Bolstering the Mechanical Robustness of Supramolecular Polymer Network by Mechanical Bond

Yuan-Hao Wang; Jing-Xi Deng; Jun Zhao; Yi Ding; Li Yang; Zhao-Ming Zhang; Xu-Zhou Yan

doi:10.1007/s10118-024-3168-7

Your Location：

Home >

Browse articles >

Bolstering the Mechanical Robustness of Supramolecular Polymer Network by Mechanical Bond

RESEARCH ARTICLE | Updated：2024-09-23

- Bolstering the Mechanical Robustness of Supramolecular Polymer Network by Mechanical Bond
- Bolstering the Mechanical Robustness of Supramolecular Polymer Network by Mechanical Bond
- 高分子科学（英文版） 2024年42卷第10期页码：1536-1544
- Affiliations：
  
  a.School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
  b.Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240, China
- Author bio：
  
  zhangzhaoming@sjtu.edu.cn (Z.M.Z.)
  xzyan@sjtu.edu.cn (X.Z.Y.)
- Funds：
  
  X. Y. acknowledges the financial support from the National Natural Science Foundation of China (Nos. 22122105 and 22071152), Natural Science Foundation of Shanghai (No. 22dz1207603), the Shuguang Program of Shanghai Education Development Foundation and the Shanghai Municipal Education Commission (No. 22SG11) and the Starry Night Science Fund of Zhejiang University Shanghai Institute for Advanced Study (No. SN-ZJU-SIAS-006). L. Y. acknowledges the financial support from the National Natural Science Foundation of China (No. 22305150). Z. Z. acknowledges the financial support from the National Natural Science Foundation of China (Nos. 22101175 and 52333001). This research is supported by State Key Laboratory of Polyolefins and Catalysis and Shanghai Key Laboratory of Catalysis Technology for Polyolefins (No. SKL-LCTP-202301).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3168-7.
- DOI：10.1007/s10118-024-3168-7
  中图分类号：
- 收稿：2024-05-12，
  
  修回：2024-05-25，
  
  录用：2024-05-27，
  
  网络首发：2024-08-20，
  
  纸质出版：2024-10-01
- Accepted：
Scan QR Code
Wang, Y. H.; Deng, J. X.; Zhao, J.; Ding, Y.; Yang, L.; Zhang, Z. M.; Yan, X. Z. Bolstering the mechanical robustness of supramolecular polymer network by mechanical bond. Chinese J. Polym. Sci. 2024, 42, 1536–1544

Yuan-Hao Wang, Jing-Xi Deng, Jun Zhao, et al. Bolstering the Mechanical Robustness of Supramolecular Polymer Network by Mechanical Bond[J]. Chinese Journal of Polymer Science, 2024, 42(10): 1536-1544.
Wang, Y. H.; Deng, J. X.; Zhao, J.; Ding, Y.; Yang, L.; Zhang, Z. M.; Yan, X. Z. Bolstering the mechanical robustness of supramolecular polymer network by mechanical bond. Chinese J. Polym. Sci. 2024, 42, 1536–1544 DOI： 10.1007/s10118-024-3168-7.

Yuan-Hao Wang, Jing-Xi Deng, Jun Zhao, et al. Bolstering the Mechanical Robustness of Supramolecular Polymer Network by Mechanical Bond[J]. Chinese Journal of Polymer Science, 2024, 42(10): 1536-1544. DOI： 10.1007/s10118-024-3168-7.

摘要

We introduced the mechanically interlocked cross-links into the supramolecular polymer network to bolster the mechanical robustness. The dually cross-linked network demonstrated enhanced mechanical properties including strength

Young’s modulus and toughness. The additional sliding motion also endowed the material with better performance in energy dissipation and recovery after deformation.

