Tunable Phase Structure of Side-chain Liquid Crystalline Polymers Enabled by Molecular Engineering of Dual Mesogenic Cores

Wen-Huan Yao; Lan-Sheng Liu; Jie Zhao; Yan-Xia Wang; An-Zhi Ma; Zheng-Rui Ma; Lan-Ying Zhang; Ruo-Chen Lan

doi:10.1007/s10118-024-3167-8

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Tunable Phase Structure of Side-chain Liquid Crystalline Polymers Enabled by Molecular Engineering of Dual Mesogenic Cores

RESEARCH ARTICLE | Updated：2024-09-23

- Tunable Phase Structure of Side-chain Liquid Crystalline Polymers Enabled by Molecular Engineering of Dual Mesogenic Cores
- Tunable Phase Structure of Side-chain Liquid Crystalline Polymers Enabled by Molecular Engineering of Dual Mesogenic Cores
- 高分子科学（英文版） 2024年42卷第10期页码：1459-1469
- Affiliations：
  
  a.College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
  b.Key Laboratory of Eco-Functional Polymer Materials of the Ministry of Education, Key Laboratory of Eco-Environmental Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China
  c.Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871, China
  d.Institute of Advanced Materials & Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
- Author bio：
  
  wenhuanyao@163.com (W.H.Y.)
  zhanglanying@pku.edu.cn (L.Y.Z.)
  lanruochen@pku.edu.cn (R.C.L.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 52263033 and 52202081), China Postdoctoral Science Foundation Funded Project (No. 2021M690954), Natural Science Foundation of Gansu Province (No. 20JR10RA105), the Natural Science Foundation of Hunan Province (No. 2022JJ30152), the graduate research funding project of Northwest Normal University (No. 2023KYZZ-S157) and Natural Science Foundation of Jiangxi Province, China (No. 20232BAB204030).
- DOI：10.1007/s10118-024-3167-8
  中图分类号：
- 收稿：2024-04-26，
  
  修回：2024-05-18，
  
  录用：2024-05-19，
  
  网络首发：2024-08-20，
  
  纸质出版：2024-10-01
- Accepted：
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Yao, W. H.; Liu, L. S.; Zhao, J.; Wang, Y. X.; Ma, A. Z.; Ma, Z. R.; Zhang, L. Y.; Lan, R. C. Tunable phase structure of side-chain liquid crystalline polymers enabled by molecular engineering of dual mesogenic cores. Chinese J. Polym. Sci. 2024, 42, 1459–1469

Wen-Huan Yao, Lan-Sheng Liu, Jie Zhao, et al. Tunable Phase Structure of Side-chain Liquid Crystalline Polymers Enabled by Molecular Engineering of Dual Mesogenic Cores[J]. Chinese Journal of Polymer Science, 2024, 42(10): 1459-1469.
Yao, W. H.; Liu, L. S.; Zhao, J.; Wang, Y. X.; Ma, A. Z.; Ma, Z. R.; Zhang, L. Y.; Lan, R. C. Tunable phase structure of side-chain liquid crystalline polymers enabled by molecular engineering of dual mesogenic cores. Chinese J. Polym. Sci. 2024, 42, 1459–1469 DOI： 10.1007/s10118-024-3167-8.

Wen-Huan Yao, Lan-Sheng Liu, Jie Zhao, et al. Tunable Phase Structure of Side-chain Liquid Crystalline Polymers Enabled by Molecular Engineering of Dual Mesogenic Cores[J]. Chinese Journal of Polymer Science, 2024, 42(10): 1459-1469. DOI： 10.1007/s10118-024-3167-8.

摘要

Through rational molecular design and modulation of side chain composition of the copolymers

as an efficient approach

it is quite efficient to achieve diverse phase transition behaviours and adjust phase structures.

Abstract

A series of novel side-chain liquid crystalline (SCLC) copolymers were synthesized by attaching two distinct mesogenic units

namely a chiral cholesteryl-based monomer (M1) and an achiral biphenyl-based monomer (M2)

to a poly(3-mercaptopropylmethylsiloxane) (PMMS) backbone

via

thiol-ene click chemistry. The influence of side chain composition on the self-assembly behavior and phase structures of these SCLC copolymers was systematically investigated using different instrument. Results indicate that three distinct liquid crysta

lline phases and four unique molecular configurations were identified within the polymer series

with the emergence of the liquid crystalline phase being a synergistic outcome of the two distinct side chains. This study underscores the critical influence of side chain dimensions

rigidity

and spatial volume on the self-assembly structures and phase characteristics of liquid crystalline polymers

providing valuable insights for the rational design and development of advanced functional materials with tailored properties.

关键词

Keywords

references

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