Side-Chain-Type Polyimide-Cu Complexes with Suppressed Activation Energy of Relaxation for Advanced High-Temperature Capacitor

Bai-Yang Zhou; Ze-Tong Ma; Shi-Long Zhong; Zhen-Jie Huang; Qi Guo; Deng-Chong Feng; Zhong-Ke Yuan; Shao-Lin Lu; Yu-Zhao Yang; Cheng Wang; Ding-Shan Yu; Xu-Dong Chen

doi:10.1007/s10118-024-3131-7

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Side-Chain-Type Polyimide-Cu Complexes with Suppressed Activation Energy of Relaxation for Advanced High-Temperature Capacitor

RESEARCH ARTICLE | Updated：2024-08-06

- Side-Chain-Type Polyimide-Cu Complexes with Suppressed Activation Energy of Relaxation for Advanced High-Temperature Capacitor
- Side-Chain-Type Polyimide-Cu Complexes with Suppressed Activation Energy of Relaxation for Advanced High-Temperature Capacitor
- 高分子科学（英文版） 2024年42卷第8期页码：1038-1048
- Affiliations：
  
  a.Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, Guangdong Engineering Technology Research Centre for High Performance Organic and Polymer Photoelectric Functional Films, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China
  b.School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China
  c.Guangdong Provincial Laboratory of Chemistry and Fine Chemical Industry Jieyang Centre, Jieyang 515200, China
  d.Chemistry and Chemical Engineering Guangdong Laboratory, Shantou 515031, China
- Author bio：
  
  mazt@gdut.edu.cn (Z.T.M.)
  zhongshilong@gdut.edu.cn (S.L.Z.)
  chenxd@gdut.edu.cn (X.D.C.)
- Funds：
  
  This work was financially supported by the National Key R&D Program of China (No. 2023YFB3812400), the National Natural Science Foundation of China (No. 52303370) and the Special Fund for the Sci-tech Innovation Strategy of Guangdong Province (No. STKJ202209082).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3131-7.
- DOI：10.1007/s10118-024-3131-7
  中图分类号：
- 纸质出版日期：2024-08-01，
  
  网络出版日期：2024-05-17，
  
  收稿日期：2024-01-21，
  
  修回日期：2024-03-11，
  
  录用日期：2024-03-26
- Accepted：
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Zhou, B. Y.; Ma, Z. T.; Zhong, S. L.; Huang, Z. J.; Guo, Q.; Feng, D. C.; Yuan, Z. K.; Lu, S. L.; Yang, Y. Z.; Wang, C.; Yu, D. S.; Chen, X. D. Side-chain-type polyimide-Cu complexes with suppressed activation energy of relaxation for advanced high-temperature capacitor. Chinese J. Polym. Sci. 2024, 42, 1038–1048

Bai-Yang Zhou, Ze-Tong Ma, Shi-Long Zhong, et al. Side-Chain-Type Polyimide-Cu Complexes with Suppressed Activation Energy of Relaxation for Advanced High-Temperature Capacitor[J]. Chinese Journal of Polymer Science, 2024,42(8):1038-1048.
Zhou, B. Y.; Ma, Z. T.; Zhong, S. L.; Huang, Z. J.; Guo, Q.; Feng, D. C.; Yuan, Z. K.; Lu, S. L.; Yang, Y. Z.; Wang, C.; Yu, D. S.; Chen, X. D. Side-chain-type polyimide-Cu complexes with suppressed activation energy of relaxation for advanced high-temperature capacitor. Chinese J. Polym. Sci. 2024, 42, 1038–1048 DOI： 10.1007/s10118-024-3131-7.

Bai-Yang Zhou, Ze-Tong Ma, Shi-Long Zhong, et al. Side-Chain-Type Polyimide-Cu Complexes with Suppressed Activation Energy of Relaxation for Advanced High-Temperature Capacitor[J]. Chinese Journal of Polymer Science, 2024,42(8):1038-1048. DOI： 10.1007/s10118-024-3131-7.

摘要

A novel polyimide-Cu complex material predicated on side-chain-type pyridine-Cu coordination achieves superior dielectric performance

which endows an elevated degree of freedom with suppressed relaxation activation energy and long-range electron delocalization

enhancing molecular dipole moment with more flexibility.

