Improving Thermal-oxidative Aging Resistance of Styrene-butadiene Rubber by Antioxidant Loaded Silica Aerogel

Xue-Fei Ping; Yu Wang; Lu Liu; Fu-Yong Liu; Hong-Wei He; Pi Wang; Wen-Wen Yu; Qiang Zheng

doi:10.1007/s10118-024-3125-5

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Improving Thermal-oxidative Aging Resistance of Styrene-butadiene Rubber by Antioxidant Loaded Silica Aerogel

RESEARCH ARTICLE | Updated：2024-08-06

- Improving Thermal-oxidative Aging Resistance of Styrene-butadiene Rubber by Antioxidant Loaded Silica Aerogel
- Improving Thermal-oxidative Aging Resistance of Styrene-butadiene Rubber by Antioxidant Loaded Silica Aerogel
- 高分子科学（英文版） 2024年42卷第8期页码：1198-1209
- Affiliations：
  
  a.College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
  b.Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering, Taiyuan 030032, China
  c.Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310058, China
- Author bio：
  
  liufuyong@tyut.edu.cn (F.Y.L.)
  zhengqiang@zju.edu.cn (Q.Z.)
- Funds：
  
  This work was financially supported by Natural Science Foundation of Shanxi Province (No. 202303021211075), Shanxi Province Science and Technology Key Research and Development Project (No. 201903D321065) and Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering (No. 2021SX-TD011).;Electronic supplementary information (ESI) is available free of charge in the online version of this article at http://doi.org/10.1007/s10118-024-3125-5.
- DOI：10.1007/s10118-024-3125-5
  中图分类号：
- 收稿：2023-12-04，
  
  修回：2024-02-28，
  
  录用：2024-03-11，
  
  网络首发：2024-04-25，
  
  纸质出版：2024-08-01
- Accepted：
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Ping, X. F.; Wang, Y.; Liu, L.; Liu, F. Y.; He, H. W.; Wang, P.; Yu, W. W.; Zheng, Q. Improving thermal-oxidative aging resistance of styrene-butadiene rubber by antioxidant loaded silica aerogel. Chinese J. Polym. Sci. 2024, 42, 1198–1209

Xue-Fei Ping, Yu Wang, Lu Liu, et al. Improving Thermal-oxidative Aging Resistance of Styrene-butadiene Rubber by Antioxidant Loaded Silica Aerogel[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1198-1209.
Ping, X. F.; Wang, Y.; Liu, L.; Liu, F. Y.; He, H. W.; Wang, P.; Yu, W. W.; Zheng, Q. Improving thermal-oxidative aging resistance of styrene-butadiene rubber by antioxidant loaded silica aerogel. Chinese J. Polym. Sci. 2024, 42, 1198–1209 DOI： 10.1007/s10118-024-3125-5.

Xue-Fei Ping, Yu Wang, Lu Liu, et al. Improving Thermal-oxidative Aging Resistance of Styrene-butadiene Rubber by Antioxidant Loaded Silica Aerogel[J]. Chinese Journal of Polymer Science, 2024, 42(8): 1198-1209. DOI： 10.1007/s10118-024-3125-5.

摘要

In this study

composite particles (A-N) with both slow-release and reinforcing functions were obtained by loading the antioxidant into the pores of silica aerogel powders. Thermo-oxidative aging of vulcanized rubber was inhibited by continuous release of antioxidant from A-N.

Abstract

The antioxidant

-isopropyl-

'-phenyl-

-phenylenediamine (4010NA) was dissolved in ethanol and impregnated into silica aerogel (SAG)

via

vacuum-pressure cycles

yielding composite particles (A-N) with enhanced sustained-release and reinforcing capabilities. The effect of A-N on the mechanical properties and thermal-oxidative aging resistance of styrene-butadiene rubber (SBR) vulcanizates was investigated. TGA and BET assessments indicated that the loading efficiency of 4010NA in SAG reached 14.26% within ethanol's solubility limit. Incorporating A-N into SBR vulcanizates significantly elevated tensile strength by 17.5% and elongation at break by 41.9% over those with fumed silica and free 4010NA. Furthermore

A-N notably enhanced the thermal-oxidative aging resistance of SBR. After aging for 96 h at 100 °C

the tensile strength and elongation at break of SBR with A-N sustained 70.09% and 58.61% of their initial values

respectively

with the retention rate of elongation at break being 62.8% higher

than that of SBR with fumed silica and free antioxidant. The study revealed that A-N composite particles significantly inhibited the crosslinking in SBR's molecular chains

reducing hardening and embrittlement during later thermal-oxidative aging stages.

关键词

Keywords

references

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