A Fluorine-Functionalized 3D Covalent Organic Framework with Entangled 2D Layers

Li-Bang Xiao; Zi-Han Wu; Jun-Jie Xin; Yuan-Peng Cheng; Bo Gui; Jun-Liang Sun; Cheng Wang

doi:10.1007/s10118-024-3133-5

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A Fluorine-Functionalized 3D Covalent Organic Framework with Entangled 2D Layers

RESEARCH ARTICLE | Updated：2024-08-06

- A Fluorine-Functionalized 3D Covalent Organic Framework with Entangled 2D Layers
- A Fluorine-Functionalized 3D Covalent Organic Framework with Entangled 2D Layers
- 高分子科学（英文版） 2024年42卷第8期页码：1210-1216
- Affiliations：
  
  a.College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
  b.College of Chemistry and Molecular Engineering, Beijing National Laboratory for Molecular Sciences, Peking University, Beijing 100871, China
- Author bio：
  
  guib09@whu.edu.cn (B.G.)
  chengwang@whu.edu.cn (C.W.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (Nos. 22225503, U21A20285 and 22375153), the Hubei Provincial Natural Science Foundation of China (No. 2023AFA011) and the Fundamental Research Funds for Central Universities (No. 2042023kf0127). We also thank the Core Facility of Wuhan University.;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3133-5.
- DOI：10.1007/s10118-024-3133-5
  中图分类号：
- 收稿：2024-03-01，
  
  修回：2024-03-20，
  
  录用：2024-03-25，
  
  网络首发：2024-05-10，
  
  纸质出版：2024-08-01
- Accepted：
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Xiao, L. B.; Wu, Z. H.; Xin, J. J.; Cheng, Y. P.; Gui, B.; Sun, J. L.; Wang, C. A fluorine-functionalized 3D covalent organic framework with entangled 2D layers. Chinese J. Polym. Sci. 2024, 42, 1210–1216

Li-Bang Xiao, Zi-Han Wu, Jun-Jie Xin, et al. A Fluorine-Functionalized 3D Covalent Organic Framework with Entangled 2D Layers[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1210-1216.
Xiao, L. B.; Wu, Z. H.; Xin, J. J.; Cheng, Y. P.; Gui, B.; Sun, J. L.; Wang, C. A fluorine-functionalized 3D covalent organic framework with entangled 2D layers. Chinese J. Polym. Sci. 2024, 42, 1210–1216 DOI： 10.1007/s10118-024-3133-5.

Li-Bang Xiao, Zi-Han Wu, Jun-Jie Xin, et al. A Fluorine-Functionalized 3D Covalent Organic Framework with Entangled 2D Layers[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1210-1216. DOI： 10.1007/s10118-024-3133-5.

摘要

A fluorine-functionalized 3D COF (3D-An-COF-F) with entangled 2D

sql

nets was designed and synthesized. Based on continuous rotation electron diffraction technique and structure modelling

3D-An-COF-F was isostructural to our reported 3D-An-COF. Interestingly

compared to 3D-An-COF without F atoms

3D-An-COF-F showed an improved CO

sorption ability and higher CO

selectivity.

Abstract

Constructing three dimensional (3D) covalent organic frameworks (COFs) through the entanglement of two dimensional (2D) nets is a promising but underdeveloped strategy. Herein

we report the design and synthesis of a fluorine functionalized 3D COF (3D-An-COF-F) formed by entangled 2D

sql

nets. The structure of 3D-An-COF-F was determined by the combination of continuous rotation electron diffraction technique and modelling based on the chemical information from real space. Interestingly

compared to the isostructural 3D-An-COF without F atoms

3D-An-COF-F showed an improved CO

sorption ability and higher CO

selectivity. Our study not only demonstrated the generality of constructing 3D COFs with entangled 2D nets by introducing bulky groups vertically in planar building blocks

but also will expand the diversity of 3D COFs for various applications.

关键词

Keywords

references

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