Preparation and Structure-Property Regulation Mechanism of Reversible Thermochromic Polydiacetylene

Zhi-Qing Ge; Shuo Yan; Zu-Xiong Pan; Shan Lei; Xuan-Zhi Mao; Chu Zhao; Mo-Zhen Wang; Xue-Wu Ge

doi:10.1007/s10118-024-3142-4

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Preparation and Structure-Property Regulation Mechanism of Reversible Thermochromic Polydiacetylene

RESEARCH ARTICLE | Updated：2024-08-06

- Preparation and Structure-Property Regulation Mechanism of Reversible Thermochromic Polydiacetylene
- Preparation and Structure-Property Regulation Mechanism of Reversible Thermochromic Polydiacetylene
- 高分子科学（英文版） 2024年42卷第8期页码：1111-1121
- Affiliations：
  
  a.Key Laboratory of Precision and Intelligent Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China
  b.Marshall Laboratory of Biomedical Engineering, International Cancer Center, Laboratory of Evolutionary Theranostics (LET), School of Biomedical Engineering, Shenzhen University Medical School, Shenzhen University, Shenzhen 518055, China
  c.Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
  d.University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  pstwmz@ustc.edu.cn (M.Z.W.)
  xwge@ustc.edu.cn (X.W.G.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 51973205) and the Fundamental Research Funds for the Central Universities (Nos. WK9110000066, WK3450000005 and WK3450000006). The authors gratefully acknowledge Prof. Gang Zou in the Department of Polymer Science and Engineering of USTC for joining us in a warm and sincere discussion on this work. We thank the Super Computing Center of USTC for providing computational resources for this paper.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3142-4.
- DOI：10.1007/s10118-024-3142-4
  中图分类号：
- 收稿：2024-03-18，
  
  修回：2024-04-03，
  
  录用：2024-04-10，
  
  网络首发：2024-05-23，
  
  纸质出版：2024-08-01
- Accepted：
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Ge, Z. Q.; Yan, S.; Pan, Z. X.; Lei, S.; Mao, X. Z.; Zhao, C.; Wang, M. Z.; Ge, X. W. Preparation and structure-property regulation mechanism of reversible thermochromic polydiacetylene. Chinese J. Polym. Sci. 2024, 42, 1111–1121

Zhi-Qing Ge, Shuo Yan, Zu-Xiong Pan, et al. Preparation and Structure-Property Regulation Mechanism of Reversible Thermochromic Polydiacetylene[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1111-1121.
Ge, Z. Q.; Yan, S.; Pan, Z. X.; Lei, S.; Mao, X. Z.; Zhao, C.; Wang, M. Z.; Ge, X. W. Preparation and structure-property regulation mechanism of reversible thermochromic polydiacetylene. Chinese J. Polym. Sci. 2024, 42, 1111–1121 DOI： 10.1007/s10118-024-3142-4.

Zhi-Qing Ge, Shuo Yan, Zu-Xiong Pan, et al. Preparation and Structure-Property Regulation Mechanism of Reversible Thermochromic Polydiacetylene[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1111-1121. DOI： 10.1007/s10118-024-3142-4.

摘要

New polydiacetylene materials with specific melting behavior and thermochromic properties can be customized by precisely regulating the structure of diacetylene monomers.

Abstract

The thermochromic mechanism and the structure-property regulation principle of reversible thermochromic polydiacetylene (PDA) materials have always been a challenging issue. In this work

a series of diacetylene monomers (m-PCDA) containing phenyl and amide or carboxyl groups were synthesized from 10

12-pentacosadiynoic acid (PCDA) through the esterification or amidation reactions. The effects of the number and the distribution of the functional groups in m-PCDA molecules on their solid-state polymerization capability

and the thermochromic mechanism of their corresponding polymers (m-PDA) were investigated and discussed in detail. The results show that the m-PCDA monomers containing both benzene ring and groups that can form hydrogen bonding interactions have strong intermolecular interaction

and are easy to carry out the solid phase polymerization under 254-nm UV irradiation to obtain the corresponding new thermochromic m-PDA materials. The thermochromic behavior of m-PDA depends on its melting process. The initial color-change temperature (blue to red) is determined by the onset melting temperature

and the temperature range in which reversible color recovery can be achieved by repeat heating-cooling treatment is determined by its melting range. According to the proposed thermochromic mechanism of PDA

various new PDA materials with precise thermochromic temperatures and reversible thermochromic temperature ranges can be designed and synthesized through the appropriate introduction of benzene ring and groups that can form hydrogen bonding interactions into the molecular structure of linear diacetylene monomer. This work provides a perspective to the precise molecular structure design and the property regulation of the reversible thermochromic PDA materials.

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