Sequence-Controlled Synthesis of Alternating Poly(ester amide)s using Water as Control Agent in One-Pot

Tao Liu; Fang-Fang Niu; Kan Cheng; Yu-Min Xia; Bo-Mou Ma; Xue-Li Wang; Jian-Yong Yu; Yong He

doi:10.1007/s10118-024-3185-6

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Sequence-Controlled Synthesis of Alternating Poly(ester amide)s using Water as Control Agent in One-Pot

RAPID COMMUNICATION | Updated：2024-08-06

- Sequence-Controlled Synthesis of Alternating Poly(ester amide)s using Water as Control Agent in One-Pot
- Sequence-Controlled Synthesis of Alternating Poly(ester amide)s using Water as Control Agent in One-Pot
- 高分子科学（英文版） 2024年42卷第8期页码：1015-1020
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  b.Innovation Center for Textile Science and Technology, Donghua University, Shanghai 201620, China
- Author bio：
  
  mabomou@dhu.edu.cn (B.M.M.)
  yhe@dhu.edu.cn (Y.H.)
- Funds：
  
  This work was financially supported by the innovation funding from WeiQiao Group (Nos. H2872307 and H2872305) and Fundamental Research Funds for the Central Universities and Graduate Student Innovation Fund of Donghua University (No. CUSF-DH-D-2024004).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3185-6.
- DOI：10.1007/s10118-024-3185-6
  中图分类号：
- 收稿：2024-04-29，
  
  修回：2024-05-27，
  
  录用：2024-06-05，
  
  网络首发：2024-07-11，
  
  纸质出版：2024-08-01
- Accepted：
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Liu, T.; Niu, F. F.; Cheng, K.; Xia, Y. M.; Ma, B. M.; Wang, X. L.; Yu, J. Y.; He, Y. Sequence-controlled synthesis of alternating poly(ester amide)s using water as control agent in one-pot. Chinese J. Polym. Sci. 2024, 42, 1015–1020

Tao Liu, Fang-Fang Niu, Kan Cheng, et al. Sequence-Controlled Synthesis of Alternating Poly(ester amide)s using Water as Control Agent in One-Pot[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1015-1020.
Liu, T.; Niu, F. F.; Cheng, K.; Xia, Y. M.; Ma, B. M.; Wang, X. L.; Yu, J. Y.; He, Y. Sequence-controlled synthesis of alternating poly(ester amide)s using water as control agent in one-pot. Chinese J. Polym. Sci. 2024, 42, 1015–1020 DOI： 10.1007/s10118-024-3185-6.

Tao Liu, Fang-Fang Niu, Kan Cheng, et al. Sequence-Controlled Synthesis of Alternating Poly(ester amide)s using Water as Control Agent in One-Pot[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1015-1020. DOI： 10.1007/s10118-024-3185-6.

摘要

In this work

the one-pot preparation of quasi-alternating PEAs was achieved by introducing water to inhibit the esterification reaction during the amidation reaction stage and subsequently promoting the esterification reaction by removing water under vacuum. The synthesized PEAs are comparable to the PEAs synthesized by traditional method.

Abstract

Poly(ester amide)s (PEAs) attract much attention as a new kind of biodegradable polymers. However

the synthesis of PEAs with sequence-regulated chain structures is still complicated due to the multistep polymerization

high monomer purity

as well as the usage of organic solvents

which greatly inhibits its development and applications. Herein

a one-pot strategy without solvent was developed to synthesize the alternating PEA from

-amino alcohol and dicarboxylic acid by sequential polycondensation

where water was used as the controlling agent for amidation and esterification. Specifically

the amidation and esterification were controlled to proceed in turn by adding or removing water

realizing the one-pot preparation of alternating PEAs. The resultant PEA is characterized by

H- and

C-NMR

and its chain structure is confirmed to be highly quasi-alternating similar to alternating PEAs prepared by classical methods The evaluations from DSC and DMA demonstrate that the properties of quasi-alternating PEA (

=102 °C

=30 J·g

−1

) are far superior to those of random PEA (

=72 °C

1 J·g

−1

关键词

Keywords

references

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