Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility <italic style="font-style: italic">via</italic> a Density Deposition Self-assembly Method

Fang-Hua Luo; Zhi-Tao Dong; Guo-Hua Chen; Chen Ma; Huai-Yuan Wang

doi:10.1007/s10118-024-3154-0

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Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method

RESEARCH ARTICLE | Updated：2024-08-06

- Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method
- Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method
- 高分子科学（英文版） 2024年42卷第8期页码：1217-1226
- Affiliations：
  
  a.College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
  b.College of Materials Science and Engineering, Huaqiao University, Xiamen 361000, China
  c.School of Chemical Engineering and Technology and State Key Laboratory for Chemical Engineering, Tianjin University, Tianjin 300350, China
- Author bio：
  
  hdcgh@hqu.edu.cn
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51373059), the Graphene Powder & Composite Materials Research Center of Fujian, and Xiamen Key Laboratory of Polymers and Electronic Materials.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3154-0.
- DOI：10.1007/s10118-024-3154-0
  中图分类号：
- 纸质出版日期：2024-08-01，
  
  网络出版日期：2024-06-07，
  
  收稿日期：2024-03-04，
  
  修回日期：2024-04-21，
  
  录用日期：2024-04-28
- Accepted：
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Luo, F. H.; Dong, Z. T.; Chen, G. H.; Ma, C.; Wang, H. Y. Preparation of PVA/GO/h-BN Janus film with high thermal conductivity and excellent flexibility via a density deposition self-assembly method. Chinese J. Polym. Sci. 2024, 42, 1217–1226

Fang-Hua Luo, Zhi-Tao Dong, Guo-Hua Chen, et al. Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method[J]. Chinese Journal of Polymer Science, 2024,42(8):1217-1226.
Luo, F. H.; Dong, Z. T.; Chen, G. H.; Ma, C.; Wang, H. Y. Preparation of PVA/GO/h-BN Janus film with high thermal conductivity and excellent flexibility via a density deposition self-assembly method. Chinese J. Polym. Sci. 2024, 42, 1217–1226 DOI： 10.1007/s10118-024-3154-0.

Fang-Hua Luo, Zhi-Tao Dong, Guo-Hua Chen, et al. Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method[J]. Chinese Journal of Polymer Science, 2024,42(8):1217-1226. DOI： 10.1007/s10118-024-3154-0.

摘要

PVA/GO/h-BN Janus films are fabricated by a simple density deposition self-assembly method without assistance of interface or auxiliary equipment

which just utilize the density difference between GO and h-BN during water evaporation. The acquired Janus films show diverse applications

such as sensing & actuating

electronic skins

soft actuators

flexible sensors.

Abstract

Janus films with asymmetric physical/chemical properties have attracted considerable attention due to their promising applications in personal thermal management

electronic skins

sensors

actuators

etc

. However

traditional methods for fabricating Janus films conventionally need the assistance of an interface o

r auxiliary equipment

which are usually complex and time-consuming. Herein

flexible poly(vinyl alcohol) (PVA)/graphene oxide (GO)/h-BN (recorded as PVA/GO/h-BN) Janus films with thermally

optically

and electrically anisotropic properties are fabricated by a simple density deposition self-assembly method

which just utilizes the density difference between GO and h-BN during water evaporation. Experimental results show that the two sides of the acquired Janus films have obvious asymmetric characteristics. In the original state of the PVA/GO/h-BN Janus films

the thermal conductivity of the GO side (10.06 W·m

–1

·K

–1

) is generally lower than that of the h-BN side (10.48 W·m

–1

·K

–1

). But after GO is reduced

the thermal conductivity of the rGO side reaches 12.17 W·m

–1

·K

–1

surpassing that of the h-BN side. In addition

the relative reflectance of the h-BN side of Janus film is also significantly higher than that of the rGO side

and the surface resistance difference between the two sides is about 4 orders of magnitude. The prepared PVA/GO/h-BN Janus films show great application potential in human thermal management

light conversion switches

and electronic skins. This study provides a simple and versatile strategy for fabricating Janus films with multifunctional (such as thermal

optical

and electrical) anisotropies.

关键词

Keywords

Janus filmsPVA/GO/h-BNDensity deposition self-assembly method

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Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method

Preparation of PVA/GO/h-BN Janus Film with High Thermal Conductivity and Excellent Flexibility via a Density Deposition Self-assembly Method

DOI：10.1007/s10118-024-3154-0

摘要

Abstract

关键词

Keywords

references