A Radiative-Cooling Hierarchical Aligned Porous Poly(vinylidene fluoride) Film by Freeze-Thaw-Promoted Nonsolvent-Induced Phase Separation

Yiting Zhang; Jiahui Sun; Yufeng Wang; Yunchen Wu; Chun Huang; Chao Zhang; Tianxi Liu

doi:10.1007/s10118-024-3128-2

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A Radiative-Cooling Hierarchical Aligned Porous Poly(vinylidene fluoride) Film by Freeze-Thaw-Promoted Nonsolvent-Induced Phase Separation

RESEARCH ARTICLE | Updated：2024-06-26

- A Radiative-Cooling Hierarchical Aligned Porous Poly(vinylidene fluoride) Film by Freeze-Thaw-Promoted Nonsolvent-Induced Phase Separation
- A Radiative-Cooling Hierarchical Aligned Porous Poly(vinylidene fluoride) Film by Freeze-Thaw-Promoted Nonsolvent-Induced Phase Separation
- 高分子科学（英文版） 2024年42卷第7期页码：976-983
- Affiliations：
  
  a.Key Laboratory of Synthetic and Biological Colloids Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China
  b.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
- Author bio：
  
  czhang@dhu.edu.cn (C.Z.)
  txliu@jiangnan.edu.cn (T.X.L.)
- Funds：
  
  This work was financially supported by the National Natural Science Foundation of China (No. 52273067), the Fundamental Research Funds for the Central Universities (No. 2232023A-03), the Shuguang Program of Shanghai Education Development Foundation and Shanghai Municipal Education Commission (No. 23SG29).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3128-2.
- DOI：10.1007/s10118-024-3128-2
  中图分类号：
- 收稿：2024-01-30，
  
  修回：2024-03-07，
  
  录用：2024-03-20，
  
  网络首发：2024-05-07，
  
  纸质出版：2024-07-01
- Accepted：
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Zhang, Y.; Sun, J.; Wang, Y.; Wu, Y.; Huang, C.; Zhang, C.; Liu, T. X. A radiative-cooling hierarchical aligned porous poly(vinylidene fluoride) film by freeze-thaw-promoted nonsolvent-induced phase separation. Chinese J. Polym. Sci. 2024, 42, 976–983

Yiting Zhang, Jiahui Sun, Yufeng Wang, et al. A Radiative-Cooling Hierarchical Aligned Porous Poly(vinylidene fluoride) Film by Freeze-Thaw-Promoted Nonsolvent-Induced Phase Separation[J]. Chinese Journal of Polymer Science, 2024, 42(7): 976-983.
Zhang, Y.; Sun, J.; Wang, Y.; Wu, Y.; Huang, C.; Zhang, C.; Liu, T. X. A radiative-cooling hierarchical aligned porous poly(vinylidene fluoride) film by freeze-thaw-promoted nonsolvent-induced phase separation. Chinese J. Polym. Sci. 2024, 42, 976–983 DOI： 10.1007/s10118-024-3128-2.

Yiting Zhang, Jiahui Sun, Yufeng Wang, et al. A Radiative-Cooling Hierarchical Aligned Porous Poly(vinylidene fluoride) Film by Freeze-Thaw-Promoted Nonsolvent-Induced Phase Separation[J]. Chinese Journal of Polymer Science, 2024, 42(7): 976-983. DOI： 10.1007/s10118-024-3128-2.

摘要

A hierarchical aligned porous poly(vinylidene fluoride) film was prepared by a freeze-thaw-promoted nonsolvent-induced phase separation approach. The resultant film can work as a thermal-insulating radiative cooler

demonstrating high sunlight reflectance of 97%

high mid-infrared selective emissivity of 96% and impressive radiative cooling performance under direct sunlight conditions.

Abstract

Passive daytime radiative cooling (PDRC) is an innovative and sustainable cooling technology that holds immense potential for addressing the energy crisis. Despite the numerous reports on radiative coolers

the design of a straightforward

efficient

and readily producible system remains a challenge. Herein

we present the development of a hierarchical aligned porous poly(vinylidene fluoride) (HAP-PVDF) film through a freeze-thaw-promoted nonsolvent-induced phase separation strategy. This film features oriented microporous arrays in conjunction with random nanopores

enabling efficient radiative cooling performance under direct sunlight conditions. The incorporation of both micro- and nano-pores in the HAP-PVDF film results in a remarkable solar reflectance of 97% and a sufficiently high infrared thermal emissivity of 96%

facilitating sub-environmental cooling at 18.3 °C on sunny days and 13.1 °C on cloudy days. Additionally

the HAP-PVDF film also exhibits exceptional flexibility and hydrophobicity. Theoretical calculations further confirm a radiative cooling power of 94.8 W·m

−2

under a solar intensity of 1000 W·m

−2

demonstrating a performance comparable to the majority of reported radiative coolers.

