Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility <italic style="font-style: italic">via</italic> a Density Deposition Self-assembly Method

Fang-Hua Luo; Zhi-Tao Dong; Guo-Hua Chen; Chen Ma; Huai-Yuan Wang

doi:10.1007/s10118-024-3154-0

Your Location：

Home >

Browse articles >

Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method

RESEARCH ARTICLE | Updated：2024-08-06

- Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method
- Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method
- 高分子科学（英文版） 2024年42卷第8期页码：1217-1226
- Affiliations：
  
  a.College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
  b.College of Materials Science and Engineering, Huaqiao University, Xiamen 361000, China
  c.School of Chemical Engineering and Technology and State Key Laboratory for Chemical Engineering, Tianjin University, Tianjin 300350, China
- Author bio：
  
  hdcgh@hqu.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51373059), the Graphene Powder & Composite Materials Research Center of Fujian, and Xiamen Key Laboratory of Polymers and Electronic Materials.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3154-0.
- DOI：10.1007/s10118-024-3154-0
  中图分类号：
- 收稿：2024-03-04，
  
  修回：2024-04-21，
  
  录用：2024-04-28，
  
  网络首发：2024-06-07，
  
  纸质出版：2024-08-01
- Accepted：
Scan QR Code
Luo, F. H.; Dong, Z. T.; Chen, G. H.; Ma, C.; Wang, H. Y. Preparation of PVA/GO/h-BN Janus film with high thermal conductivity and excellent flexibility via a density deposition self-assembly method. Chinese J. Polym. Sci. 2024, 42, 1217–1226

Fang-Hua Luo, Zhi-Tao Dong, Guo-Hua Chen, et al. Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1217-1226. DOI: 10.1007/s10118-024-3154-0.
Luo, F. H.; Dong, Z. T.; Chen, G. H.; Ma, C.; Wang, H. Y. Preparation of PVA/GO/h-BN Janus film with high thermal conductivity and excellent flexibility via a density deposition self-assembly method. Chinese J. Polym. Sci. 2024, 42, 1217–1226 DOI： 10.1007/s10118-024-3154-0.

Fang-Hua Luo, Zhi-Tao Dong, Guo-Hua Chen, et al. Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1217-1226. DOI: 10.1007/s10118-024-3154-0. DOI：

摘要

PVA/GO/h-BN Janus films are fabricated by a simple density deposition self-assembly method without assistance of interface or auxiliary equipment

which just utilize the density difference between GO and h-BN during water evaporation. The acquired Janus films show diverse applications

such as sensing & actuating

electronic skins

soft actuators

flexible sensors.

Abstract

Janus films with asymmetric physical/chemical properties have attracted considerable attention due to their promising applications in personal thermal management

electronic skins

sensors

actuators

etc

. However

traditional methods for fabricating Janus films conventionally need the assistance of an interface o

r auxiliary equipment

which are usually complex and time-consuming. Herein

flexible poly(vinyl alcohol) (PVA)/graphene oxide (GO)/h-BN (recorded as PVA/GO/h-BN) Janus films with thermally

optically

and electrically anisotropic properties are fabricated by a simple density deposition self-assembly method

which just utilizes the density difference between GO and h-BN during water evaporation. Experimental results show that the two sides of the acquired Janus films have obvious asymmetric characteristics. In the original state of the PVA/GO/h-BN Janus films

the thermal conductivity of the GO side (10.06 W·m

–1

·K

–1

) is generally lower than that of the h-BN side (10.48 W·m

–1

·K

–1

). But after GO is reduced

the thermal conductivity of the rGO side reaches 12.17 W·m

–1

·K

–1

surpassing that of the h-BN side. In addition

the relative reflectance of the h-BN side of Janus film is also significantly higher than that of the rGO side

and the surface resistance difference between the two sides is about 4 orders of magnitude. The prepared PVA/GO/h-BN Janus films show great application potential in human thermal management

light conversion switches

and electronic skins. This study provides a simple and versatile strategy for fabricating Janus films with multifunctional (such as thermal

optical

and electrical) anisotropies.