Abstract

Supramolecular polymer networks (SPNs) are celebrated for their dynamic nature

yet they often exhibit inadequate mechanical properties. Thus far

the quest to bolster the mechanical resilience of SPNs while preserving their dynamic character presents a formidable challenge. Herein

we introduce [2]rotaxane into SPN to serve as another cross-link

which could effectively enhance the mechanical robustness of the polymer network without losing the dynamic properties. Compared with SPN

the dually cross-linked network (DPN) demonstrates superior breaking strength

Young’s modulus

puncture force and toughness

underscoring its superior robustness. Furthermore

the cyclic tensile tests reveal that the energy dissipation capacity of DPN rivals

and in some cases surpasses

that of SPN

owing to the efficient energy dissipation pathway facilitated by [2]rotaxane. In addition

benefiting from stable topological structure of [2]rotaxane

DPN exhibits accelerated recovery from deformation

indicating superior elasticity compared to SPN. This strategy elevates the performance of SPNs across multiple metrics

presenting a promising avenue for the development of high-performance dynamic materials.

关键词

Keywords

references

Aida, T.; Meijer, E. W.; Stupp, S. I. Functional supramolecular polymers. Science 2012 , 335 , 813−817..

Sun, P.; Qin, B.; Xu, J. F.; Zhang, X. Supramonomers for controllable supramolecular polymerization and renewable supramolecular polymeric materials. Prog. Polym. Sci. 2022 , 124 , 101486..

Zhang, C. Z.; Mao, D. K.; Paluzzi, V. E.; Mao, C. D. Supramolecular polymerization of DNA double-crossover-like motifs in various dimensions. Chinese J. Polym. Sci. 2023 , 41 , 1501−1507..

Bai, R. X.; Yang, X.; Zhao, J.; Zhang, Z. M.; Yan, X. Z. Phototriggered formation of a supramolecular polymer network based on orthogonal H-bonding and host-guest recognition. Chem. Res. Chinese Universities 2023 , 39 , 777−781..

Guo, Z. W.; Zhao, J.; Liu, Y. H.; Li, G. F.; Wang, H.; Hou, Y.; Zhang, M. M.; Li, X. P.; Yan, X. Z. Conformational effect on fluorescence emission of tetraphenylethylene-based metallacycles. Chin. Chem. Lett. 2021 , 32 , 1691−1695..

Liu, K.; Jiang, Y. W.; Bao, Z. N.; Yan, X. Z. Skin-inspired electronics enabled by supramolecular polymeric materials. CCS Chem. 2019 , 1 , 431−447..

Zhu, Y.; Zheng, W.; Wang, W.; Yang, H. B. When polymerization meets coordination-driven self-assembly: metallo-supramolecular polymers based on supramolecular coordination complexes. Chem. Soc. Rev. 2021 , 50 , 7395−7417..

Liu, X. H.; Mokarizadeh, A. H.; Narayanan, A.; Mane, P.; Pandit, A.; Tseng, Y. M.; Tsige, M.; Joy, A. Multiphasic coacervates assembled by hydrogen bonding and hydrophobic interactions. J. Am. Chem. Soc. 2023 , 145 , 23109−23120..

Yan, X. Z.; Liu, Z. Y.; Zhang, Q. H.; Lopez, J.; Wang, H.; Wu, H. C.; Niu, S.; Yan, H. P.; Wang, S. H.; Lei, T.; Li, J. H.; Qi, D. P.; Huang, P. G.; Huang, J. P.; Zhang, Y.; Wang, Y. Y.; Li , G. L.; Tok, J. B. H.; Chen, X. D.; Bao, Z. N. Quadruple H-bonding cross-linked supramolecular polymeric materials as substrates for stretchable, antitearing, and self-healable thin film electrodes. J. Am. Chem. Soc. 2018 , 140 , 5280−5289..

Cheng, M. J.; Zhang, Q.; Shi, F. Macroscopic supramolecular assembly and its applications. Chinese J. Polym. Sci. 2018 , 36 , 306−321..

Hua, B.; Shao, L.; Li, M.; Liang, H. Z.; Huang, F. H. Macrocycle-based solid-state supramolecular polymers. Acc. Chem. Res. 2022 , 55 , 1025−1034..

