Upcycling of Poly(butylene adipate-<italic style="font-style: italic">co</italic>-terephthalate) into Dual Covalent Adaptable Networks through Chain Breaking-Crosslinking Strategy

Bin-Bo Wang; Rong Huang; Xin Wang; Tao Jiang; Yi Wang; Shuai Du; Fa-Lin Li; Jin Zhu; Song-Qi Ma

doi:10.1007/s10118-024-3179-4

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Upcycling of Poly(butylene adipate-co-terephthalate) into Dual Covalent Adaptable Networks through Chain Breaking-Crosslinking Strategy

RESEARCH ARTICLE | Updated：2024-09-23

- Upcycling of Poly(butylene adipate-co-terephthalate) into Dual Covalent Adaptable Networks through Chain Breaking-Crosslinking Strategy
- Upcycling of Poly(butylene adipate-co-terephthalate) into Dual Covalent Adaptable Networks through Chain Breaking-Crosslinking Strategy
- 高分子科学（英文版） 2024年42卷第10期页码：1505-1513
- Affiliations：
  
  a.Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China
  b.Key Laboratory of Bio-based Polymeric Materials Technology and Application of Zhejiang Province, Divisions of Polymers and Composites, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  c.University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  songqi.ma@jiangnan.edu.cn or msqhyd@126.com
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 52373007 and 52073296), Innovative Leading Talent of Taihu Lake Talent Plan in Wuxi City, Zhejiang Ten Thousand Talent Program, and Research startup fund from Jiangnan University.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3179-4.
- DOI：10.1007/s10118-024-3179-4
  中图分类号： M
- 收稿：2024-04-30，
  
  修回：2024-06-01，
  
  录用：2024-06-03，
  
  网络首发：2024-08-27，
  
  纸质出版：2024-10-01
- Accepted：
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Wang, B. B.; Huang, R.; Wang, X.; Jiang, T.; Wang, Y.; Du, S.; Li, F. L.; Zhu, J.; Ma, S. Q. Upcycling of poly(butylene adipate-co-terephthalate) into dual covalent adaptable networks through chain breaking-crosslinking strategy. Chinese J. Polym. Sci. 2024, 42, 1505–1513

Bin-Bo Wang, Rong Huang, Xin Wang, et al. Upcycling of Poly(butylene adipate-co-terephthalate) into Dual Covalent Adaptable Networks through Chain Breaking-Crosslinking Strategy[J]. Chinese Journal of Polymer Science, 2024, 42(10): 1505-1513. DOI: 10.1007/s10118-024-3179-4.
Wang, B. B.; Huang, R.; Wang, X.; Jiang, T.; Wang, Y.; Du, S.; Li, F. L.; Zhu, J.; Ma, S. Q. Upcycling of poly(butylene adipate-co-terephthalate) into dual covalent adaptable networks through chain breaking-crosslinking strategy. Chinese J. Polym. Sci. 2024, 42, 1505–1513 DOI： 10.1007/s10118-024-3179-4.

Bin-Bo Wang, Rong Huang, Xin Wang, et al. Upcycling of Poly(butylene adipate-co-terephthalate) into Dual Covalent Adaptable Networks through Chain Breaking-Crosslinking Strategy[J]. Chinese Journal of Polymer Science, 2024, 42(10): 1505-1513. DOI: 10.1007/s10118-024-3179-4. DOI：

摘要

Poly(butylene adipate-

-terephthalate) was efficiently upcycled into performance-enhanced dual covalent adaptable networks via chain breaking-crosslinking strategy while maintaining degradability and processability.

Abstract

Poly(butylene adipate-

-terephthalate) (PBAT)

a widely studied biodegradable material

has not effectively addressed the problem of plastic waste. Taking into consideration the cost-effectiveness

upcycling PBAT should take precedence over direct composting degradation. The present work adopts a chain breaking-crosslinking strategy

upcycling PBAT into dual covalent adaptable networks (CANs). During the chain-breaking stage

the ammonolysis between PBAT and polyethyleneimine (PEI) established the primary crosslinked network. Subsequently

styrene maleic anhydride copolymer (SMA) reacted with the hydroxyl group

culminating in the formation of dual covalent adaptable networks. In contrast to PBAT

the PBAT-dual-CANs exhibited a

notable Young's modulus of 239 MPa

alongside an inherent resistance to creep and solvents. Owing to catalysis from neighboring carboxyl group and excess hydroxyl groups

the PBAT-dual-CANs exhibited fast stress relaxation. Additionally

they could be recycled through extrusion and hot-press reprocessing

while retaining their biodegradability. This straightforward strategy offers a solution for dealing with plastic waste.