关键词

Keywords

references

de Gennes, P. G. Weiche Materie. (Nobel-Vortrag). Angew. Chem. Int. Ed. 1992 , 104 , 856−859..

de Gennes, P. G. Soft matter (Nobel Lecture). Angew. Chem. Int. Ed. 1992 , 31 , 842−845..

Cho, I.; Lee, K. W. Morphology of latex particles formed by poly(methyl methacrylate) -seeded emulsion polymerization of styrene. J. Appl. Polym. Sci. 1985 , 30 , 1903−1926..

Perro, A.; Reculusa, S.; Ravaine, S.; Bourgeat Lami, E.; Duguet, E. Design and synthesis of Janus micro- and nanoparticles. J. Mater. Chem . 2005 , 15 , 3745−3760..

Pang, X.; Wan, C.; Wang, M.; Lin, Z. Strictly biphasic soft and hard Janus structures: synthesis, properties, and applications. Angew. Chem. Int. Ed. 2014 , 53 , 5524−5538..

Fujii, S.; Kappl, M.; Butt, H. J.; Sugimoto, T.; Nakamura, Y. Soft Janus colloidal crystal film. Angew. Chem. Int. Ed. 2012 , 51 , 9809−9813..

Zhu, W.; Yang, H.; Lan, Y.; Yin, X.; Wang, S.; Wang, C.; Gao, N.; Li, G. Photonic janus films with highly tunable Janus balance. Adv. Mater. Interfaces 2016 , 3 , 201600225..

Zhang, P.; Wang, Q.; Guo, R.; Zhang, M.; Wang, S.; Lu, C.; Xue, M.; Fan, J.; He, Z.; Rao, W. Self-assembled ultrathin film of CNC/PVA-liquid metal composite as a multifunctional Janus material. Mater. Horiz. 2019 , 6 , 1643−1653..

Zhou, W.; Xiao, P.; Chen, T. Carbon-based janus films toward flexible sensors, soft actuators, and beyond. Acc. Mater. Res. 2023 , 4 , 334−347..

Cheng, Q.; Li, M.; Zheng, Y.; Su, B.; Wang, S.; Jiang, L. Janus interface materials: superhydrophobic air/solid interface and superoleophobic water/solid interface inspired by a lotus leaf. Soft Matter 2011 , 7 , 5948−5951..

He, J.; Xiao, P.; Shi, J.; Liang, Y.; Lu, W.; Chen, Y.; Wang, W.; Théato, P.; Kuo, S. W.; Chen, T. High performance humidity fluctuation sensor for wearable devices via a bioinspired atomic-precise tunable graphene-polymer heterogeneous sensing junction. Chem. Mater. 2018 , 30 , 4343−4354..

Yang, H. C.; Hou, J.; Chen, V.; Xu, Z. K. Janus membranes: exploring duality for advanced separation. Angew. Chem. Int. Ed. 2016 , 55 , 13398−13407..

Xiao, P.; Wan, C.; Gu, J.; Liu, Z.; Men, Y.; Huang, Y.; Zhang, J.; Zhu, L.; Chen, T. 2D Janus hybrid materials of polymer-grafted carbon nanotube/graphene oxide thin film as flexible, miniature e lectric carpet. Adv. Funct. Mater . 2015 , 25 , 2428−2435..

Li, S.; Xiao, P.; Yang, W.; Zhang, C.; Gu, J.; Kuo, S. W.; Chen, T. Hierarchically nanostructured Janus membranes toward sustainable and efficient solar-to-thermal management. Adv. Funct. Mater . 2023 , 33 , 202209654..

Wang, C.; Xia, K.; Wang, H.; Liang, X.; Yin, Z.; Zhang, Y. Advanced carbon for flexible and wearable electronics. Adv. Mater. 2019 , 31 , e1801072..

Han, B.; Zhang, Y. L.; Chen, Q. D.; Sun, H. B. Carbon-based photothermal actuators. Adv. Funct. Mater . 2018 , 28 , 201802235..

Chen, R. Q.; Ma, H.; Ma, X. L.; Ai, T. H.; Chai, Y. Q.; Zhang, H. R.; Li, F. W.; Wang, X. S.; Li, C. H.; Ji, J. H.; Xue, M. Q. Polymer crystallization regulation in liquid phase enables wearable full-featured thermoplastic-based smart Janus film. Chem. Eng. J . 2023 , 457 , 2022.141163..

