High Performance Microwave Absorption Material Based on Metal-Backboned Polymer

Jia-Ning Xu; Kai-Wen Zeng; Yi-Feng Zhang; Yi-Bei Yang; Zi-Wei Liu; Yue Liu; Jia-Jia Wang; Kai-Lin Zhang; Yan-Ru-Zhen Wu; Hao Sun; Hui-Sheng Peng

doi:10.1007/s10118-024-3181-x

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High Performance Microwave Absorption Material Based on Metal-Backboned Polymer

RESEARCH ARTICLE | Updated：2024-12-03

- High Performance Microwave Absorption Material Based on Metal-Backboned Polymer
- High Performance Microwave Absorption Material Based on Metal-Backboned Polymer
- 高分子科学（英文版） 2024年42卷第12期页码：1881-1887
- Affiliations：
  
  a.State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Institute of Fiber Materials and Devices, and Laboratory of Advanced Materials, Fudan University, Shanghai 200438, China
  b.Frontiers Science Center for Transformative Molecules, School of Chemistry and Chemical Engineering, and Zhangjiang Institute for Advanced Study, Shanghai Jiao Tong University, Shanghai 200240, China
- Author bio：
  
  penghs@fudan.edu.cn
- Funds：
  
  This work was financially supported by MOST (Nos. 2022YFA1203001 and 2022YFA1203002), NSFC (Nos. T2321003, 22335003 and 22105045) and STCSM (Nos. 21511104900 and 20JC1414902).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3181-x.
- DOI：10.1007/s10118-024-3181-x
  中图分类号：
- 收稿：2024-04-18，
  
  修回：2024-05-26，
  
  录用：2024-06-03，
  
  网络首发：2024-09-13，
  
  纸质出版：2024-12-01
- Accepted：
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Xu, J. N.; Zeng, K. W.; Zhang, Y. F.; Yang, Y. B.; Liu, Z. W.; Liu, Y.; Wang, J. J.; Zhang, K. L.; Wu, Y. R. Z.; Sun, H.; Peng, H. S. High performance microwave absorption material based on metal-backboned polymer. Chinese J. Polym. Sci. 2024, 42, 1881–1887

Jia-Ning Xu, Kai-Wen Zeng, Yi-Feng Zhang, et al. High Performance Microwave Absorption Material Based on Metal-Backboned Polymer[J]. Chinese Journal of Polymer Science, 2024, 42(12): 1881-1887.
Xu, J. N.; Zeng, K. W.; Zhang, Y. F.; Yang, Y. B.; Liu, Z. W.; Liu, Y.; Wang, J. J.; Zhang, K. L.; Wu, Y. R. Z.; Sun, H.; Peng, H. S. High performance microwave absorption material based on metal-backboned polymer. Chinese J. Polym. Sci. 2024, 42, 1881–1887 DOI： 10.1007/s10118-024-3181-x.

Jia-Ning Xu, Kai-Wen Zeng, Yi-Feng Zhang, et al. High Performance Microwave Absorption Material Based on Metal-Backboned Polymer[J]. Chinese Journal of Polymer Science, 2024, 42(12): 1881-1887. DOI： 10.1007/s10118-024-3181-x.

摘要

A new carbon/nickel microwave absorption material is produced from nickel-based metal-backboned polymers through a thermal reduction method. It shows a minimum reflection loss of −49.1 dB at 13.04 GHz due to the molecule-level nickel doping for stable heterogeneous interface between carbon and metal nickel regions.

Abstract

Metal-backboned polymers with anisotropy microstructures are promising for conductive

optoelectronic

and magnetic functional materials. However

the structure-property relationships governing the interplay between the chemical structure and electromagnetic property of the metal-backboned polymer have been rarely investigated. Here we report a carbon/nickel hybrid from metal-backboned polymer to serve as electromagnetic wave-absorbing materials

which exhibit high microwave absorption capacity and tunable absorption band. The presence of nickel backbones promote the generation of heterogeneous interfaces with carbon during calcination

thereby enhancing the wave-absorbing capacity of the carbon/nickel hybrid. The C/Ni hybrids show a minimal reflection loss of −49.1 dB at 13.04 GHz

and its frequency of the absorption band can be adjusted by controlling the thickness of the absorption layer.

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references

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