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references

Baca, D.; Monroy, R.; Castillo, M.; Elkhazraji, A.; Farooq, A.; Ahmad, R. Dioxins and plastic waste: a scientometric analysis and systematic literature review of the detect ion methods. Environ. Adv. 2023 , 13 , 100439..

Kaiser, K.; Schmid, M.; Schlummer, M. Recycling of polymer-based multilayer packaging: a review. Recycling 2018 , 3 , 1..

Li, H.; Aguirre-Villegas, H. A.; Allen, R. D.; Bai, X.; Benson, C. H.; Beckham, G. T.; Bradshaw, S. L.; Brown, J. L.; Brown, R. C.; Cecon, V. S.; Curley, J. B.; Curtzwiler, G. W.; Dong, S.; Gaddameedi, S.; García, J. E.; Hermans, I.; Kim, M. S.; Ma, J.; Mark, L. O.; Mavrikakis, M.; Olafasakin, O. O.; Osswald, T. A.; Papanikolaou, K. G.; Radhakrishnan, H.; Sanchez Castillo, M. A.; Sánchez-Rivera, K. L.; Tumu, K. N.; Van Lehn, R. C.; Vorst, K. L.; Wright, M. M.; Wu, J.; Zavala, V. M.; Zhou, P.; Huber, G. W. Expanding plastics recycling technologies: chemical aspects, technology status and challenges. Green Chem. 2022 , 24 , 8899−9002..

Naderi Kalali, E.; Lotfian, S.; Entezar Shabestari, M.; Khayatzadeh, S.; Zhao, C.; Yazdani Nezhad, H. A critical review of the current progress of plastic waste recycling technology in structural materials. Curr. Opin. Green Sust. 2023 , 40 , 100763..

Verma, R.; Vinoda, K. S.; Papireddy, M.; Gowda, A. N. S. Toxic pollutants from plastic waste- A review. Procedia Environ. Sci. 2016 , 35 , 701−708..

Canopoli, L.; Fidalgo, B.; Coulon, F.; Wagland, S. T. Physico-chemical properties of excavated plastic from landfill mining and current recycling routes. Waste Manage. 2018 , 76 , 55−67..

Roy, S.; Ghosh, T.; Zhang, W.; Rhim, J. W. Recent progress in PBAT-based films and food packaging applications: a mini-review. Food Chem. 2024 , 437 , 137822..

Elvers, D.; Song, C. H.; Steinbüchel, A.; Leker, J. Technology trends in biodegradable polymers: evidence from patent analysis. Polym. Rev. 2016 , 56 , 584−606..

Shah, M. Z.; Quraishi, M.; Sreejith, A.; Pandit, S.; Roy, A.; Khandaker, M. U. Sustainable degradation of synthetic plastics: a solution to rising environmental concerns. Chemosphere 2024 , 352 , 141451..

Luo, X.; Muttaqin, F.; Zhang, Y. Investigating non-petroleum-based biodegradable polymers as eco-friendly and sustainable materials in asphalt modification: a review on natural rubbers and natural oils. J. Clean. Prod. 2024 , 436 , 140483..

Wang, Y.; van Putten, R.; Tietema, A.; Parsons, J. R.; Gruter, G. M. Polyester biodegradability: importance and potential for optimisation. Green Chem. 2024 , 26 , 3698−3716..

Chan, Q.; Alias, S. A.; Quek, S. W.; Ng, C. Y.; Ku Marsilla, K. I. A review of the preparations, properties, and applications of smart biodegradable polymers. Polym. Plast. Technol. Mater. 2023 , 62 , 1273−1289..

Scaffaro, R.; Maio, A.; Sutera, F.; Gulino, E. F.; Morreale, M. Degradation and recycling of films based on biodegradable polymers: A short review. Polymers 2019 , 11 , 651..

Bartolucci, L.; Cordiner, S.; De Maina, E.; Kumar, G.; Mele, P.; Mulone, V.; Igliński, B.;Piechota, G., Sustainable valorization of bioplastic waste: a review on effective recycling routes for the most widely used biopolymers, Int. J. Mol. Sci . 2023 , 24 , 7696..

Shen, C. F.; Zhao, X.; Long, Y. W.; An, W. L.; Zhou, X. L.; Liu, X. H.; Xu, S. M.; Wang, Y. Z. Approach for the low carbon footprint of biodegradable plastic P BAT: Complete recovery of its every monomer via high-efficiency hydrolysis and separation. ACS Sustainable Chem. Eng. 2023 , 11 , 2005−2013..

.Wu, S. S.; Lu, H. J.; Li, Y. D.; Zhang, S. D.; Zeng, J. B. Unlocking the potential of poly(butylene succinate) through incorporation of vitrimeric network based on dynamic imine bonds. Chinese J. Polym. Sci. 2024 , 42 , 1414−1424..

Zhang, M. Q. Self-healing polymeric materials: on a winding road to success. Chinese J. Polym. Sci. 2022 , 40 , 1315−1316..