Jiang, J. C.; Pi, Q. M.; Zhou, J. H.; Du, Y. X.; Li, Y. B. A simple preparation of ultrathin AuNWs-PEDOT:PSS bilayer Janus film for high performance ch emiresistive ammonia gas sensor. Sensor. Actuat. B-Chem . 2023 , 394 , 134370..

Han, J. D.; Zhang, K. X.; Rao, Z. L.; Chen, J. X.; Meng, Y.; Quan, D. P.; Bai, Y. A surface grafting strategy for antifouling/bioadhesive properties on a Janus-type polymeric thin film. Appl. Surf. Sci . 2024 , 649 , 159146..

Yang, H. C.; Xie, Y.; Hou, J.; Cheetham, A. K.; Chen, V.; Darling, S. B. Janus membranes: creating asymmetry for energy efficiency. Adv. Mater. 2018 , 30 , e1801495..

Liang, Y.; Xiao, P.; Wang, S.; Shi, J.; He, J.; Zhang, J.; Huang, Y.; Chen, T. Scalable fabrication of free-standing, stretchable CNT/TPE ultrathin composite films for skin adhesive epidermal electronics. J. Mater. Chem. C. 2018 , 6 , 6666−6671..

Mohata, S.; Dey, K.; Bhunia, S.; Thomas, N.; Gowd, E. B.; Ajithkumar, T. G.; Reddy, C. M.; Banerjee, R. Dual nanomechanics in anisotropic porous covalent organic framework Janus-type thin films. J. Am. Chem. Soc. 2021 , 144 , 400−409..

Hong, S.; Schaber, C. F.; Dening, K.; A ppel, E.; Gorb, S. N.; Lee, H. Air/water interfacial formation of freestanding, stimuli-responsive, self-healing catecholamine Janus-faced microfilms. Adv. Mater. 2014 , 26 , 7581−7587..

He, J.; Xiao, P.; Lu, W.; Shi, J.; Zhang, L.; Liang, Y.; Pan, C.; Kuo, S. W.; Chen, T. A Universal high accuracy wearable pulse monitoring system via high sensitivity and large linearity graphene pressure sensor. Nano Energy 2019 , 59 , 422−433..

Chen, T.; Xia, J.; Gu, J.; Lu, G.; Xue, Q.; Liu, C.; Yan, L.; Chen, T. Engineering Janus CNTs/OCS composite membrane at air/water interface for excellent dye molecules screening. Chem. Eng. J . 2021 , 417 , 127947..

Xia, J. Y.; Xiao, P.; Gu, J. C.; Chen, T. Y.; Liu, C. H.; Yan, L. K.; Chen, T. Interfacial self-assembled GR/GO ultrathin membranes on a large scale for molecular sieving. J. Mater. Chem. A. 2020 , 8 , 18735−18744..

Xiao, P.; Liang, Y.; He, J.; Zhang, L.; Wang, S.;Gu, J.; Zhang, J.; Huang, Y.; Kuo, S. W.; Chen, T. Hydrophilic/hydrophobic interphase-mediated bubble-like stretchable Janus ultrathin films toward self-adaptive and pneumatic multifunctional electronics. ACS Nano 2019 , 13 , 4368−43 78..

He, J.; Zhou, R. H.; Zhang, Y. F.; Gao, W. C.; Chen, T.; Mai, W. J.; Pan, C. F. Strain-insensitive self-powered tactile sensor arrays based on intrinsically stretchable and patternable ultrathin conformal wrinkled graphene-elastomer composite. Adv. Funct. Mater . 2022 , 32 , 202107281..

Yu, R.; Zhang, H.; Guo, B. Conductive biomaterials as bioactive wound dressing forwound healing and skin tissue engineering. Nano-Micro Lett. 2021 , 14 , 1..

Ji, L.; Yan, L.; Chao, M.; Li, M.; Gu, J.; Lei, M.; Zhang, Y.; Wang, X.; Xia, J.; Chen, T.; Nie, Y. J.; Chen, T. Sphagnum inspired g-C 3 N 4 nano/microspheres with smaller bandgap in heterojunction membranes for sunlight-driven water purification. Small 2021 , 17 , e2007122..