Zhao, Z. H.; Chen, S. Y.; Zhao, P. C.; Luo, W. L.; Luo, Y. L.; Zuo, J. L.; Li, C. H. Mechanically adaptive polymers constructed from dynamic coordination equilibria. Angew. Chem. Int. Ed. 2024 , 63 , e202400758..

Fu, T. f.; Li, Z. J.; Zhang, Z. X.; Zhang, X. L.; Wang, F. Supramolecular cross-linking and gelation of conjugated polycarbazoles via hydrogen bond assisted molecular tweezer/guest complexation. Macromolecules 2017 , 50 , 7517−7525..

Song , Y.; Liu, Y.; Qi, T.; Li, G. L. Towards dynamic but supertough healable polymers through biomimetic hierarchical hydrogen-bonding interactions. Angew. Chem. Int. Ed. 2018 , 57 , 13838−13842..

Zeng, F.; Han, Y.; Yan, Z. C.; Liu, C. Y.; Chen, C. F. Supramolecular polymer gel with multi stimuli responsive, self-healing and erasable properties generated by host-guest interactions. Polymer 2013 , 54 , 6929−6935..

Li, Y. X.; Li, S.; Sun, J. Degradable poly(vinyl alcohol)-based supramolecular plastics with high mechanical strength in a watery environment. Adv. Mater. 2021 , 33 , 2007371..

Webber, M. J.; Appel, E. A.; Meijer, E. W.; Langer, R. Supramolecular biomaterials. Nat. Mater. 2016 , 15 , 13−26..

Xia, D. Y.; Wang, P.; Ji, X. F.; Khashab, N. M.; Sessler, J. L.; Huang, F. H. Functional supramolecular polymeric networks: The marriage of covalent polymers and macrocycle-based host-guest interactions. Chem. Rev. 2020 , 120 , 6070−6123..

Nakajima, T.; Fukuda, Y.; Kurokawa, T.; Sakai, T.; Chung, U. I.; Gong, J. P. Synthesis and fracture process analysis of double network hydrogels with a well-defined first network. ACS Macro Lett. 2013 , 2 , 518−521..

Xiao, T. X.; Zhou, L.; Sun, X. Q.; Huang, F. H.; Lin, C.; Wang, L. Y. Supramolecular polymers fabricated by orthogonal self-assembly based on multiple hydrogen bonding and macrocyclic host–guest interactions. Chin. Chem. Lett. 2020 , 31 , 1−9..

Yu, H. T.; Tang, J. W.; Feng, Y. Y.; Feng, W. Structural design and application of azo-based supramolecular polymer systems. Chinese J. Polym. Sci. 2019 , 37 , 1183−1199..

Zhang, Z. M.; Cheng, L.; Zhao, J.; Wang, L.; Liu, K.; Yu, W.; Yan, X. Z. Synergistic covalent and supramolecular polymers for mechanically robust but dynamic materials. Angew. Chem. Int. Ed. 2020 , 59 , 12139−12146..

Zhang, X. H.; Zhao, J.; Liu, K.; Li, G. F.; Zhao, D.; Zhang, Z. M.; Wan, J. J.; Yang, X.; Bai, R. X.; Wang, Y. M.; Zhang, W.; Yan, X. Z. Weldable and closed-loop recyclable monolithic dynamic covalent polymer aerogels. Natl. Sci. Rev. 2022 , 9 , nwac012..

Yu, P.; Huang, Q. R.; Wang, Y.; Peng, W.; Jia, Z. C.; Wang, H. Y.; Ma, J. J.; Wang, C. Y.; Yan, X. Z. Water-driven malleable, weldable and eco-friendly recyclable carbon fiber reinforced dynamic composites. Chin. J. Chem. 2024 , 42 , 516−522..