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references

Abbasi, K. R.; Shahbaz, M.; Zhang, J.; Irfan, M.; Alvarado, R. Analyze the environmental sustainability factors of china: the role of fossil fuel energy and renewable energy. Renew. Energy 2022 , 187 , 390−402..

Aqilah, N.; Zaki, S. A.; Hagishima, A.; Rijal, H. B.; Yakub, F. Analysis on electricity use and indoor thermal environment for typical air-conditioning residential buildings in malaysia. Urban Clim. 2021 , 37 , 100830..

Maqbool, M.; Aftab, W.; Bashir, A.; Usman, A.; Guo, H.; Bai, S. Engineering of polymer-based materials for thermal management solutions. Compos. Commun. 2022 , 29 , 101048..

Xue, X.; Qiu, M.; Li, Y.; Zhang, Q. M.; Li, S.; Yang, Z.; Feng, C.; Zhang, W.; Dai, J. G.; Lei, D. Creating an eco-friendly building coating with smart subambient radiative cooling. Adv. Mater. 2020 , 32 , 1906751..

Raman, A. P.; Anoma, M. A.; Zhu, L.; Rephaeli, E.; Fan, S. Passive radiative cooling below ambient air temperature under direct sunlight. Nature 2014 , 515 , 540−544..

Zeng, S.; Pian,S.; Su, M.; Qing, Y.; Li, Xin.; Ma,Y.; Tao, G. Hierarchical-morphology metafabric for scalable passive daytime radiative cooling. Science 2021 , 373 , 692−696..

Tao, S.; Guan, F.; Chen, F.; Chen, M.; Fang, Z.; Lu, C.; Xu, Z. Construction of colorful super-omniphobic emitters for high-efficiency passive radiative cooling. Compos. Commun. 2021 , 28 , 100975..

Chan, K. Y.; Shen, X.; Yang, J.; Lin, K. T.; Venkatesan, H.; Kim, E.; Zhang, H.; Lee, J. H.; Yu, J.; Yang, J. Scalable anisotropic cooling aerogels by additive freeze-casting. Nat. Commun. 2022 , 13 , 5553..

Zhao, B.; Hu, M.; Ao, X.; Chen, N.; Pei, G. Radiative cooling: a review of fundamentals, materials, applications, and prospects. Appl. Energy 2019 , 236 , 489−513..

Chai, J.; Fan, J. Solar and thermal radiation-modulation materials for building applications. Adv. Energy Mater. 2022 , 13 , 2202932..

Xu, X.; Gu, J.; Zhao, H.; Zhang, X.; Dou, S.; Li, Y.; Zhao, J.; Zhan, Y.; Li, X. Passive and dynamic phase-change-based radiative cooling in outdoor weather. ACS Appl. Mater. Interfaces 2022 , 14 , 14313−14320..

Rephaeli, E.; Raman, A.; Fan, S. Ultrabroadband photonic structures to achieve high-performance daytime radiative cooling. Nano Lett. 2013 , 13 , 1457−1461..

Hossain, M. M.; Jia, B.; Gu, M. A metamaterial emitter for highly efficient radiative cooling. Adv. Opt. Mater. 2015 , 3 , 1047−1051..

Zhang, H.; Ly, K. C. S.; Liu, X.; Chen, Z.; Yan, M.; Wu, Z.; Wang, X.; Zheng, Y.; Zhou, H.; Fan, T. Biologically inspired flexible photonic films for efficient passive radiative cooling. Proc. Natl. Acad. Sci. 2020 , 117 , 14657−14666..

Yao, Z.; Yaoguang, M.; N., D. S.; Dongliang, Z.; Runnan, L.; Xiaobo, Y. Scalable-manufactured randomized glass-polymer hybrid metamaterial for daytime radiative cooling. Science 2017 , 355 , 1062−1066..

Li, X.; Peoples, J.; Yao, P.; Ruan, X. Ultrawhite BaSO 4 paints and films for remarkable daytime subambient radiative cooling. ACS Appl. Mater. Interfaces 2021 , 13 , 21733−21739..

Xiang, B.; Zhang, R.; Luo, Y.; Zhang, S.; Xu, L.; Min, H.; Tang, S.; Meng, X. 3D porous polymer film with designed pore architecture and auto-depositedSiO 2 for highly efficient passive radiative cooling. Nano Energy 2021 , 81 , 105600..

