Concerted Steric and Electronic Strategy in Thermostable Salicylaldiminato Nickel Catalysts for Ethylene (Co)polymerization

Hong-Yu Ji; Hong-Liang Mu; Chun-Feng Tang; Yu-Xing Zhang; Yue Chi; Zhong-Bao Jian

doi:10.1007/s10118-024-3148-y

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Concerted Steric and Electronic Strategy in Thermostable Salicylaldiminato Nickel Catalysts for Ethylene (Co)polymerization

RESEARCH ARTICLE | Updated：2024-08-06

- Concerted Steric and Electronic Strategy in Thermostable Salicylaldiminato Nickel Catalysts for Ethylene (Co)polymerization
- Concerted Steric and Electronic Strategy in Thermostable Salicylaldiminato Nickel Catalysts for Ethylene (Co)polymerization
- 高分子科学（英文版） 2024年42卷第8期页码：1085-1092
- Affiliations：
  
  a.Key Laboratory of Advanced Structural Materials, Ministry of Education, School of Materials Science and Engineering, Changchun University of Technology, Changchun 130012, China
  b.State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  yxzhang7@ciac.ac.cn (Y.X.Z.)
  yuechi@ccut.edu.cn (Y.C.)
  zbjian@ciac.ac.cn (Z.B.J.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 22122110 and U23B6011 for Z.J.) and the Jilin Provincial Science and Technology Department Program (No. 20210101070JC for Y.C.).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3148-y.
- DOI：10.1007/s10118-024-3148-y
  中图分类号：
- 收稿：2024-03-24，
  
  修回：2024-04-17，
  
  录用：2024-04-18，
  
  网络首发：2024-06-05，
  
  纸质出版：2024-08-01
- Accepted：
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Ji, H. Y.; Mu, H. L.; Tang, C. F.; Zhang, Y. X.; Chi, Y.; Jian, Z. B. Concerted steric and electronic strategy in thermostable salicylaldiminato nickel catalysts for ethylene (co)polymerization. Chinese J. Polym. Sci. 2024, 42, 1085–1092

Hong-Yu Ji, Hong-Liang Mu, Chun-Feng Tang, et al. Concerted Steric and Electronic Strategy in Thermostable Salicylaldiminato Nickel Catalysts for Ethylene (Co)polymerization[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1085-1092.
Ji, H. Y.; Mu, H. L.; Tang, C. F.; Zhang, Y. X.; Chi, Y.; Jian, Z. B. Concerted steric and electronic strategy in thermostable salicylaldiminato nickel catalysts for ethylene (co)polymerization. Chinese J. Polym. Sci. 2024, 42, 1085–1092 DOI： 10.1007/s10118-024-3148-y.

Hong-Yu Ji, Hong-Liang Mu, Chun-Feng Tang, et al. Concerted Steric and Electronic Strategy in Thermostable Salicylaldiminato Nickel Catalysts for Ethylene (Co)polymerization[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1085-1092. DOI： 10.1007/s10118-024-3148-y.

摘要

Concerted steric and electronic strategy in neutral Ni(II) catalysts enables the enhancement of thermostability in ethylene (co)polymerization

thus producing semicrystalline PE

PE wax

PE oil

and functional PE.

Abstract

Olefin polymerization is one of the most important chemical reactions in industry. This work presents a strategy that emphasizes the synergistic

关键词

Keywords

references

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