Ren, H.; Zheng, L.; Wang, G.; Gao, X.; Tan, Z.; Shan, J.; Cui, L.; Li, K.; Jian, M.; Zhu,L.; Zhang, Y.; Peng, H.; Wei, D.; Liu, Z. Transfer-medium-free nanofiber-reinforced graphene film and applications in wearable transparent pressure sensors. ACS Nano 2019 , 13 , 5541−5548..

Zhang, L.; Yu, J.; Yang, M.; Xie, Q.; Peng, H.; Liu, Z. Janus graphene from asymmetric two-dimensional chemistry. Nat. Commun. 2013 , 4 , 1443..

Liang, J.; Huang, Y.; Zhang, L.; Wang, Y.; Ma, Y.; Guo, T.; Chen, Y. Molecular-level dispersion of graphene into poly(vinyl alcohol) and effective reinforcement of their nanocomposites. Adv. Funct. Mater. 2009 , 19 , 2297−2302..

Luo, F.; Zhang, M.; Chen, S.; Xu, J.; Ma, C.; Chen, G. Sandwich-structured PVA/rGO films from self-construction with high thermal conductivity and electrical insulation. Compos. Sci. Technol . 2021 , 207 , 108707..

Yu, C.; Zhang, Q.; Zhang, J.; Geng, R.; Tian, W.; Fan, X.; Yao, Y. One-step in situ ball milling synthesis of polymer-functionalized few-layered boron nitride and its application in high thermally conductive cellulose composites. ACS Appl. Nano Mater. 2018 , 1 , 4875−4883..

Hu, D.; Ma, W.; Zhang, Z.; Ding, Y.; Wu, L. Dual bio-inspired design of highly thermally conductive and superhydrophobic nanocellulose composite films. ACS Appl. Mater. Interfaces 2020 , 12 , 11115−11125..

Tsai, M. H.; Tseng, I. H.; Chiang, J. C.; Li, J. J. Flexible polyimide films hybrid with functionalized boron nitride and graphene oxide simultaneously to improve thermal conduction and dimensional stability. ACS Appl. Mater. Interfaces 2014 , 6 , 8639−8645..

Lee, D.; Lee, B.; Park, K. H.; Ryu, H. J.; Jeon, S.; Hong, S. H. Scalable exfoliation process for highly soluble boron nitride nanoplatelets by hydroxide-assisted ball milling. Nano Lett. 2015 , 15 , 1238−1244..

Routh, A. F.; Russel, W. B. Deformation mechanisms during latex film formation: experimental evidence. Ind. Eng. Chem. Res. 2001 , 40 , 4302−4308..

Yang, H. S.; Li, Z. L.; Sun, G. Q.; Jin, X. T.; Lu, B.; Zhang, P. P.; Lin, T. Y.; Qu, L. T. Superplastic air-dryable graphene hydrogels for wet-press assembly of ultrastrong superelastic aerogels with infinite macroscale. Adv. Funct. Mater . 2019 , 29 , 201901917..

Gao, P.; Guo, L.; Sun, J.; Wang, Y.; She, Z.; Gao, M.; Zhao, Y.; Jin, C. Effect of alkyl polyglycosides on the performance of thermophilic bacteria pretreatment for saline waste sludge hydrolysis. Bioresour. Technol. 2020 , 296 , 122307..

Peng, Y.; Xiao, D.; Yu, G.; Feng, Y.; Li, J.; Zhao, X.; Tang, Y.; Wang, L.; Zhang, Q. Effect of an eco-friendly o/w emulsion stabilized with amphiphilic sodium alginate derivatives on lambda-cyhalothrin adsorption-desorption on natural soil minerals. J. Environ. Sci. 2019 , 78 , 230−238..

Zhao, Y.; Liu, W.; Hu, X.; Li, X.; Wang, C.; Yu, Y.; Zhang, J. Effect of surfactant on urease-producing flora from waste activated sludge using microbially induced calcite precipitation technology to suppress coal dust. Environ. Res. 2023 , 237 , 116941..

