M. Muzafarov

doi:10.1007/s10118-024-3190-9

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Luminescent Composite Films Based on Mechanically Strong Ladder-like Polyphenylsilsesquioxane and Oligophenyleuropiumsiloxane

RESEARCH ARTICLE | Updated：2024-11-04

- Luminescent Composite Films Based on Mechanically Strong Ladder-like Polyphenylsilsesquioxane and Oligophenyleuropiumsiloxane
- Luminescent Composite Films Based on Mechanically Strong Ladder-like Polyphenylsilsesquioxane and Oligophenyleuropiumsiloxane
- 高分子科学（英文版） 2024年42卷第11期页码：1793-1801
- Affiliations：
  
  a.A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119334, Russian Federation
  b.Tula State Lev Tolstoy Pedagogical University, Tula 300026, Russian Federation
  c.V. Topchiev Institute of Petrochemical Synthesis Russian Academy of Sciences, Moscow 119991, Russian Federation
  d.Moscow Institute of Physics and Technology (National Research University), Dolgoprudny, Moscow Region 141700, Russian Federation
  e.N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow 117393, Russian Federation
- Author bio：
  
  anisimov.ineos@gmail.com
- Funds：
  
  The study was financially supported by the Russian Science Foundation (No. 23-79-10256). Characterization of compounds were performed with financial support from the Ministry of Scienceand Higher Education of the Russian Federation (No. 075-00277-24-00) using the equipment of the Center for Molecular Composition Studies of INEOS RAS.
- DOI：10.1007/s10118-024-3190-9
  中图分类号：
- 收稿：2024-03-25，
  
  修回：2024-05-29，
  
  录用：2024-06-10，
  
  网络首发：2024-09-13，
  
  纸质出版：2024-11-30
- Accepted：
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Kim, E. E.; Ershova, T. O.; Belova, A. S.; Khanin, D. A.; Bashkova, E. V.; Nikiforova, G. G.; Kononevich, Y. N.; Anisimov, A. A.; Shchegolikhina, O. I.; Muzafarov, A. M. Luminescent composite films based on mechanically strong ladder-like polyphenylsilsesquioxane and oligophenyleuropiumsiloxane. Chinese J. Polym. Sci. 2024, 42, 1793–1801

E. E. Kim, T. O. Ershova, A. S. Belova, et al. Luminescent Composite Films Based on Mechanically Strong Ladder-like Polyphenylsilsesquioxane and Oligophenyleuropiumsiloxane[J]. Chinese Journal of Polymer Science, 2024, 42(11): 1793-1801.
Kim, E. E.; Ershova, T. O.; Belova, A. S.; Khanin, D. A.; Bashkova, E. V.; Nikiforova, G. G.; Kononevich, Y. N.; Anisimov, A. A.; Shchegolikhina, O. I.; Muzafarov, A. M. Luminescent composite films based on mechanically strong ladder-like polyphenylsilsesquioxane and oligophenyleuropiumsiloxane. Chinese J. Polym. Sci. 2024, 42, 1793–1801 DOI： 10.1007/s10118-024-3190-9.

E. E. Kim, T. O. Ershova, A. S. Belova, et al. Luminescent Composite Films Based on Mechanically Strong Ladder-like Polyphenylsilsesquioxane and Oligophenyleuropiumsiloxane[J]. Chinese Journal of Polymer Science, 2024, 42(11): 1793-1801. DOI： 10.1007/s10118-024-3190-9.

摘要

New luminescent composites based on ladder-like olyphenylsilsesquioxane were synthesized and fully investigated. Oligophenyleuropiumsiloxane showing good compatibility with the matrix was utilized as luminescent filler

and organosilicon

-diketones were used as “antenna” ligands. Composites demonstrate high luminescence intensity

transparency

mechanical strength and thermal stability

as well as sensitivity to ammonia vapors.

Abstract

Nowadays organosilicon luminescent materials are of increasing interest due to the variety of their synthetic or modification techniques and application fields. Ladder polyphenylsilsesquioxanes (L-PPSQ) are a unique class of organosilicon polymers

which can be ideal matrices for the luminescent composites due to their high thermal stability

optical transparency and mechanical strength. In this work

new mechanically strong

heat-resistant

transparent and sensitive to ammonia vapor luminescent composite films based on L-PPSQ have been obtained. As the source of Europium ions oligophenyleuropiumsiloxane was used

demonstrating perfect compatibility to the matrix due to the similar nature. To improve luminescent properties of the films

new organosilicon ligands were introduced into the composites and their influence on the properties of the materials was studied. Valuable properties of described composites may allow their further application as multifunctional coatings.

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references

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