Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network <italic style="font-style: italic">via</italic> Electrosynthesis for High-performance Electrochromic Supercapacitors

Chun-Hui Du; Yu-Hua Xu; Hui Li; Zhi-Xin Wu; Han-Jun Yang; Xi-Mei Liu; Bao-Yang Lu; Guang-Ming Nie; Ge Zhang

doi:10.1007/s10118-024-3175-8

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Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network via Electrosynthesis for High-performance Electrochromic Supercapacitors

RESEARCH ARTICLE | Updated：2024-11-04

- Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network via Electrosynthesis for High-performance Electrochromic Supercapacitors
- Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network via Electrosynthesis for High-performance Electrochromic Supercapacitors
- 高分子科学（英文版） 2024年42卷第11期页码：1749-1757
- Affiliations：
  
  a.Jiangxi Key Lab of Flexible Electronics, Flexible Electronics Innovation Institute, Jiangxi Science & Technology Normal University, Nanchang 330013, China
  b.Key Laboratory of Optic-Electric Sensing and Analytical Chemistry for Life Science, MOE, State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
- Author bio：
  
  luby@jxstnu.edu.cn (B.Y.L.)
  gnie@qust.edu.cn (G.M.N.)
  zhangge20082006@126.com (G.Z.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 52103214, 52364039 and 51973102), Natural Science Foundation of Jiangxi Provincial (Nos. GJJ2201301 and 20232BAB202044), Natural Science Foundation of Shandong Province (Nos. ZR2022MB042 and ZR2019MB067), Innovation Ability Improvement Project of Science and Technology Small and Medium-Size Enterprise in Shandong Province (No. 2022TSGC1121), Qinghai Provincial Basic Research Program (No. 2021-ZJ-710), Scientific Fund of Jiangxi Science & Technology Normal University (No. 2022QNBJRC004) and Talent Fund of QUST (2020).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3175-8.
- DOI：10.1007/s10118-024-3175-8
  中图分类号：
- 收稿：2024-04-12，
  
  修回：2024-05-08，
  
  录用：2024-05-23，
  
  网络首发：2024-08-20，
  
  纸质出版：2024-11-30
- Accepted：
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Du, C. H.; Xu, Y. H.; Li, H.; Wu, Z. X.; Yang, H. J.; Liu, X. M.; Lu, B. Y.; Nie, G. M.; Zhang, G. Tough hydrogen bonding crosslinked poly(3-fluorothiophene) network via electrosynthesis for high-performance electrochromic supercapacitors. Chinese J. Polym. Sci. 2024, 42, 1749–1757

Chun-Hui Du, Yu-Hua Xu, Hui Li, et al. Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network via Electrosynthesis for High-performance Electrochromic Supercapacitors[J]. Chinese Journal of Polymer Science, 2024, 42(11): 1749-1757. DOI: 10.1007/s10118-024-3175-8.
Du, C. H.; Xu, Y. H.; Li, H.; Wu, Z. X.; Yang, H. J.; Liu, X. M.; Lu, B. Y.; Nie, G. M.; Zhang, G. Tough hydrogen bonding crosslinked poly(3-fluorothiophene) network via electrosynthesis for high-performance electrochromic supercapacitors. Chinese J. Polym. Sci. 2024, 42, 1749–1757 DOI： 10.1007/s10118-024-3175-8.

Chun-Hui Du, Yu-Hua Xu, Hui Li, et al. Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network via Electrosynthesis for High-performance Electrochromic Supercapacitors[J]. Chinese Journal of Polymer Science, 2024, 42(11): 1749-1757. DOI: 10.1007/s10118-024-3175-8. DOI：

摘要

A high-performance EC-SC material

PFT

with tough hydrogen bonding cross-linked intermolecular polymer network by one-step electrosynthesis is prepared.

PFT

-based FESDs can be used to visually monitor the energy storage state in real-time and maintain outstanding stability under mechanical distortion like bending.

Abstract

As a type of bi-functional device

electrochromic supercapacitors (EC-SCs) have attracted extensive attention in diverse applications such as flexible electronics. However

despite recent encouraging progress

rational design and development of high-performance EC-SC materials with desirable stability remain challenging for practical applications. Here

we propose a fluorination strategy to develop high-performance EC-SC materials w

ith tough hydrogen bonding cross-linked intermolecular polymer network by one-step electrosynthesis of 3-fluorothiophene. The electrosynthesized free-standing poly(3-fluorothiophene) (PFT

)

films simultaneously achieve high electrochromic performance (optical contrast 42% at 560 nm with reversible color changes between purple and blue)

and good capacitance property (290 F·g

−1

1 A·g

−1

)

as well as outstanding cyclic stability (

2% reduction after 20000 cycles). We further demonstrate the fabrication of PFT-based flexible electrochromic supercapacitor devices (FESDs)

and the resultant devices can be used to visually monitor the energy storage state in real-time and maintain outstanding stability under mechanical distortion like bending. Such a tough fluorination hydrogen bonding cross-linking strategy may provide a new design concept for high-performance EC-SC materials and reliable FESDs toward practical applications.

关键词

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references

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Tough Hydrogen Bonding Crosslinked Poly(3-fluorothiophene) Network via Electrosynthesis for High-performance Electrochromic Supercapacitors

DOI：10.1007/s10118-024-3175-8

摘要

Abstract

关键词

Keywords

references