Abstract

The burgeoning growth of the new energy vehicles and aviation industry has escalated the need for energy storage capacitors capable of stable operation in harsh environments. The advent of metal-polyimide complexes has illuminated a novel approach for preparing temperature-resistant capacitors. However

the general application of these metal-polyimide complexes is impeded by the high dielectric loss and low breakdown strength

consequences of main-chain coordination and excessive metal ions content. Herein

our study proposes a novel polyimide-Cu complex material (POP-Cu) predicated on side-chain-type pyridine-Cu coordination

utilizing the structural backbone PMDA-ODA of mature commercial PI (Kapton) with reliable performance. Owing to the high degree of freedom afforded by the side chain with suppressed relaxation activation energy and the long-range electron delocalization formed by

coordination

the dielectric constant of this material containing merely 2.7 mol

% Cu increases from 3.25 (POPI) to 5.58

while maintaining a remarkably low dielectric loss of 0.0066. Meanwhile

this material exhibits a substantial DC breakdown strength of 436.2 MV·m

−1

and a high energy density of 5.42 J·cm

−3

coupled with superior mechanical and thermal properties. Even at 150 °C

it retains over 90% of its room-temperature energy density

demonstrating notable dielectric stability under high temperatures. These attributes underscore its promising application for capacitors operating in harsh environments.

关键词

Keywords

Dielectric performancePolyimide complexesSide-Chain-TypeHigh-temperature capacitor

references

Wang, Y. G.; Song, Y. F.; Xia, Y. Y. Electrochemical capacitors: mechanism, materials, systems, characterization and applications.Chem. Soc. Rev.2016,45, 5595−5925..

Feng, Q. K.; Zhong, S. L.; Pei, J. Y.; Zhao, Y.; Zhang, D. L.; Liu, D. F.; Zhang, Y. X.; Dang, Z. M. Recent progress and future prospects on all-organic polymer dielectrics for energy storage capacitors.Chem. Rev.2022,122, 3820−3878..

Pan, H.; Li, F.; Liu, Y.; Zhang, Q.; Wang, M.; Lan, S.; Zheng, Y.; Ma, J.; Gu, L.; Shen, Y.; Yu, P.; Zhang, S.; Chen, L. Q.; Lin, Y. H.; Nan, C. W. Ultrahigh-energy density lead-free dielectric filmsviapolymorphic nanodomain design.Science2019,365, 578−582..

Dang, Z. M.; Yuan, J. K.; Yao, S. H.; Liao, R. J. Flexible nanodielectric materials with high permittivity for power energy storage.Adv. Mater.2013,25, 6334−6365..

Dang, Z. M.; Zheng, M. S.; Zha, J. W. 1D/2D carbon nanomaterial-polymer dielectric composites with high permittivity for power energy storage applications.Small 2016 , 12, 1688-1701..

Liu, X. J.; Zheng, M. S.; Chen, G.; Dang, Z. M.; Zha, J. W. High-temperature polyimide dielectric materials for energy storage: theory, design, preparation and properties.Energy Environ. Sci.2022,15, 56−81..

Tan, D.; Zhang, L. L.; Chen, Q.; Irwin, P. High-temperature capacitor polymer films.J. Electron. Mater.2014,43, 4569−4575..

Yao, Z. H.; Song, Z.; Hao, H.; Yu, Z. Y.; Cao, M. H.; Zhang, S. J.; Lanagan, M. T.; Liu, H. X. Homogeneous/inhomogeneous-structured dielectrics and their energy-storage performances.Adv. Mater.2017,29, 1601727..

Gong, Y.; Chen, D.; Duan, J. J.; Zhang, X. H.; Ma, Y. H.; Zhao, C. W.; Yang, W. T. Largely enhanced energy density of BOPP-OBT@CPP-BOPP sandwich-structured dielectric composites.J. Mater. Chem. C2022,10, 13074−13083..

Zhang, T. D.; Yu, H. N.; Jung, Y. H.; Zhang, C. H.; Feng, Y.; Chen, Q. G.; Lee, K. J.; Chi, Q. G. Significantly improved high-temperature energy storage performance of BOPP films by coating nanoscale inorganic layer.Energy Environ. Mater. 2022 , DOI: 10.1002/eem2.12549.

Li, Q.; Yao, F. Z.; Liu, Y.; Zhang, G. Z.; Wang, H.; Wang, Q. High-temperature dielectric materials for electrical energy storage.Ann. Rev. Mater. Res.2018,48, 219−243..