Sun, Y.; Ji, Y.; Javed, M.; Li, X.; Fan, Z.; Wang, Y.; Cai, Z.; Xu, B. Preparation of passive daytime cooling fabric with the synergistic effect of radiative cooling and evaporative cooling. Adv. Mater. Technol. 2021 , 7 , 2100803..

Zhou, K.; Li, W.; Patel, B. B.; Tao, R.; Chang, Y.; Fan, S.; Diao, Y.; Cai, L. Three-dimensional printable nanoporous polymer matrix composites for daytime radiative cooling. Nano Lett. 2021 , 21 , 1493−1499..

Jyotirmoy, M.; Yanke, F.; C., O. A.; Mingxin, J.; Kerui, S.; N., S. N.; Zhou, Z. H.; Xianghui, X.; Nanfang, Y.; Yuan, Y. Hierarchically porous polymer coatings for highly efficient passive daytime radiative cooling. Science 2018 , 362 , 315−319..

Shan, X.; Liu, L.; Wu, Y.; Yuan, D.; Wang, J.; Zhang, C.; Wang, J. Aerogel-functionalized thermoplastic polyurethane as waterproof, breathable freestanding films and coatings for passive daytime radiative cooling. Adv. Sci. 2022 , 9 , 2201190..

Zhong, H.; Li, Y.; Zhang, P.; Gao, S.; Liu, B.; Wang, Y.; Meng, T.; Zhou, Y.; Hou, H.; Xue, C. Hierarchically hollow microfibers as a scalable and effective thermal insulating cooler for buildings. ACS Nano 2021 , 15 , 10076−10083..

Yang, P.; He, J.; Ju, Y.; Zhang, Q.; Wu, Y.; Xia, Z.; Chen, L.; Tang, S. Dual-mode integrated Janus films with highly efficient NaH 2 PO 2 -enhanced infrared radiative cooling and solar heating for year-round thermal management. Adv. Sci. 2023 , 10 , 2206176..

Han, C.; Zhang, H.; Chen, Q.; Li , T.; Kong, L.; Zhao, H.; He, L. A directional piezoelectric sensor based on anisotropic PVDF/MXene hybrid foam enabled by unidirectional freezing. Chem. Eng. J. 2022 , 450 , 138280..

Munirasu, S.; Banat, F.; Durrani, A. A.; Haija, M. A. Intrinsically superhydrophobic PVDF membrane by phase inversion for membrane distillation. Desalination 2017 , 417 , 77−86..

Back, J.; Brandstätter, R.; Spruck, M.; Koch, M.; Penner, S.; Rupprich, M. Parameter screening of PVDF/PVP multi-channel capillary membranes. Polymers 2019 , 11 , 463..

Oikonomou, E. K.; Karpati, S.; Gassara, S.; Deratani, A.; Beaume, F.; Lorain, O.; Tencé-Girault, S.; Norvez, S. Localization of antifouling surface additives in the pore structure of hollow fiber PVDF membranes. J. Membr. Sci. 2017 , 538 , 77−85..

Wu, L.; Sun, J.; Wang, Q. Poly(vinylidene fluoride)/polyethersulfone blend membranes: effects of solvent sort, polyethersulfone and polyvinylpyrrolidone concentration on their properties and morphology. J. Membr. Sci. 2006 , 285 , 290−298..

Liao, X. L.; Sun, D. X.; Cao, S.; Zhang, N.; Huang, T.; Lei, Y. Z.; Wang, Y. Freely switchable super-hydrophobicity and super-hydrophilicity of sponge-like poly(vinylidene fluoride) porous fibers for highly efficient oil/water separation. J. Hazard. Mater . 2021 , 416 ..

Jinlei, L.; Xueyang, W.; Dong, L.; Ning, X.; Bin, Z.; Shanhui, F.; Jia, Z. A tandem radiative/evaporative cooler for weather-insensitive and high-performance daytime passive cooling. Sci. Adv. 2022 , 8 , eabq0411..

Xu, Y.; Fang, Y.; Tao, S.; Fang, Z.; Ni, Y.; Lu, C.; Xu, C.; Li, W.; Xu, Z. A transparent radiative cooling emitter with multi-band spectral regulation for building energy saving. Compos. Commun. 2023 , 43 , 101717..

Cai, C.; Wei, Z.; Ding, C.; Sun, B.; Chen, W.; Gerhard, C.; Nimerovsky, E.; Fu, Y.; Zhang, K. Dynamically tunable all-weather daytime cellulose aerogel radiative supercooler for energy-saving building. Nano Lett. 2022 , 22 , 4106−4114..

Wang, T.; Wu, Y.; Shi, L.; Hu, X.; Chen, M.; Wu, L. A structural polymer for highly efficient all-day passive radiative cooling. Nat. Commun. 2021 , 12 , 365..

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