Yang, H.; Li, Z.; Lu, B.; Gao, J.; Jin, X.; Sun, G.; Zhang, G.; Zhang, P.; Qu, L. Reconstruction of inherent graphene oxide liquid crystals for large-scale fabrication of structure-intact graphene aerogel bulk toward practical applications. ACS Nano 2018 , 12 , 11407−11416..

Zhang, X.; Zhang, T.; Wang, Z.; Ren, Z.; Yan, S.; Duan, Y.; Zhang, J. Ultralight, superelastic, and fatigue-resistant graphene aerogel templated by graphene oxide liquid crystal stabilized air bubbles. ACS Appl. Mater. Interfaces 2019 , 11 , 1303−1310..

Zhang, X.; Yang, G.; Zong, L.; Jiang, M.; Song, Z.; Ma, C.; Zhang, T.; Duan, Y.; Zhang, J. Tough, ultralight, and water-adhesive graphene/natural rubber latex hybrid aerogel with sandwich like cell wall and biomimetic rose-petal-like surface. ACS Appl. Mater. Interfaces 2020 , 12 , 1378−1386..

An, D.; Cheng, S.; Zhang, Z.; Jiang, C.; Fang, H.; Li, J.; Liu, Y.; Wong, C. P. A polymer-based thermal management material with enhanced thermal conductivity by introducing three-dimensional networks and covalent bond connections. Carbon 2019 , 155 , 258−267..

Zhang, W.; Kong, Q. Q.; Tao, Z.; Wei, J.; Xie, L.; Cui, X.; Chen, C. M. 3D thermally cross-linked graphene aerogel-enhanced silicone rubber elastomer as thermal interface material. Adv. Mater. Interfaces 2019 , 6 , 201900147..

Zeng, X. L.; Yao, Y. M.; Gong, Z. Y.; Wang, F. F.; Sun, R.; Xu, J. B.; Wong, C. P. Ice-templated assembly strategy to construct 3D boron nitride nanosheet networks in polymer composites for thermal conductivity improvement. Small 2015 , 11 , 6205−6213..

Zhang, Y.; Wang, S.; Tang, P.; Zhao, Z.; Xu, Z.; Yu, Z. Z.; Zhang, H. B. Reali zing spontaneously regular stacking of pristine graphene oxide by a chemical-structure-engineering strategy for mechanically strong macroscopic films. ACS Nano 2022 , 16 , 8869−8880..

An, F.; Li, X.; Min, P.; Li, H.; Dai, Z.; Yu, Z. Z. Highly anisotropic graphene/boron nitride hybrid aerogels with long-range ordered architecture and moderate density for highly thermally conductive composites. Carbon 2018 , 126 , 119−127..

Zhao, H. Y.; Yu, M. Y.; Liu, J.; Li, X.; Min, P.; Yu, Z. Z. Efficient preconstruction of three-dimensional graphene networks for thermally conductive polymer composites. Nano-Micro Lett . 2022 , 14 , 129..

Li, L.; Li, M.; Zhang, Z.; Qin, Y.; Shui, X.; Xia, J.; Xiong, S.; Wang, B.; Zhang, Z.; Wei, X.; Kong, X. D.; Gong, P.; Cai, T.; Pan, Z. B.; Li, Y.; Fan, J. C.; Lin, C. T.; Jiang, N.; Yu, J. H. Robust composite film with high thermal conductivity and excellent mechanical properties by constructing a long-range ordered sandwich structure. J. Mater. Chem. A. 2022 , 10 , 9922−9931..

浏览量

714

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Durable Anti-fogging and Abrasion-resistant Coatings Based on Polyoxometalates-Hydrophilic Resin Composites with Enhanced Cohesion and Adhesion

Highly Regio- and trans-Selective Ring-opening Metathesis Polymerization of Chiral Aza-norbornene with a Simple Phenylimido-Tungsten Catalyst

Molecularly Engineered Polyimide Films with Switchable Cavitation for Bidirectional Passive Thermal Regulation

Silk Sericin-inspired Poly-β-homoserine for Protein Protection

Experimental Investigation of Graphene and TiO2 Reinforced Poly(vinyl alcohol)-based Fiber Metal Laminates

Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method

Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method

DOI：10.1007/s10118-024-3154-0

摘要

Abstract

关键词

Keywords

references