Cross-linked Electrospun Gel Polymer Electrolytes for Lithium-Ion Batteries

Xue Gong; Qin Xiao; Qing-Yin Li; Wen-Cui Liang; Feng Chen; Long-Yu Li; Shi-Jie Ren

doi:10.1007/s10118-024-3136-2

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Cross-linked Electrospun Gel Polymer Electrolytes for Lithium-Ion Batteries

RESEARCH ARTICLE | Updated：2024-08-06

- Cross-linked Electrospun Gel Polymer Electrolytes for Lithium-Ion Batteries
- Cross-linked Electrospun Gel Polymer Electrolytes for Lithium-Ion Batteries
- 高分子科学（英文版） 2024年42卷第8期页码：1021-1028
- Affiliations：
  
  College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  longyu88@scu.edu.cn (L.Y.L.)
  rensj@scu.edu.cn (S.J.R.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 21574087 and 51973128) and Science and Technology Department of Sichuan Province (Nos. 2019YJ0128 and 2019YFG0277). LL thanks the supports from the Fundamental Research Funds for the Central Universities.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3136-2.
- DOI：10.1007/s10118-024-3136-2
  中图分类号：
- 收稿：2024-02-25，
  
  修回：2024-04-06，
  
  录用：2024-04-07，
  
  网络首发：2024-05-17，
  
  纸质出版：2024-08-01
- Accepted：
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Gong, X.; Xiao, Q.; Li, Q. Y.; Liang, W. C.; Chen, F.; Li, L. Y.; Ren, S. J. Cross-linked electrospun gel polymer electrolytes for lithium-ion batteries. Chinese J. Polym. Sci. 2024, 42, 1021–1028

Xue Gong, Qin Xiao, Qing-Yin Li, et al. Cross-linked Electrospun Gel Polymer Electrolytes for Lithium-Ion Batteries[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1021-1028.
Gong, X.; Xiao, Q.; Li, Q. Y.; Liang, W. C.; Chen, F.; Li, L. Y.; Ren, S. J. Cross-linked electrospun gel polymer electrolytes for lithium-ion batteries. Chinese J. Polym. Sci. 2024, 42, 1021–1028 DOI： 10.1007/s10118-024-3136-2.

Xue Gong, Qin Xiao, Qing-Yin Li, et al. Cross-linked Electrospun Gel Polymer Electrolytes for Lithium-Ion Batteries[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1021-1028. DOI： 10.1007/s10118-024-3136-2.

摘要

We prepared CPM films with excellent thermal stability and high porosity by electrospinning and cross-linking in sequence. Then CPM films were activated by immersing in electrolyte to prepare CGPEs with enhanced electrolyte uptake and high ionic conductivity.

Abstract

Lithium-ion batteries (LI

Bs) benefit from an effective electrolyte system design in both terms of their safety and energy storage capability. Herein

a series of precursor membranes with high porosity were produced using electrospinning technology by mixing PVDF and triblock copolymer (PS-PEO-PS)

resulting in a porous structure with good interconnections

which facilitates the absorbency of a large amount of electrolyte and further increases the ionic conductivity of gel polymer electrolytes (GPEs). It has been demonstrated that post-cross-linking of the precursor membranes increases the rigidity of the nanofibers

which allows the polymer film to be dimensionally stable up to 260 °C while maintaining superior electrochemical properties. The obtained cross-linked GPEs (CGPEs) showed high ionic conductivity up to 4.53×10

−3

S·cm

−1

. With the CGPE-25

the assembled Li/LiFePO

half cells exhibited good rate capability and maintained a capacity of 99.4% and a coulombic efficiency of 99.3% at 0.1 C. These results suggest that the combination of electrospinning technique and post-cross-linking is an effective method to construct polymer electrolytes with high thermal stability and steadily decent electrochemical performance

particularly useful for Lithium-ion battery applications that require high-temperature usage.

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