Li, H.; Zhou, Y.; Liu, Y.; Li, L.; Liu, Y.; Wang, Q. Dielectric polymers for high-temperature capacitive energy storage.Chem. Soc. Rev.2021,50, 6369−6400..

Dong, J. F.; Li, L.; Qiu, P. Q.; Pan, Y. P.; Niu, Y. J.; Sun, L.; Pan, Z. Z.; Liu, Y. Q.; Tan, L.; Xu, X. W.; Xu, C.; Luo, G. F.; Wang, Q.; Wang, H. Scalable polyimide-organosilicate hybrid films for high-temperature capacitive energy storage.Adv. Mater.2023,35, 2211487..

Zheng, W. W.; Yang, T. Z.; Qu, L. J.; Liang, X. C.; Liu, C. N.; Qian, C.; Zhu, T. W.; Zhou, Z. X.; Liu, C.; Liu, S. W.; Chi, Z. G.; Xu, J.; Zhang, Y. Temperature resistant amorphous polyimides with high intrinsic permittivity for electronic applications.Chem. Eng. J.2022,436, 135060..

Li, Y. P.; Yin, J. H.; Feng, Y.; Li, J. L.; Zhao, H.; Zhu, C. C.; Yue, D.; Liu, Y. P.; Su, B.; Liu, X. X. Metal-organic framework/polyimide composite with enhanced breakdown strength for flexible capacitor.Chem. Eng. J.2022,429, 132228..

Wu, D.; Zhao, X.; Li, X. T.; Dong, J.; Zhang, Q. H. Dual-crosslinked polyimide dielectric films containing Cu elements for high-temperature film capacitors.Compos. Commun.2023,42, 101653..

Alamri, A.; Wu, C.; Nasreen, S.; Tran, H.; Yassin, O.; Gentile, R.; Kamal, D.; Ramprasad, R.; Cao, Y.; Sotzing, G. High dielectric constant and high breakdown strength polyimide via tin complexation of the polyamide acid precursor.RSC Adv.2022,12, 9095−9100..

Peng, X. W.; Xu, W. H.; Chen, L. L.; Ding, Y. C.; Chen, S. L.; Wang, X. Y.; Hou, H. Q. Polyimide complexes with high dielectric performance: toward polymer film capacitor applications.J. Mater. Chem. C2016,4, 6452−6456..

Chen, L. L.; Ding, Y. C.; Yang, T.; Wan, C. F.; Hou, H. Q. Synthesis and properties of a high dielectric constant copolymer of a copper phthalocyanine oligomer grafted to amino-capped polyimide.J. Mater. Chem. C2017,5, 8371−8375..

Peng, X. W.; Wu, Q.; Jiang, S. H.; Hanif, M.; Chen, S. L.; Hou, H. Q. High performance polyimide-Yb complex with high dielectric constant and low dielectric loss.Mater. Lett.2014,133, 240−242..

Silaghi, M. A., inPolymeric Dielectric Materials, InTech, Croatia, 2012 , p. 9..

Liu, J.; Li, M. F.; Yang, Y. Z.; Xu, L. R.; Lin, J. J.; Hong, W.; Chen, X. D. Metal conductive surface patterning on photoactive polyimide.Adv. Funct. Mater.2017,27, 1701674..

Zhong, S. L.; Zhou, B. Y.; Gu, X. R.; Yu, D. S.; Chen, X. D. Palladium-assisted metal patterning on polyimide surfaces.Chinese. J. Polym. Sci.2022,40, 1287−1296..

Lyons, A. M.; Vasile, M. J.; Pearce, E. M.; Waszczak, J. V. Copper chloride complexes with poly(2-vinylpyridine): preparation and redox properties.Macromolecules1988,21, 3125−3134..

Zhu, Y. Q.; Kang, E. T.; Neoh, K. G.; Chan, L.; Lai, D. M. Y.; Huan, A. C. H. Surface modification of SiLK®by graft copolymerization with 4-vinylpyridine for reduction in copper diffusion.Appl. Surf. Sci.2004,225, 144−155..

Bei, R. X.; Qian, C.; Zhang, Y.; Chi, Z. G.; Liu, S. W.; Chen, X. D.; Xu, J. R.; Aldred, M. P. Intrinsic low dielectric constant polyimides: relationship between molecular structure and dielectric properties.J. Mater. Chem. C2017,5, 12807−12815..