Deng, J. X.; Bai, R. X.; Zhao, J.; Liu, G. Q.; Zhang, Z. M.; You, W.; Yu, W.; Yan, X. Z. Insights into the correlation of cross-linking modes with mechanical properties for dynamic polymeric networks. Angew. Chem. Int. Ed. 2023 , 62 , e202309058..

Amano, S.; Fielden, S. D. P.; Leigh, D. A. A catalysis-driven artificial molecular pump. Nature 2021 , 594 , 529−534..

Cao, Z. Q.; Wu, D. P.; Li, M. Z.; Yang, F.; Li, Z. K.; An, W. K.; Jiang, S.; Zheng, X.; Niu, C. Y.; Qu, D. H. An acid-base responsive linear-cyclic polymer rotaxane molecular shuttle with fluorescence signal output. Chin. Chem. Lett. 2022 , 33 , 1533−1536..

Li, W. J.; Wang, W.; Wang, X. Q.; Li, M.; Ke, Y. B.; Yao, R.; Wen, J.; Yin, G. Q.; Jiang, B.; Li, X. P.; Yin, P. C.; Yang, H. B. Daisy chain dendrimers: Integrated mechanically interlocked molecules with stimuli-induced dimension modulation feature. J. Am. Chem. Soc. 2020 , 142 , 8473−8482..

Zhang, Z. M.; Zhao, J.; Guo, Z. W.; Zhang, H.; Pan, H.; Wu, Q.; You, W.; Yu, W.; Yan, X. Z. Mechanically interlocked networks cross-linked by a molecular necklace. Nat. Commun. 2022 , 13 , 1393..

Mena, Hernando S.; Pérez E. M. Mechanically interlocked materials. Rotaxanes and catenanes beyond the small molecule. Chem. Soc. Rev. 2019 , 48 , 5016−5032..

Bruns, C. J.; Stoddart, J. F. Rotaxane-based molecular muscles. Acc. Chem. Res. 2014 , 47 , 2186−2199..

Sauvage, J. P. From chemical topology to molecular machines (nobel lecture). Angew. Chem. Int. Ed. 2017 , 56 , 11080−11093..

Xue, M.; Yang, Y.; Chi, X. D.; Yan, X. Z.; Huang, F. H. Development of pseudorotaxanes and rotaxanes: From synthesis to stimuli-responsive motions to applications. Chem. Rev. 2015 , 115 , 7398−7501..

Tsai, C. Y.; Cheng, H. T.; Chiu, S. H. Improbable rotaxanes constructed from surrogate malonate rotaxanes as encircled methylene synthons. Angew. Chem. Int. Ed. 2023 , 62 , e202308974..

Du, R. C.; Jin, Q.; Zhu, T. S.; Wang, C. X.; Li, S.; Li, Y. Z.; Huang, X. X.; Jiang, Y.; Li, W. L.; Bao, T. W.; Cao, P. F.; Pan, L. J.; Chen, X. D.; Zhang, Q. H.; Jia, X. D. Sliding cyclodextrin molecules along polymer chains to enhance the stretchability of conductive composites. Small 2022 , 18 , 2200533..

Dai, W. T.; Xie, Z. H.; Ke, Y. B.; You, Y.; Rong, M. Z.; Zhang, M. Q. Topological confinement in reversibly interlocked polymer networks. Chinese J. Polym. Sci. 2024 , 42 , 133−140..

Stoddart, J. F. Mechanically interlocked molecules (mims)—molecular shuttles, switches, and machines (nobel lecture). Angew. Chem. Int. Ed. 2017 , 56 , 11094−11125..

Wang, Y. M.; Zhang, Z. M.; Zhang, H.; Zhao, J.; Liu, G. Q.; Bai, R. X.; Liu, Y. H.; You, W.; Yu, W.; Yan X. Z. Mechanically interlocked [an ] daisy chain networks. Chem 2023 , 9 , 2206−2221..

Forgan, R. S.; Sauvage, J. P.; Stoddart, J. F. Chemical topology: Complex molecular knots, links, and entanglements. Chem. Rev. 2011 , 111 , 5434−5464..