Liu, T.; Fei, M. E.; Zhao, B. M.; Zhang, J. W. Progress in biobased vitrimers. Acta Polymerica Sinica (in Chinese) 2020 , 51 , 817−832..

Zhou, X. W.; Huang, J.; Zhang, X. H.; Li, T.; Wang, Y.; Wang, S. B.; Xia, B. H.; Dong, W. F. Design of tough, yet strong, heat-resistant PLA/PBAT blends with reconfigurable shape memory behavior by engineering exchangeable covalent crosslinks. Chinese J. Polym. Sci. 2023 , 41 , 1868−1878..

Liu, X. H.; Xu, S. M.; Zhang, F.; Wang, X. L.; Wang, Y. Z. Chemical upcycling of polymeric materials. Acta Polymerica Sinica (in Chinese) 2022 , 53 , 1005−1022..

Liu, Y. B.; Xu, Z.; Zhang, Z. M.; Bao, R. Y.; Yang, M. B.; Yang, W. Blowing tough polylactide film enabled by the in situ construction of covalent adaptive networks with epoxidized soybean oil as dynamic crosslinks. Green Chem. 2023 , 25 , 5182−5194..

Maaz, M.; Riba-Bremerch, A.; Guibert, C.; Van Zee, N. J.; Nicolaÿ, R. Synthesis of polyethylene vitrimers in a single step: consequences of graft structure, reactive extrusion conditions, and processing aids. Macromolecules 2021 , 54 , 2213−2225..

Röttger, M.; Domenech, T.; van der Weegen, R.; Breuillac, A.; Nicolaÿ, R.; Leibler, L. High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis. Science 2017 , 356 , 62−65..

Jehanno, C.; Alty, J. W.; Roosen, M.; De Meester, S.; Dove, A. P.; Chen, E. Y. X.; Leibfarth, F. A.; Sardon, H. Critical advances and future opportunities in upcycling commodity polymers. Nature 2022 , 603 , 803−814..

Qiu, J. F.; Ma, S. Q.; Wang, S.; Tang, Z.; Li, Q.; Tian, A. P.; Xu, X. W.; Wang, B. B.; Lu, N.; Zhu, J. Upcycling of polyethylene terephthalate to continuously reprocessable vitrimers through reactive extrusion. Macromolecules 2021 , 54 , 703−712..

Kloxin, C. J.; Scott, T. F.; Adzima, B. J.; Bowman, C. N. Covalent adaptable networks (CANs): A unique paradigm in cross-linked polymers. Macromolecules 2010 , 43 , 2643−2653..

Fan, Z. Y.; Shi, Z. Z.; Ma, L.; Gong, P. J.; Bao, R. Y.; Yang, M. B.; Yang, W. Dynamic cross-linked poly(butylene adipate- co -terephthalate) for high-performance green foam. ACS Sustainable Chem. Eng. 2023 , 11 , 16354−16364..

Zheng, J. W.; Lu, J. W.; Yang, Z. X.; Liu, T. Fabrication of recyclable and biodegradable PBAT vitrimer via construction of highly dynamic cross-linked network. Polym. Degrad. Stabil. 2024 , 219 , 110602..

Wang, B. B.; Du, S.; Wang, Y.; Li, F. L.; Ding, Y.; Zhu, J.; Ma, S. Q. Efficient conversion of poly(butylene adipate- co -terephthalate) into covalent adaptable networks via a chain breaking-crosslinking strategy. Polym. Chem. 2023 , 14 , 4057−4063..

Han, J.; Liu, T.; Hao, C.; Zhang, S.; Guo, B. H.; Zhang, J. W. A catalyst-free epoxy vitrimer system based on multifunctional hyperbranched polymer. Macromolecules 2018 , 51 , 6789−6799..

Han, J. R.; Liu, T.; Zhang, S.; Hao, C.; Xin, J. N.; Guo, B. H.; Zhang, J. W. Hyperbranched polymer assisted curing and repairing of an epoxy coating. Ind. Eng. Chem.Res. 2019 , 58 , 6466−6475..

Delahaye, M.; Winne, J. M.; Du Prez, F. E. Internal catalysis in covalent adaptable networks: Phthalate monoester transesterification as a versatile dynamic cross-linking chemistry. J. Am. Chem. Soc. 2019 , 141 , 15277−15287..

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Upcycling of Poly(butylene adipate-co-terephthalate) into Dual Covalent Adaptable Networks through Chain Breaking-Crosslinking Strategy

Upcycling of Poly(butylene adipate-co-terephthalate) into Dual Covalent Adaptable Networks through Chain Breaking-Crosslinking Strategy

DOI：10.1007/s10118-024-3179-4

摘要

Abstract

关键词

Keywords

references