Xie, R. X.; Weisen, A. R.; Lee, Y. M.; Aplan, M. A.; Fenton, A. M.; Masucci, A. E.; Kempe, F.; Sommer, M.; Pester, C. W.; Colby, R. H.; Gomez, E. D. Glass transition temperature from the chemical structure of conjugated polymers.Nat. Commun.2020,11, 893..

Pankaj, S.; Hempel, E.; Beiner, M. Side-chain dynamics and crystallization in a series of regiorandom poly(3-alkylthiophenes).Macromolecules.2009,42, 716−724..

Guo, M.; Hayakawa, T.; Kakimoto, M.; Goodson, T. Organic macromolecular high dielectric constant materials: synthesis, characterization, and applications.J. Phys. Chem. B2011,115, 13419−13432..

Wei, J. J.; Zhu, L. Intrinsic polymer dielectrics for high energy density and low loss electric energy storage.Prog. Polym. Sci.2020,106, 101254..

Tony, B.; David, B., inElectrical Properties of Polymers, Cambridge University Press, Cambridge, 2008 , p. 58..

Tong, H.; Ahmad, A.; Fu, J.; Xu, H. Y.; Fan, T.; Hou, Y. D.; Xu, J. Revealing the correlation between molecular structure and dielectric properties of carbonyl-containing polyimide dielectrics.J. Appl. Polym. Sci.2019,136, 47883..

Huang, X. Y.; Xie, L. Y.; Hu, Z. W.; Jiang, P. K. Influence of batio3nanoparticles on dielectric, thermophysical and mechanical properties of ethylene-vinyl acetate elastomer/BaTiO3microcomposites.IEEE Trns. Dielectr. Electr. Insul.2011,18, 375−383..

Starkweather, H. W. Simple and complex relaxations.Macromolecules1981,14, 1277−1281..

Korzhenko, A.; Tabellout, M.; Emery, J. R. Influence of a metal–polymer interfacial interaction on dielectric relaxation properties of polyurethane.Polymer.1999,40, 7187−7195..

Wu, D.; Zhao, X.; Li, X. T.; Dong, J.; Zhang, Q. H. Polyimide film containing sulfone groups with high dielectric properties.Polymer2022,256, 125221..

Feng, Q. K.; Liu, D. F.; Zhang, Y. X.; Pei, J. Y.; Zhong, S. L.; Hu, H. Y.; Wang, X. J.; Dang, Z. M. Significantly improved high-temperature charge-discharge efficiency of all-organic polyimide composites by suppressing space charges.Nano Energy.2022,99, 107410..

Zhang, Z. B.; Wang, D. H.; Litt, M. H.; Tan, L. S.; Zhu, L. High-temperature and high-energy-density dipolar glass polymers based on sulfonylated poly(2,6-dimethyl-1,4-phenylene oxide).Angew. Chem. Int. Ed.2018,57, 1528−1531..

Liu, G.; Feng, Y.; Zhang, T. D.; Zhang, C. H.; Chi, Q. G.; Zhang, Y. Q.; Zhang, Y.; Lei, Q. Q. High-temperature all-organic energy storage dielectric with the performance of self-adjusting electric field distribution.J. Mater. Chem. A2021,9, 16384−16394..

Li, H.; Chang, B. S.; Kim, H.; Xie, Z. L.; Lainé, A.; Ma, L.; Xu, T. L.; Yang, C. Q.; Kwon, J.; Shelton, S. W.; Klivansky, L. M.; Altoé, V.; Gao, B.; Schwartzberg, A. M.; Peng, Z.; Ritchie, R. O.; Xu, T.; Salmeron, M.; Ruiz, R.; Sharpless, K. B.; Wu, P.; Liu, Y. High-performing polysulfate dielectrics for electrostatic energy storage under harsh conditions.Joule2023,7, 95−111..

Ai, D.; Li, H.; Zhou, Y.; Ren, L. L.; Han, Z. B.; Yao, B.; Zhou, W.; Zhao, L.; Xu, J. M.; Wang, Q. Tuning nanofillers inin situprepared polyimide nanocomposites for high-temperature capacitive energy storage.Adv. Energy Mater.2020,10, 1903881..

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