Xiong, Z. Q.; Yu, W. Sliding dynamics of slide-ring polymers based on the bead-spring model. Chinese J. Polym. Sci. 2023 , 41 , 1410−1424..

Zhang, Z. M.; Zhao, J.; Yan, X. Z. Mechanically interlocked polymers with dense mechanical bonds. Acc. Chem. Res. 2024 , 57 , 992−1006..

Zhao, J.; Zhang, Z. M.; Cheng, L.; Bai, R. X.; Zhao, D.; Wang, Y. M.; Yu, W.; Yan, X. Z. Mechanically interlocked vitrimers. J. Am. Chem. Soc. 2022 , 144 , 872−882..

Zhao, J.; Zhang, Z. M.; Wang, C. Y.; Yan, X. Z. Synergistic dual dynamic bonds in covalent adaptable networks. CCS Chem. 2024 , 6 , 41−56..

Wang, Y. H.; Yang, L.; Cheng, L.; Zhao, J.; Bai, R. X.; Wang, W. B.; Qu, S. L.; Zhang, Z. M.; Yu, W.; Yan, X. Z. Strengthening and toughening styrene-butadiene rubber by mechanically interlocked cross-links. Sci. China Chem . 2024 , DOI: 10.1007/s11426-024-2049-0..

Wang, Y. M.; Zhang, H.; Zhang, Z. M.; Zhao, J.; Bai, R. X.; Liu, Y. H.; Zhang, X. H., Yan, X. Z. Thermo-responsive topological metamorphosis in covalent-and-supramolecular polymer architectures. Aggregate 2022 , 3 , e206..

Sawada, J.; Aoki, D.; Uchida, S.; Otsuka, H.; Takata, T. Synthesis of vinylic macromolecular rotaxane cross-linkers endowing network polymers with toughness. ACS Macro Lett. 2015 , 4 , 598−601..

Liu, C.; Morimoto, N.; Jiang, L.; Kawahara, S.; Noritomi, T.; Yokoyama, H.; Mayumi, K.; Ito, K. Tough hydrogels with rapid self-reinforcement. Science 2021 , 372 , 1078−1081..

Akae, Y.; Sawada, J.; Nakajima, K.; Takata, T. The effect of the axle end structure and number of through-space bonds on the properties of rotaxane crosslinked polymers. Angew. Chem. Int. Ed. 2023 , 62 , e202303341..

Liu, Y. H.; Guo, Z. W.; Guo, Y. C.; Li, G. F.; Yang, S. B.; Yan, X. Z.; Shen, Y.; Wang, J. B. Topological effect on fluorescence emission of tetraphenylethylene-based metallacages. Chin. Chem. Lett. 2023 , 34 , 108531..

Liu, Y. H.; Wan, J. J.; Zhao, X. Y.; Zhao, J.; Guo, Y. C.; Bai, R. X.; Zhang, Z. M.; Yu, W.; Gibson, H. W.; Yan, X. Z. Highly strong and tough supramolecular polymer networks enabled by cryptand-based host-guest recognition. Angew. Chem. Int. Ed. 2023 , 62 , e202302370..

Zhang, Z. M.; Zhao, J.; Yan, X. Z. Synergistic covalent-and-supramolecular polymers. Acta Polymerica Sinica (in Chinese) 2022 , 53 , 691−706..

浏览量

266

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Dynamic Supramolecular Polymer Networks Constructed by Synergistic Dual Host-Guest Interactions

Silk Sericin-inspired Poly-β-homoserine for Protein Protection

Enhancing Processability of Phenylethynyl-terminated Imide Oligomers and Properties of Cured Polyimides via ―CF3 Incorporation

Upgrading Commercially Available Polyethylene to High-value Materials with Strong Mechanical Performance and Hydrophilicity by Blending with Ethylene/meta-Methoxystyrene Copolymers

Bioinspired Zinc-doped Nano Hydroxyapatite Reinforced Poly(lactic acid) Composites for Bone Repair